Adhesive compositions

• US 4,600,745 A
• Filed: 07/08/1985
• Issued: 07/15/1986
• Est. Priority Date: 06/17/1982
• Status: Expired due to Term

• Current Assignee: Evode Ltd (Rag-Stiftung)
• Original Assignee: Evode Ltd (Rag-Stiftung)
• Inventors: Creighton, Edward
• Primary Examiner(s): Lilling, Herbert J.
• Application Number:
  US06/752,014
• Time in Patent Office: 372 Days
• Field of Search: 524/534, 524/425, 524/433, 524/788, 524/856, 525/236, 528/389
• US Class Current: 524/534
• CPC Class Codes: C08K 3/06 Sulfur
• CPC Class Codes: C08L 9/00 Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
• CPC Class Codes: C09J 109/00 Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons

Abstract

An adhesive composition for filling gaps and sealing joints in engineering assembly comprises a blend of 100 parts by weight of a liquid polybutadiene polymer having an average molecular weight from 1,000 and a viscosity from 2 to 800 dPas at 25° C., at least 40 percent of the unsaturation having a 1,4 configuration, preferably cis 1,4; 5 to 60 parts of powdered sulphur; 2.5 to 70 parts of an organic accelerator or accelerators; and up to 80 percent by weight of an inert filler or fillers. The adhesive composition may also include promoters, dessicants, blowing agents and/or solid rubber, preferably solid polybutadiene.

Claims

1. An adhesive composition which is in the form of a paste and which comprises a vulcanizable component, powdered sulfur, an accelerator system and a filler system, at least about 83 percent by weight of the vulcanizable component being a liquid polybutadiene polymer specimen having an average molecular weight in the range of 1,000 to 10,000, a viscosity in the range of 2 to 800 dPas at 25°

C. and at least 40 percent of the unsaturation in the 1,4 configuration;

said vulcanizable component constituting 100 parts by weight of the composition;

said powdered sulfur constituting 5 to 60 parts by weight of the composition;

said accelerator system constituting 2.5 to 70 parts by weight of the composition; and

said filler system, which comprises at least one inert filler, constituting up to 80 percent by weight of the composition.

2. An adhesive composition as claimed in claim 1 wherein said 40 percent of the unsaturation is in the cis 1,4 configuration.

3. An adhesive composition as claimed in claim 1 wherein said liquid polybutadiene polymer specimen has at least 70 percent of the unsaturation in the cis 1,4 configuration.

4. An adhesive composition as claimed in claim 1 wherein said liquid polybutadiene polymer specimen has less than 5 percent of the unsaturation in the vinyl 1,2 configuration.

5. An adhesive composition as claimed in claim 1, wherein said vulcanizable component includes solid rubber.

6. An adhesive composition as claimed in claim 5, wherein said solid rubber constitutes about 17 percent by weight of said vulcanizable component.

7. An adhesive composition as claimed in claim 1, wherein said vulcanizable component consists of said liquid polybutadiene polymer specimen.

8. An adhesive composition as claimed in claim 5 wherein said solid rubber is solid polybutadiene.

9. An adhesive composition as claimed in claim 3, wherein said liquid polybutadiene polymer specimen has substantially all of the unsaturation in the cis 1,4 configuration.