Method of making light polarizer

• US 4,591,512 A
• Filed: 01/25/1985
• Issued: 05/27/1986
• Est. Priority Date: 01/25/1985
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: Polaroid Corporation (PLR IP Holdings LLC)
• Inventors: Trapani, Giorgio B., Racich, James L., Schuler, Norman W.
• Primary Examiner(s): Hoffman, James R.
• Application Number:
  US06/694,921
• Time in Patent Office: 487 Days
• Field of Search: 427/163, 427/160, 350/397, 350/398
• US Class Current: 427/163.1
• CPC Class Codes: B05D 3/12 by mechanical means
• CPC Class Codes: B05D 7/04 to surfaces of films or sheets producing layered products by applying coatings of pasty or pulverulent plastics B29C41/00

Abstract

There is described a method for making visible range dichroic polarizer material comprising a uniaxially stretched film of polyvinyl alcohol stained with iodine and treated with a borating solution containing a zinc salt. The method comprises the steps of staining a uniaxially stretched sheet of polyvinyl alcohol and further stretching the stained sheet while it is being treated with a borating solution containing a zinc salt. High efficiency visible range dichroic polarizer elements having good neutrality, very high extinction and high transmittance can be made according to the method.

Claims

1. A method of making a light polarizing element comprising the steps of

immersing a uniaxially stretched film of polyvinyl alcohol in an iodine stain solution, and

restretching said stained film in substantially the previously uniaxially stretched direction while immersing it in a borating solution comprising an aqueous solution of boric acid, potassium iodide and zinc ion.

2. The method as defined in claim 1 wherein said uniaxially stretched film of polyvinyl alcohol is approximately 3.6 times its normal dimension in the stretched direction and wherein said restretching is from about 35% to about 50% of the stretched dimension of the film.

3. The method as defined in claim 2 wherein said restretching is about 40% of the stretched dimension of the film.

4. The method as defined in claim 1 and further including the step of relaxing said uniaxially stretched film in substantially the previously uniaxially stretched direction while it is immersed in said iodine stain solution.

5. The method as defined in claim 4 wherein said relaxing is from about 5% to about 15% of said uniaxially stretched dimension.