Programmable solvent delivery system and process

• US 4,595,495 A
• Filed: 02/22/1985
• Issued: 06/17/1986
• Est. Priority Date: 02/22/1985
• Status: Expired due to Fees

• Current Assignee: Eldex Laboratories Incorporated
• Original Assignee: Eldex Laboratories Incorporated
• Inventors: Carleton, Joseph G., Yotam, Reuben
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US06/704,201
• Time in Patent Office: 480 Days
• Field of Search: 210/101, 210/143, 210/198.2, 417/18
• US Class Current: 210/101
• CPC Class Codes: F04B 11/0058 with piston speed control
• CPC Class Codes: F04B 11/0066 with special shape of the actuating element
• CPC Class Codes: F04B 11/0075 connected in series
• CPC Class Codes: F04B 9/042 the means being cams
• CPC Class Codes: G01N 30/34 of fluid composition, e.g. gradient G01N30/36 takes precedence
• CPC Class Codes: G05D 11/132 by controlling the flow of the individual components G05D11/133 takes precedence

Abstract

A solvent delivery system (10) has first and second pistons (92, 94) and cylinders (58, 68) connected to first and second cams (110, 112). The cams (110, 112) each have a ramped portion (150, 162) and an abrupt step (152, 164). The first cylinder (58) is connected to solenoid valves (44, 46, 48) to fill the first cylinder with solvent components during movement of cam follower (104) along ramped portion (150) of the first cam (110). Spring (140) urges the first piston (92) forward into first cylinder (58). Movement of the cam follower (104) over the step (152) of the cam (110) moves the piston (92) forward abruptly to force the solvent components from cylinder (58) into second cylinder (68). Spring (178) urges piston (94) back in cylinder (68). The second cam (112) is reversed relative to first cam (110). Movement of cam follower (106) over abrupt step (164) of second cam (112) moves second piston (94) back abruptly in cylinder (68) to receive and mix the solvent components in the cylinder (68). Movement of cam follower (106) along ramped portion (162) of cam (112) moves piston (94) forward to force the solvent mixture from the second cylinder (68). A third piston (96) and cylinder (74) has a lesser volume than the first and second cylinders (58, 68). A third cam (114) and cam follower (108) move the third piston (96) back in cylinder (74) when second piston (94) moves forward in second cylinder (68). The second cylinder (68) delivers the solvent mixture to outlet (80) and fills third cylinder (74) while second piston (94) moves forward and third piston (96) moves back. The third cylinder (74) delivers the solvent mixture to outlet (80) while the third piston moves forward, the solvent component fills the first cylinder (58) and the first piston (92) and cylinder (58) fill the second cylinder (68). Check valves (60, 72, 78) prevent backflow in the system.

Claims

1. A solvent delivery system, which comprises first and second pistons and cylinders operatively coupled to first and second cams and cam followers, said first and second cams each having a ramped portion and an abrupt step, said first cylinder being connected to a plurality of solvent component inlets to fill said first cylinder with the solvent components during movement of said first cam follower along the ramped portion of said first cam, a first biasing means connected to urge said first piston forward into said first cylinder, movement of said first cam follower over the abrupt step of said first cam allowing said first piston to move forward abruptly to force the solvent components from said first cylinder into said second cylinder, a second biasing means connected to urge said second piston back in said second cylinder, said second cam being reversely arranged relative to said first cam, so that movement of said second cam follower over the abrupt step of said second cam allows said second piston to move back abruptly in said second cylinder to allow the solvent components to enter and be mixed to form a solvent mixture in said second cylinder, movement of said second cam follower along the ramped portion of said second cam moving said second piston forward into said second cylinder to force the solvent mixture from said second cylinder, a third piston and cylinder, said third cylinder having a lesser volume than said first cylinder and said second cylinder, a third cam and cam follower coupled to reciprocate said third piston in said third cylinder, said third cam being configured and positioned relative to said second cam so that said third piston moves back in said third cylinder when said second piston moves forward in said second cylinder, said second cylinder and said third cylinder being connected so that said second cylinder delivers the solvent mixture to an outlet and fills said third cylinder while said second piston moves forward in said second cylinder and said third piston moves back in said third cylinder, and said third cylinder delivers the solvent mixture to the outlet while said third piston moves forward in said third cylinder, said solvent component inlets fill said first cylinder and said first piston and cylinder fill said second cylinder, and first, second and third check valves, said first check valve being connected between said plurality of solvent component inlets and said first cylinder, said second check valve being connected between said first cylinder and said second cylinder and said third check valve being connected between said second cylinder and said third cylinder.

2. The solvent delivery system of claim 1 in which said first, second and third cams are mounted on a common shaft and a stepper motor is coupled to said shaft.

3. The solvent delivery system of claim 2 additionally comprising a plurality of solenoid valves, one of said plurality of solenoid valves being connected between each of said solvent component inlets and said first cylinder.

4. The solvent delivery system of claim 3 additionally comprising a microprocessor connected to supply control signals to said plurality of solenoid valves.

5. The solvent delivery system of claim 4 in which said microprocessor is further connected to supply control signals to said stepper motor.

6. The solvent delivery system of claim 5 additionally comprising a sensor positioned to sense position of said shaft and connected to supply position input signals to said microprocessor.

7. The solvent delivery system of claim 6 additionally comprising a pressure transducer between said second and third cylinders and said outlet, said pressure transducer being connected to supply pressure input signals to said microprocessor.

8. The solvent delivery system of claim 1 in which said first piston and cylinder is configured to deliver a somewhat larger volume than said second piston and cylinder.

9. The solvent delivery system of claim 5 in which said system is configured so that said second and third pistons and cylinders overlap in providing the solvent to the outlet.

10. A solvent delivery system, which comprises first and second pistons and cylinders operatively coupled to first and second piston drive means configured to move said first and second pistons abruptly in one direction and more slowly in an opposite direction, said first cylinder being connected to a plurality of solvent component inlets to fill said first cylinder with the solvent components during movement of said first piston drive means to move said piston in its slowly moving direction, movement of said first piston drive means in its abruptly moving direction causing said first piston to move forward abruptly to force the solvent components from said first cylinder into said second cylinder, said second piston drive means being reversely arranged relative to said first piston drive means, so that movement of said second piston drive means in its abruptly moving direction causes said second piston to move back abruptly in said second cylinder to allow the solvent components to enter and be mixed to form a solvent mixture in said second cylinder, movement of said second piston drive means in its slowly moving direction moving said second piston forward into said second cylinder to force the solvent mixture from said second cylinder, a third piston and cylinder, said third cylinder having a lesser volume than said first cylinder and said second cylinder, a third piston drive means coupled to reciprocate said third piston in said third cylinder, said third piston drive means being configured relative to said second piston drive means so that said third piston moves back in said third cylinder when said second piston moves forward in said second cylinder, said second cylinder and said third cylinder being connected so that said second cylinder delivers the solvent mixture to an outlet and fills said third cylinder while said second piston moves forward in said second cylinder and said third piston moves back in said third cylinder, and said third cylinder delivers the solvent mixture to the outlet while said third piston moves forward in said third cylinder, said solvent component inlets fill said first cylinder and said first piston and cylinder fill said second cylinder, and first, second and third backflow prevention means, said first backflow prevention means being connected between said plurality of solvent component inlets and said first cylinder, said second backflow prevention means being connected between said first cylinder and said second cylinder and said third backflow prevention means being connected between said second cylinder and said third cylinder.

11. The solvent delivery system of claim 10 in which said first, second and third piston drive means are mounted on a common shaft powered by a single motive means coupled to said shaft.

12. The solvent delivery system of claim 11 additionally comprising a plurality of controllable valves, one of said plurality of controllable valves being connected between each of said solvent component inlets and said first cylinder.

13. The solvent delivery system of claim 12 additionally comprising a microprocessor connected to supply control signals to said plurality of controllable valves.

14. The solvent delivery system of claim 13 in which said microprocessor is further connected to supply control signals to said motive means.

15. The solvent delivery system of claim 14 additionally comprising a sensor positioned to sense position of said shaft and connected to supply position input signals to said microprocessor.

16. The solvent delivery system of claim 15 additionally comprising a pressure transducer between said second and third cylinders and said outlet, said pressure transducer being connected to supply pressure input signals to said microprocessor.

17. The solvent delivery system of claim 10 in which said first piston and cylinder is configured to deliver a somewhat larger volume than said second piston and cylinder.

18. The solvent delivery system of claim 10 in which said system is configured so that said second and third pistons and cylinders overlap in providing the solvent to the outlet.

19. A process for delivering a solvent mixture, which comprises drawing a plurality of solvent components for the mixture from a plurality of solvent component inlets into a first cylinder, abruptly injecting the solvent components into a second cylinder to mix the components in the second cylinder, forcing the resulting solvent mixture out of the second cylinder to supply a first portion of the solvent mixture to an outlet for the solvent mixture and a second portion of the solvent mixture to a third cylinder, and forcing the second portion of the solvent mixture from the third cylinder to supply the second portion of the solvent mixture to the outlet while drawing the solvent components into the first cylinder and injecting the solvent components from the first cylinder into the second cylinder.

20. The process of claim 19 additionally comprising the step of opening the controllable valves for each solvent component inlet for different lengths of time during the step of drawing the solvent components into the first cylinder to vary the composition of the solvent mixture.

21. The process of claim 19 additionally comprising the step of sensing solvent pressure while delivering the solvent mixture to the outlet and using the sensed pressure to compensate for solvent compressibility.

22. The process of claim 21 in which the sensed pressure is used to compensate for solvent compressibility by reducing an amount of force applied to the solvent mixture in the second and third cylinders to force the solvent mixture from the second and third cylinders to the outlet during an interval in which the second and third cylinders both supply the solvent mixture to the outlet.

23. The process of claim 19 in which the first cylinder delivers a somewhat larger volume of solvent components than the solvent mixture delivered by the second cylinder.

24. The process of claim 19 in which the second and third pistons and cylinders overlap in providing the solvent to the outlet.