Stainless steel overcoat for sputtered films

• US 4,594,137 A
• Filed: 09/09/1983
• Issued: 06/10/1986
• Est. Priority Date: 09/09/1983
• Status: Expired due to Term

• Current Assignee: PPG Industries Incorporated Pittsburgh PA
• Original Assignee: PPG Industries Incorporated (Nouryon BV)
• Inventors: Criss, Russell C., Gillery, F. Howard
• Primary Examiner(s): Demers, Arthur P.
• Application Number:
  US06/530,570
• Time in Patent Office: 1,005 Days
• Field of Search: 428/426, 428/432, 428/433, 428/434, 428/428, 204/192 SP, 204/192 R, 204/192 C
• US Class Current: 204/192.16
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3607 Coatings of the type glass/inorganic compound/metal
• CPC Class Codes: C03C 17/3613 Coatings of type glass/inorganic compound/metal/inorganic compound/metal/other
• CPC Class Codes: C03C 17/3642 the multilayer coating containing a metal layer
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 17/3689 one oxide layer being obtained by oxidation of a metallic layer
• CPC Class Codes: C03C 2217/78 Coatings specially designed to be durable, e.g. scratch-resistant
• CPC Class Codes: C23C 14/16 on metallic substrates or on substrates of boron or silicon
• CPC Class Codes: C23C 14/18 on other inorganic substrates

Abstract

A method is disclosed for improving the stability and durability of sputtered metal films such as silver and copper by means of depositing a protective overcoat of a metal such as stainless steel on the exposed surface of the film.

Claims

1. In a method for coating a substrate with an elemental metal film selected from the group consisting of silver, copper, gold, platinum and palladium by cathode sputtering, the improvement which comprises depositing over the elemental metal film a protective overcoat of a metal which forms a dense oxide surface which protects said elemental metal film from oxidation.

2. In a method for coating a substrate with an elemental metal film by cathode sputtering, the improvement which comprises depositing over the elemental metal film a protective overcoat of a metal selected from the group consisting of stainless steel, titanium, vanadium, chromium, aluminum, tin, tantalum and nickel and alloys thereof.

3. In a method for coating a glass substrate with an elemental metal film by cathode sputtering wherein the substrate is first coated with a primer metal which bonds oxidatively with the glass surface, the improvement which comprises depositing over the elemental metal film a protective overcoat of a metal which forms a dense oxide surface, selected from the group consisting of stainless steel, titanium, vanadium, chromium, aluminum, tin, tantalum, nickel and alloys thereof.

4. The improved method according to claim 3, wherein the elemental metal film is selected from the group consisting of silver, gold, platinum, palladium, copper and mixtures thereof.

5. In a method for coating a substrate with an elemental metal film by cathode sputtering, wherein the elemental metal film is selected from the group consisting of silver, gold, platinum, palladium, copper and mixtures thereof, the improvement which comprises depositing over the elemental metal film a protection overcoat of a metal which forms a dense oxide surface selected from the group consisting of stainless steel and titanium.

6. The improved method according to claim 5, wherein primer, elemental metal film layers and overcoat are deposited by magnetically enhanced cathode sputtering.

7. The improved method according to claim 6, wherein the substrate is transparent, the primer layer is stainless steel, the elemental metal film comprises a layer of silver and a layer of copper, and the overcoat is stainless steel.

8. The improved method according to claim 7, wherein the substrate is glass and the stainless steel primer has a thickness of about 20 to 25 Angstroms.

9. The improved method according to claim 8, wherein the stainless steel overcoat has a thickness of about 30 to 40 Angstroms.

10. In a method for coating glass with a two-layer film of silver and copper by cathode sputtering, the improvement which comprises depositing over the film a protective overcoat of a metal which forms a dense oxide surface layer.

11. The improved method according to claim 10, wherein the overcoat metal is selected from the group consisting of stainless steel, titanium, vanadium, chromium, aluminum, tin, tantalum and nickel alloys.

12. The improved method according to claim 11, wherein the overcoat metal is stainless steel.

13. The improved method according to claim 12, wherein the thickness of the stainless steel overcoat is about 30 to 40 Angstroms.

14. The improved method according to claim 13, wherein the stainless steel primer, the silver and copper layers of the film and the stainless steel overcoat are all deposited by magnetron sputtering.