Automotive paint compositions containing pearlescent pigments and dyes

• US 4,598,020 A
• Filed: 08/16/1985
• Issued: 07/01/1986
• Est. Priority Date: 08/16/1985
• Status: Expired due to Term

• Current Assignee: BASF Corporation (BASF SE)
• Original Assignee: Inmont Corp. (BASF SE)
• Inventors: Panush, Sol
• Primary Examiner(s): Lilling, Herbert J.
• Application Number:
  US06/766,237
• Time in Patent Office: 319 Days
• Field of Search: 523/171, 523/210, 427/385.5, 427/388.1, 427/407.1, 427/407.2, 427/408, 427/409, 428/324, 428/334, 428/443, 428/461, 428/537.1, 428/689, 428/690, 428/411.1
• US Class Current: 428/411.1
• CPC Class Codes: C08K 9/02 Ingredients treated with inorganic substances
• CPC Class Codes: C09D 5/36 Pearl essence, e.g. coatings containing platelet-like pigments for pearl lustre
• CPC Class Codes: Y10T 428/251 Mica
• CPC Class Codes: Y10T 428/263 Coating layer not in excess of 5 mils thick or equivalent
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]
• CPC Class Codes: Y10T 428/31652 Of asbestos
• CPC Class Codes: Y10T 428/31692 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31989 Of wood

Abstract

A transparent topcoat coating compositions is described comprising a thermosetting resin material containing a pigment composition and a soluble dye. The pigment composition contains about 40 weight percent to about 80 weight percent of iron oxide encapsulated mica particles. The composition also contains 0.5 weight percent to about 82.5 weight percent of a soluble 1:2 chrome or 1:2 cobalt metal organic complex dye. When used in a multi-coat coating process as a base coat overcoated with a transparent topcoat, an article is produced having improved pearlescent color effects, improved depth and clarity, and resistance to fade from ultraviolet light.

Claims

1. A pearlescent coating composition comprising thermoplastic or thermosetting resin containing about 1% to about 25% by weight of a pigment composition comprising about 5% to about 90% by weight of iron oxide encapsulated mica particles, wherein the improvement comprises the inclusion of about 0.5 weight percent to about 82.5 weight percent (of the pigment composition) in the coating of a metal organic complex dye selected from the group consisting of 1:

2 cobalt metal organic complex dyes and 1;

2 chrome metal organic complex dyes, the inclusion of such metal organic complex dyes resulting in a fade-free coating composition.

2. The coating composition of claim 1 wherein the pigment composition additionally comprises about 0.5 weight percent to about 18 weight percent of a metallic flake pigment.

3. The coating composition of claim 1 wherein the metal organic complex dye is selected from the group consisting of C.I. Solvent Yellow 88, C.I. Solvent Yellow 89, C.I. Solvent Yellow 25, C.I. Solvent Orange 11, C.I. Solvent Orange 59, C.I. Solvent Red 7, C.I. Solvent Violet 24, and C.I. Solvent Black 29.

4. The composition of claim 1 wherein the thermosetting resin is an acrylic resin.

5. A substrate material coated with at least two layers of polymer including a base coat comprising a pigmented thermosetting resin and a transparent topcoat on the base coat comprising a clear thermosetting or thermoplastic resin, the pigmented thermosetting resin comprising about 1% to about 25% by weight of a pigment composition comprising about 5% to about 90% by weight of iron oxide encapsulated mica particles, wherein the improvement comprises the inclusion of about 0.5 percent to about 82.5 percent by weight (of the pigment composition) of a metal organic complex dye selected from the group consisting of 1:

2 chrome or 1;

2 cobalt metal organic complex dye in the base coat resulting in a coating which is fade free.

6. The substrate material of claim 5 wherein the pigment composition additionally comprises about 0.5 weight percent to about 18 weight percent of a metallic flake pigment.

7. The substrate material of claim 5 wherein the metal organic complex dye is selected from the group consisting of C.I. Solvent Yellow 88, C.I. Solvent Yellow 89, C.I. Solvent Yellow 25, C.I. Solvent Orange 11, C.I. Solvent Orange 59, C.I. Solvent Red 7, C.I. Solvent Violet 24 and C.I. Solvent Black 29.

8. A method of coating a substrate with multiple layers of polymer comprising applying at least one layer of a base coat of pigmented thermosetting resin to the substrate, applying at least one layer of a transparent thermosetting or thermoplastic topcoat on the base coat, and drying and curing the applied coatings, the pigmented thermosetting resin comprising about 1% to about 25% by weight of a pigment composition comprising about 5% to about 90% by weight of iron oxide encapsulated mica particles, wherein the improvement comprises the inclusion of about 0.5 weight percent to about 82.5 weight percent by weight (of the pigment composition) of a metal organic complex dye selected from the group consisting of 1:

2 chrome and 1;

2 cobalt metal organic complex dyes in the base coat resulting in a fade free coating.

9. The method of claim 8 wherein the metal organic complex dye is selected from the group consisting of C.I. Solvent Yellow 88, C.I. Solvent Yellow 89, C.I. Solvent Yellow 25, C.I. Solvent Orange 11, C.I. Solvent Orange 59, C.I. Solvent Red 7, C.I. Solvent Violet 24 and C.I. Solvent Black 29.

10. The method of claim 8 wherein the pigment composition additionally comprises about 0.5 weight percent to aobut 18 weight percent of a metallic flake pigment.