Foam regulators containing paraffin hydrocarbons and hydrophobic silica

• US 4,590,237 A
• Filed: 01/02/1985
• Issued: 05/20/1986
• Est. Priority Date: 01/02/1984
• Status: Expired due to Fees

• Current Assignee: Henkel KGaA (Henkel AG & Co KGaA)
• Original Assignee: Henkel KGaA (Henkel AG & Co KGaA)
• Inventors: Giesen, Brigitte, Seiter, Wolfgang, Schmadel, Edmund, Wuhrmann, Juan C.
• Primary Examiner(s): Foelak, Morton
• Assistant Examiner(s): Moore, M. L.
• Application Number:
  US06/688,207
• Time in Patent Office: 503 Days
• Field of Search: 524/480, 524/479, 252/99
• US Class Current: 524/480
• CPC Class Codes: B01D 19/04 by addition of chemical substances
• CPC Class Codes: B01D 19/0404 characterised by the nature of the chemical substance
• CPC Class Codes: B01D 19/0409 compounds containing Si-atoms
• CPC Class Codes: C11D 3/0026 Low foaming or foam regulating compositions
• CPC Class Codes: C11D 3/18 Hydrocarbons C11D3/164 takes precedence

Abstract

Foam regulators particularly suitable for use in surfactant-containing compositions, comprising a mixture of paraffin hydrocarbons and hydrophobic silica, preferably admixed with a carrier.

Claims

1. A foam regulator composition for in surfactant-containing products, consisting essentially of a mixture of

(a) microcrystalline paraffin wax having a solidification point of about 60°

to 95°

C., in an amount of about 5 to 60%;

(b) hard paraffin having a solidification point of about 40°

to 60°

C., in an amount of about 15 to 60%;

(c) soft paraffin having a solidification point of about 32°

to 42°

C., in an amount of about 1 to 50%; and

(d) hydrophobic, finely divided silica, in an amount of about 3 to 18%;

all percentages being by weight based on the total weight of the mixture, said composition being free from surfactants.

2. The foam regulator of claim 1 wherein said component (a) has a solidifiction point of about 62°

to 90°

C. and is present in an amount of about 20 to 55%.

3. The foam regulator of claim 1 wherein component (a) has a solidification point of about 62°

to 90°

C. and is present in an amount of about 30 to 50%.

4. The foam regulator of claim 1 wherein component (b) has a solidification point of about 42°

to 56°

C. and is present in an amount of about 20 to 50%.

5. The foam regulator of claim 1 wherein component (b) has a solidification point of about 42°

to 56°

C. and is present in an amount of about 25 to 45%.

6. The foam regulator of claim 1 wherein component (a) and component (b) are together present in an amount of at least about 50%.

7. The foam regulator of claim 1 wherein component (a) and component (b) are together present in an amount of about 65 to 85%.

8. The foam regulator of claim 1 wherein component (c) has a solidification point of about 35°

to 40°

C. and is present in an amount of about 5 to 25%.

9. The foam regulator of claim 1 wherein component (d) is present in an amount of about 5 to 15%.

10. The foam regulator of claim 1 wherein component

(a) has a solidification point of about 62°

to 90°

C. and is present in an amount of about 20 to 55%.

(b) has a solidification point of about 42°

to 56°

C. and is present in an amount of about 20 to 50%.

(c) has a solidification point of about 35°

to 40°

C. and is present in an amount of about 5 to 25%; and

(d) is present in an amount of about 5 to 15%.

11. The foam regulator of claim 10 wherein component (a) and component (b) are together present in an amount of about 65 to 85%.

12. The foam regulator of claim 1 further admixed with an auxiliary component which is at least one alcohol of the formula ##STR2## wherein:

R¹ and R² may be the same or different and each are C_4-16 -alkyl, the total number of carbon atoms being between 16 and 30.

13. The foam regulator of claim 12 wherein R¹ and R² are each straight chain.

14. The foam regulator of claim 12 wherein R¹ and R² are each a C_6-12 -alkyl.

15. The foam regulator of claim 12 wherein about 2 to 20 parts by weight of said mixture of (a), (b), (c), and (d) is admixed with said auxiliary component present q.s. to 100 parts by weight.

16. The foam regulator of claim 15 wherein:

component

(a) is present in about 20 to 45%;

(b) is present in about 15 to 40%;

(c) is present in about 20 to 50%;

(d) is present in about 5 to 15%.

17. The foam regulator of claim 1 adsorbed on a water-soluble granular carrier whose particles have a grain size of about 0.1 to 1.6 mm.

18. The foam regulator of claim 12 adsorbed on a water-soluble granular carrier whose particles have a grain size of about 0.1 to 1.6 mm.

19. The foam regulator of claim 17 wherein said foam regulator composition is about 2 to 20% by weight of the adsorbed granulate.

20. The foam regulator of claim 18 wherein said foam regulator composition is about 2 to 20% by weight of the adsorbed granulate.

21. The foam regulator of claim 17 wherein said mixture of (a), (b), (c) and (d) is adsorbed while in a molten state and said carrier granules are heated.

22. The foam regulator of claim 18 wherein said mixture of (a), (b), (c) and (d) is adsorbed while in a molten state and said carrier granules are heated.

23. The foam regulator of claim 21 wherein the temperature of said carrier is plus/minus 20°

C. of the solidification point of said molten mixture.

24. The foam regulator of claim 22 wherein the temperature of said carrier is plus/minus 20°

C. of the solidification point of said molten mixture.

25. The foam regulator of claim 21 wherein said mixture of (a), (b), (c), and (d) is adsorbed while in the form of an aqueous solution or dispersion and said adsorbed granules are then spray dried.

26. The foam regulator of claim 23 wherein said mixture of (a), (b), (c), and (d) is adsorbed while in the form of an aqueous solution or dispersion and said adsorbed granules are then spray dried.

27. The foam regulator of claim 25 wherein water-soluble polymers are added to said aqueous solution or dispersion in a quantity of about 0.3 to 3% by weight based on the weight of the anhydrous constituents, prior to admixture with said granular carrier.

28. The foam regulator of claim 26 wherein water-soluble polymers are added to said aqueous solution or dispersion in a quantity of about 0.3 to 3% by weight based on the weight of the anhydrous constituents, prior to admixture with said granular carrier.