Direct liquid phase bonding of ceramics to metals

• US 4,602,731 A
• Filed: 12/24/1984
• Issued: 07/29/1986
• Est. Priority Date: 12/24/1984
• Status: Expired due to Fees

• Current Assignee: BorgWarner Incorporated
• Original Assignee: BorgWarner Incorporated
• Inventors: Dockus, Kostas F.
• Primary Examiner(s): Ramsey, Kenneth J.
• Application Number:
  US06/685,683
• Time in Patent Office: 582 Days
• Field of Search: 228/121, 228/122, 228/124, 228/194, 228/198
• US Class Current: 228/121
• CPC Class Codes: B23K 35/001 Interlayers, transition pieces for metallurgical bonding of workpieces
• CPC Class Codes: C04B 2235/6581 Total pressure below 1 atmosphere, e.g. vacuum
• CPC Class Codes: C04B 2237/064 based on alumina or aluminates
• CPC Class Codes: C04B 2237/123 based on iron group metals, e.g. steel
• CPC Class Codes: C04B 2237/343 Alumina or aluminates
• CPC Class Codes: C04B 2237/348 Zirconia, hafnia, zirconates or hafnates
• CPC Class Codes: C04B 2237/36 Non-oxidic
• CPC Class Codes: C04B 2237/365 Silicon carbide
• CPC Class Codes: C04B 2237/368 Silicon nitride
• CPC Class Codes: C04B 2237/38 Fiber or whisker reinforced
• CPC Class Codes: C04B 2237/402 Aluminium
• CPC Class Codes: C04B 2237/406 Iron, e.g. steel
• CPC Class Codes: C04B 2237/52 Pre-treatment of the joining surfaces, e.g. cleaning, machining
• CPC Class Codes: C04B 2237/704 of one or more of the ceramic layers or articles
• CPC Class Codes: C04B 2237/72 Forming laminates or joined articles comprising at least two interlayers directly next to each other
• CPC Class Codes: C04B 2237/86 Joining of two substrates at their largest surfaces, one surface being complete joined and covered, the other surface not, e.g. a small plate joined at it's largest surface on top of a larger plate
• CPC Class Codes: C04B 37/005 consisting of glass or ceramic material
• CPC Class Codes: C04B 37/006 consisting of metals or metal salts
• CPC Class Codes: C04B 37/025 consisting of glass or ceramic material
• CPC Class Codes: C04B 37/026 consisting of metals or metal salts

Abstract

The direct liquid phase bonding of ceramics to metals or other ceramics in an inert atmosphere without prior metallization wherein a nickel-plated aluminum-silicon brazing alloy or aluminum or aluminum alloy filler material between the ceramic and metal layers provides a joint of high strength at a low bonding temperature without affecting the ceramic microstructure or the mechanical properties of the materials. This technique is also useful for fabricating composite laminates.

Claims

1. A method of bonding at least two material layers together, at least one layer being a ceramic, comprising the steps of cleaning the surfaces of the layers to be bonded, plating a brazing alloy sheet with nickel, nickel-lead or cobalt-lead, sandwiching the plated brazing alloy between the material layers to be bonded, heating the material layers and brazing alloy to a temperature in the range of 1100°

to 1200°

F. for a time period of three to five minutes in an inert atmosphere or vacuum, and cooling the bonded article.

2. A method of bonding as set forth in claim 1, wherein one of said layers is a ceramic material and the other layer is a metal.

3. A method of bonding as set forth in claim 2, in which said metallic layer is selected from the group consisting of cast iron, steel, stainless steel, aluminum, titanium and an alloy of iron, nickel and cobalt.

4. A method of bonding as set forth in claim 3, wherein said metallic layer is plated with a thin film of nickel, nickel-lead or cobalt-lead.

5. A method of bonding as set forth in claim 1, in which both of said layers are ceramic materials.

6. A method of bonding as set forth in claim 5, in which the ceramic materials of the two layers are identical.

7. A method of bonding as set forth in claim 1, wherein said ceramic layer is selected from the group consisting of zirconia, alumina, tungsten carbide, silicon carbide and silicon nitride.

8. A method of bonding as set forth in claim 7, wherein said ceramic layer is plated with a thin film of nickel, nickel-lead or cobalt-lead.

9. A method of bonding as set forth in claim 1, in which said heating step is carried out in a vacuum.

10. A method of bonding as set forth in claim 1, in which said inert atmosphere is selected from the group consisting of nitrogen, argon and helium.

11. A method of bonding as set forth in claim 1, in which said heating step includes a preheating stage in a furnace to raise the layers to 500°

F., a high temperature stage in the range of 1100°

to 1200°

F., and a low temperature stage allowing the article to cool to 500°

F. before removing from the furnace.

12. A method of bonding as set forth in claim 1, in which a layer of alumina or Kovar is interposed between the metal and ceramic layers when the metal and ceramic layers have a substantial difference in the coefficients of expansion.

13. A method of bonding as set forth in claim 12, in which a sheet of a brazing alloy or aluminum filler material is interposed between all three layers.