Radiation image storage panel

• US 4,599,539 A
• Filed: 05/15/1984
• Issued: 07/08/1986
• Est. Priority Date: 05/16/1983
• Status: Expired due to Term

• Current Assignee: Fuji Photo Film Company Limited No 200 Oonakazato Fujinomiya-Shi Shizuoka Japan
• Original Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Inventors: Yamazaki, Hisashi, Ishizuka, Akio, Yamazaki, Kikuo
• Primary Examiner(s): Moore, David K.
• Assistant Examiner(s): WIEDER, KENNETH A
• Application Number:
  US06/610,575
• Time in Patent Office: 784 Days
• Field of Search: 313/502, 313/525, 313/543, 313/586, 313/509, 313/503, 252/301.36, 428/416, 428/423.7
• US Class Current: 313/525
• CPC Class Codes: G21K 4/00 Conversion screens for the conversion of the spatial distribution of X-rays or particle radiation into visible images, e.g. fluoroscopic screens photographic processes using X-ray intensifiers G03C5/17; discharge tubes comprising luminescent screens H01J1/62; cathode ray tubes for X-ray conversion with optical output H01J31/50

Abstract

A radiation image storage panel comprising a support and a phosphor layer provided thereon which comprises a binder and a stimulable phosphor dispersed therein, characterized in that said binder contains a (meth)acrylic copolymer in the amount of 5-100% by weight, which has repeating units represented by the formulas (I), (II) and (III): ##STR1## in which each of R₁, R₃ and R₅ is independently a hydrogen atom or an alkyl group; R₂ is a group selected from those consisting of an alkyl group, a cycloalkyl group, an aryl group, a heterocyclic group and an aralkyl group; R₄ is a hydrogen atom or an alkyl group and R₂ ≠R₄ ; and x, y and z representing molar percents are numbers satisfying the conditions of 5≦x≦99, 1≦y+z≦95 and x+y+z≧90. The (meth)acrylic copolymer is preferably employed in combination with a linear polyester having a hydroxyl value in the range of 20-70%.

Claims

1. A radiation image storage panel comprising a support and a phosphor layer provided thereon which comprises a binder and a stimulable phosphor dispersed therein, characterized in that said binder contains a (meth)acrylic copolymer in the amount of 5-100% by weight, which has repeating units represented by the formulas (I), (II) and (III):

##STR6## in which each of R₁, R₃ and R₅ is independently a hydrogen atom or an alkyl group;

R₂ is a group selected from those consisting of an alkyl group, a cycloalkyl group, an aryl group, a heterocyclic group and an aralkyl group;

R₄ is a hydrogen atom or an alkyl group and R₂ ≠

R₄ ; and

x, y and z representing molar percents are numbers satisfying the conditions of 5≦

x≦

99, 1≦

y+z≦

95 and x+y+z≧

90.

2. The radiation image storage panel as claimed in claim 1, in which x, y and z in the formulas (I), (II) and (III) are numbers satisfying the conditions of 50≦

x≦

95, 5≦

y+z≦

50 and x+y+z≧

95, and said binder contains the (meth)acrylic copolymer in the amount of 40-90% by weight.

3. The radiation image storage panel as claimed in claim 2, in which x, y and z in the formulas (I), (II) and (III) are numbers satisfying the conditions of 70≦

x≦

95, y=0, 5≦

z≦

30 and x+y+z≧

95.

4. The radiation image storage panel as claimed in claim 2, in which x, y and z in the formulas (I), (II) and (III) are numbers satisfying the conditions of x+y+z=100.

5. The radiation image storage panel as claimed in claim 1, in which said (meth)acrylic copolymer is crosslinked with a crosslinking agent.

6. The radiation image storage panel as claimed in claim 5, in which said crosslinking agent is polyisocyanate.

7. The radiation image storage panel as claimed in any one of claims 1 through 6, in which said stimulable phosphor is a divalent europium activated alkaline earth metal fluorohalide phosphor.

8. A radiation image storage panel comprising a support, a phosphor layer which comprises a binder and a stimulable phosphor dispersed therein, and a protective film, superposed in this order, characterized in that said binder contains a mixture of a (meth)acrylic copolymer having repeating units represented by the formulas (I), (II) and (III) and a linear polyester having a hydroxyl value in the range of 20-70% whose content is not more than 40% by weight of said mixture, in the amount of 60-100% by weight:

##STR7## in which each of R₁, Rhd 3 and R₅ is independently a hydrogen atom or an alkyl group;

R₂ is a group selected from those consisting of an alkyl group, a cycloalkyl group, an aryl group, a heterocyclic group and an aralkyl group;

R₄ is a hydrogen atom or an alkyl group and R₂ ≠

R₄ ; and

x, y and z representing molar percents are numbers satisfying the conditions of 5≦

x≦

99, 1≦

y+z≦

95 and x+y+z≧

90.

9. The radiation image storage panel as claimed in claim 8, in which said linear polyester has a molecular weight in the range of 3×

10³ -10⁴.

10. The radiation image storage panel as claimed in claim 8, in which said binder contains the mixture of (meth)acrylic copolymer and linear polyester in the amount of 75-95% by weight.

11. The radiation image storage panel as claimed in claim 8, in which the content of said linear polyester is in the range of 10-40% by weight of the mixture.

12. The radiation image storage panel as claimed in any one of claims 8 through 11, in which said stimulable phosphor is a divalent europium activated alkaline earth metal fluorohalide phosphor.