Apparatus and process for desalination combining freeze concentration, centrifugation, and reverse osmosis

• US 4,592,768 A
• Filed: 10/20/1983
• Issued: 06/03/1986
• Est. Priority Date: 10/20/1983
• Status: Expired due to Fees

• Current Assignee: Chicago Bridge & Iron Company (Mcdermott International Incorporated)
• Original Assignee: Chicago Bridge & Iron Company (Mcdermott International Incorporated)
• Inventors: Cutler, Donald R., Blankshain, Alan R.
• Primary Examiner(s): Sever, Frank
• Application Number:
  US06/543,760
• Time in Patent Office: 957 Days
• Field of Search: 62/532, 62/536, 62/544, 23/296, 23/295 R, 210/652, 210/774, 210/321.1, 210/433.2, 210/259, 210/651, 210/295
• US Class Current: 62/532
• CPC Class Codes: B01D 2311/02 Specific process operations before starting the membrane separation process
• CPC Class Codes: B01D 2311/106 Cooling
• CPC Class Codes: B01D 2311/2676 Centrifugal separation
• CPC Class Codes: B01D 61/025 Reverse osmosis; Hyperfiltration
• CPC Class Codes: B01D 61/08 Apparatus therefor
• CPC Class Codes: B01D 9/0013 by indirect heat exchange
• CPC Class Codes: C02F 1/22 by freezing
• CPC Class Codes: Y02A 20/124 Water desalination
• CPC Class Codes: Y02A 20/131 Reverse-osmosis

Abstract

Apparatus comprising a freeze exchanger in which an aqueous mixture is indirectly cooled by a cooling fluid to produce an aqueous mixture containing ice; a centrifuge; a conduit for feeding an ice slurry from the freeze exchanger to the centrifuge; a heater; a conduit for feeding ice from the centrifuge to the heater to melt the ice; a water treatment apparatus; a conduit for feeding the water from the heater to the water treatment apparatus to condition the water for contact with a reverse osmosis membrane; a reverse osmosis apparatus; and a conduit for feeding the conditioned water to the reverse osmosis apparatus in which the water is purified by reverse osmosis. A method comprising feeding an aqueous mixture into indirect heat exchange with a cooling fluid to produce ice particles in the aqueous mixture and thus to form an ice slurry; centrifuging the ice slurry to separate the ice and form an aqueous effluent; melting the separated ice and treating the resulting water to remove components which damage a reverse osmosis membrane; and subjecting the treated water to reverse osmosis using a reverse osmosis membrane to produce potable water and an impure water stream.

Claims

1. Apparatus comprising means designed for producing potable water from brine by converting brine to ice containing residual brine adhering to the ice and removing the brine from the ice to yield potable water when melted, the means comprising:

a freeze exchanger in which brine is indirectly cooled by heat exchange with a cooling fluid to produce brine containing ice;

a centrifuge;

conduit means for feeding an ice slurry from the freeze exchanger to the centrifuge to separate ice from the brine;

a heater;

conduit means for feeding the ice from the centrifuge to the heater to melt the ice;

a water treatment apparatus;

conduit means for feeding the water from the heater to the water treatment apparatus to condition the water for contact with a reverse osmosis membrane;

a reverse osmosis apparatus; and

conduit means for feeding the conditioned water from the treatment apparatus to the reverse osmosis apparatus in which the water is purified by reverse osmosis.

2. Apparatus according to claim 1 including a conduit means for returning brine effluent from the centrifuge to the freeze exchanger.

3. Apparatus according to claim 2 including a conduit means for returning impure water from the reverse osmosis apparatus to the freeze exchanger.

4. Apparatus according to claim 1 including a refrigeration closed loop containing the cooling fluid used in the freeze exchanger;

the cooling fluid is a refrigerant;

the refrigeration closed loop includes a refrigerant water cooled condenser;

conduit means for feeding warm water from the condenser to the heater to indirectly melt ice in the heater; and

conduit means for feeding cold water from the heater to the condenser to indirectly cool and condense refrigerant therein.

5. A method comprising producing potable water from brine by converting brine to ice containing residual brine adhering to the ice and removing the brine from the ice to yield potable water when melted, including:

feeding brine into indirect heat exchange with a cooling fluid to produce ice particles in the brine and thus to form an ice slurry;

centrifuging the ice slurry to separate the ice and brine;

melting the separated ice and treating the resulting water to remove components which damage a reverse osmosis membrane; and

subjecting the treated water to reverse osmosis using a reverse osmosis membrane to produce potable water and an impure water stream.

6. A method according to claim 5 including recycling the brine from the centrifuging to the freeze exchanger.

7. A method according to claim 5 including recycling the impure water stream from the reverse osmosis step to the freeze exchanger.

8. A method according to claim 5 in which:

the cooling fluid is a refrigerant in a refrigeration closed loop which includes a water cooled condenser for condensing the refrigerant;

the separated ice is melted indirectly in a water heated heater;

cold water from the heater is fed to the condenser to condense the refrigerant; and

warm water from the condenser is fed to the heater to melt the ice.