Supported liquid membrane electrochemical separators

• US 4,592,973 A
• Filed: 05/03/1985
• Issued: 06/03/1986
• Est. Priority Date: 10/05/1983
• Status: Expired due to Fees

• Current Assignee: Castles Technology Co. Ltd.
• Original Assignee: Castles Technology Co. Ltd.
• Inventors: Pemsler, J. Paul, Dempsey, Michael D.
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US06/730,251
• Time in Patent Office: 396 Days
• Field of Search: 429/249, 429/254, 429/253, 429/206
• US Class Current: 429/206
• CPC Class Codes: C25B 13/08 based on organic materials
• CPC Class Codes: C25C 7/04 Diaphragms; Spacing elements
• CPC Class Codes: H01M 10/24 Alkaline accumulators
• CPC Class Codes: H01M 50/417 Polyolefins
• CPC Class Codes: H01M 50/489 Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
• CPC Class Codes: H01M 50/491 Porosity
• CPC Class Codes: H01M 50/497 Ionic conductivity
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

Supported liquid membrane separators improve the flexibility, efficiency and service life of electrochemical cells for a variety of applications. In the field of electrochemical storage, an alkaline secondary battery with improved service life is described in which a supported liquid membrane is interposed between the positive and negative electrodes. The supported liquid membranes of this invention can be used in energy production and storage systems, electrosynthesis systems, and in systems for the electrowinning and electrorefining of metals.

Claims

1. A separator for use in electrochemical cells, comprising:

a hydrophobic microporous membrane; and

a liquid ionic transport agent comprising an organic agent dissolved in an organic solvent supported by a porous matrix of the membrane that selectively transports specific cation or anion species through the membrane while rejecting others, wherein said liquid ionic transport agent is insoluble in the electrochemical electrolyte solution.

2. The separator of claim 1 wherein said electrolyte insoluble liquid ionic transport agent comprises:

a water insoluble organic complexing agent dissolved in a water insoluble polar organic solvent wherein the polar character of the solvent ensures low resistivity of the separator enabling the required current demand of the electrochemical cell.

3. The separator of claim 2 wherein said polar organic solvent is selected from the group consisting of hexanol, heptanol, n-octanol, n-decanol, cyclohexanol, phenethyl alcohol, benzyl alcohol and mixtures thereof.

4. The separator of claim 1 wherein the membrane has an overall porosity between about 30 to about 65 percent.

5. The separator of claim 4 wherein the membrane has a thickness from about 1 to about 3 mils.

6. The separator of claim 5 wherein the saturated membrane has a resistivity of less than about 100 ohm-cm².

7. The separator of claim 4 wherein the saturated membrane has a resistivity of less than about 10 ohm-cm².

8. A supported liquid membrane comprising a hydrophobic microporous membrane having a thickness between about 0.5 and 25 mils, whose pores support a mixture of a water insoluble organic complexing agent dissolved in a organic solvent therefore, wherein the mixture, which is substantially insoluble in the electrochemical electrolyte solution, selectively transports specific cation and anion species through said membrane.

9. The supported liquid membrane of claim 8 wherein the solvent is a mixture of a polar organic solvent and a hydrocarbon solvent.

10. The supported liquid membrane of claim 8 wherein the polar organic solvent is selected from the group consisting of cyclohexanol, hexanol, benzyl alcohol, decanol, phenethyl alcohol and mixtures thereof.

11. In an alkaline battery comprising at least one pair of a positive electrode and a negative electrode the improvement comprising a hydrophobic microporous membrane which supports within its porous matrix a liquid ionic transport agent interposed between the negative and the positive electrode, said agent which is substantially insoluble in the electrochemical electrolyte solution and consisting essentially of an organic ion transport agent in a polar organic solvent therefore, such that the electrolyte insoluble agent selectively transports specific cation and anion species through the microporous membrane.