Method for increasing the reactivity and digestibility of cellulose with ammonia
First Claim
1. A process for enhancing the cellulose digestibility and protein availability of alfalfa to enhance the alfalfa as a feed for animals, said process comprising applying ammonia to the alfalfa for a time period less than about one hour at a treatment pressure in the range of about 140 psia to about 180 psia and at a treatment temperature of about 25°
- C., thereby increasing the digestibility of the cellulose in the alfalfa and increasing the availablity of protein from the fibers and from within the cell walls of the the alfalfa to animals.
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Abstract
A method of treating cellulose-containing materials to increase chemical and biological reactivity of cellulose. The cellulose is contacted, in a pressure vessel, with a volatile liquid swelling agent having a vapor pressure greater than atmospheric at ambient temperatures, such as ammonia. The contact is maintained for a sufficient time to enable said agent to swell the cellulose fibers. The pressure is rapidly reduced to atmospheric, allowing said agent to boil and explode the cellulose fiber structure. The rapid pressure reduction also causes some freezing of the cellulose. The agent is separated from said cellulose and recovered for recycling.
146 Citations
6 Claims
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1. A process for enhancing the cellulose digestibility and protein availability of alfalfa to enhance the alfalfa as a feed for animals, said process comprising applying ammonia to the alfalfa for a time period less than about one hour at a treatment pressure in the range of about 140 psia to about 180 psia and at a treatment temperature of about 25°
- C., thereby increasing the digestibility of the cellulose in the alfalfa and increasing the availablity of protein from the fibers and from within the cell walls of the the alfalfa to animals.
- View Dependent Claims (2, 3)
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4. The method of treating alfalfa having a water content of up to about 30% by weight of increase the chemical and biological rcactivity, comprising mixing alfalfa with liquid ammonia, in the weight ratio of ammonia to alfalfa of about one to one respectively, at a temperature of about 25°
- C., and under the vapor pressure of liquid ammonia at said temperature, maintaining said alfalfa and ammonia mixture at said mixing temperature and pressure for a period of time sufficient for the ammonia to swell the cellulose of the alfalfa, rapidly reducing the pressure from mixing pressure to atmospheric pressure and allowing the ammonia to boil and thereby to explode and freeze the alfalfa, maintaining said alfalfa and ammonia mixture at the boiling point of the ammonia for a time sufficient to continue freeze treating of the alfalfa to disrupt the cellulose cells of the alfalfa and enhance the reactivity thereof in an animal digestive process, and separating the treated alfalfa from the liquid and gaseous ammonia and recovering the ammonia for recycling.
- 5. A process for enhancing the cellulose digestibility and protein availibility of alfalfa, said process comprising applying ammonia to the alfalfa for a time period less than about one hour at a treatment pressure in the range of about 140 psia to about 180 psia, and at ambient temperature, explosively reducing the pressure from the treatment pressure to atmospheric pressure, and separating the ammonia from the alfalfa, thereby increasing the digestibility of the cellulose in the alfalfa and increasing the availability of protein from the fibers and from within the cell walls of the alfalfa.
Specification