Aluminum and silica clad refractory oxide thermal spray powder

• US 4,593,007 A
• Filed: 12/06/1984
• Issued: 06/03/1986
• Est. Priority Date: 12/06/1984
• Status: Expired due to Fees

• Current Assignee: Sulzer Metco Incorporated (Sulzer AG)
• Original Assignee: Perkinelmer Incorporated
• Inventors: Novinski, Edward R.
• Primary Examiner(s): Dixon, Jr., William R.
• Assistant Examiner(s): Group, Karl
• Application Number:
  US06/678,869
• Time in Patent Office: 544 Days
• Field of Search: 428/403, 428/404, 427/423, 501/104, 501/105, 501/128, 501/133, 501/152, 501/154, 501/134
• US Class Current: 501/105
• CPC Class Codes: C23C 4/06 Metallic material
• CPC Class Codes: Y10T 428/2991 Coated
• CPC Class Codes: Y10T 428/2993 Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]

Abstract

A thermal spray powder comprising particles with a central core of a material selected from the group consisting of zirconium oxide, magnesium oxide, hafnium oxide, cerium oxide, yttrium oxide and combinations thereof. The core then has discrete aluminum particles and silicon dioxide homogeneously disposed in a binder deposited thereon to form the thermal spray powder which may be thermal sprayed to produce an abradable and erosion resistant coating.

Claims

1. A thermal spray powder characterized by ability to produce an abradable and erosion resistant coating, consisting essentially of particles having a central core of a material selected from the group consisting of zirconium oxide, magnesium oxide, hafnium oxide, cerium oxide, yttrium oxide and combinations thereof, and aluminum and silicon dioxide homogeneously bonded to the surface of said core;

the powder particles having a size between about 149 microns and 5 microns; and

said aluminum being present in an amount between 0.5% and 15% by weight, and said silicon dioxide being present in an amount between 0.5% and 20% by weight, based on the total of the aluminum and the core material.

2. The thermal spray powder according to claim 1 in which said central core consisting essentially of a material selected from the group consisting of zirconium oxide, magnesium oxide and combinations thereof.

3. A thermal spray powder according to claim 1 in which said aluminum is present in an amount between 1% and 10% by weight and said silicon dioxide is present in an amount between 1% and 10% by weight, based on the total of the aluminum and the core material.

4. A thermal spray powder according to claim 1 in which said aluminum and said silicon dioxide are in the form of discrete particles bonded to the surface of said core with a binder, said aluminum particles having a size below 10 microns and said silicon dioxide particles having a size below 1 micron.

5. The thermal spray powder according to claim 4 in which said binder is an organic binder.

6. A thermal spray powder characterized by ability to produce an abradable and erosion resistant coating, consists essentially of particles having a central core of a material selected from the group consisting of zirconium oxide, magnesium oxide, hafnium oxide, cerium oxide, yttrium oxide and combinations thereof, and discrete particles of aluminum having a size below 10 microns bonded to the surface of said core with a binder comprising a silicon dioxide derivative of ethyl silicate;

the powder particles having a size between about 149 microns and 5 microns; and

said aluminum being present in an amount between 0.5% and 15% by weight, and said silicon dioxide being present in an amount between 0.5% and 20% by weight, based on the total of the aluminum and the core material.

7. The thermal spray powder according to claim 6 in which said binder further is an organic binder of the water soluble type.

8. The thermal spray powder according to claim 6 in which said central core consists essentially of a material selected from the group consisting of zirconium oxide, magnesium oxide and combinations thereof.

9. A thermal spray powder according to claim 6 in which said aluminum is present in the amount between 1% and 10% by weight and said silicon dioxide constant is between about 1% and 10% by weight based on the total of the aluminum and the core material.

10. A thermal spray powder characterized by ability to produce an abradable and erosion resistant coating, consisting essentially of particles having a magnesium zirconate core coated with a binder containing discrete particles of aluminum having a size below 10 microns, in which said spray powder particles have a size between about 149 microns and 5 microns, and said binder consisting essentially of organic binder of the water soluble type and a silicon dioxide derivative of ethyl silicate;

said aluminum being present in an amount between 1% and 10% by weight based on the total of the aluminum and core, and said silicon dioxide being present in an amount between 1% and 10% by weight, based on the total of the aluminum and core.