Polypropylene sheet

• US 4,604,441 A
• Filed: 03/20/1985
• Issued: 08/05/1986
• Est. Priority Date: 03/29/1984
• Status: Expired due to Term

• Current Assignee: Kuraray Company Limited
• Original Assignee: Kuraray Company Limited
• Inventors: Narukawa, Hiroshi, Ueeda, Ryuhei, Fujii, Kiyonobu
• Primary Examiner(s): Michl, Paul R.
• Application Number:
  US06/713,829
• Time in Patent Office: 503 Days
• Field of Search: 526/351
• US Class Current: 526/351
• CPC Class Codes: B29C 55/02 of plates or sheets
• CPC Class Codes: C08J 2323/10 Homopolymers or copolymers of propene
• CPC Class Codes: C08J 5/18 Manufacture of films or sheets

Abstract

Polypropylene sheets of high impact resistance at low temperature and of improved formability characterized by specific parameters are described. Such polypropylene sheets are produced by spreading under pressure polypropylene sheets at a temperature within a very narrow range in the vicinity of the melting point of the propylene-based polymer.

Claims

1. A polypropylene sheet having a thickness of at least 200 μ

m characterized in (a) that the base material is a propylene-based polymer having a melt flow rate of not more than 5 and a propylene unit content of not less than 70% by weight, (b) that the maximum value (Ftmax) among the values (Ft'"'"'s) of integration of the force parallel to the sheet plane, as appearing upon heating said sheet at a temperature above the melting point thereof over the time period during which said force is observed, falls within the range of 0.5-45 kg.minute/cm², (c) that the ratio (RFt) between Ft'"'"'s measured in directions at right angles to each other on the sheet plane is not more than 10, and (d) that the melting point (Tms) of said sheet is higher than the melting point (Tmr) of said sheet as measured after melting followed by recrystallization in the unstrained condition, the melting point difference (Δ

Tms=Tms-Tmr) being at least 3°

C.

2. The sheet of claim 1, wherein the propylene-based polymer constituting said sheet has a crystallinity of at least 65% and wherein the orientation function (fc) is not more than 0.4.

3. The sheet of claim 2, wherein the average notched izod impact strength of said sheet at 0°

C. is at least 50 kg.cm/cm.

4. The sheet of claim 3, wherein the average notched izod impact strength of said sheet at -30°

C. is at least 30 kg.cm/cm.

5. The sheet of claim 4, wherein the dimensional change in sheet thickness as measured at 120°

C. is not more than 5%.

6. The sheet of claim 5, wherein the ratio (RIzo) between notched izod impact strength values measured at 0°

C. in directions at right angles to each other on the sheet plane is not more than 3.

7. The sheet of claim 1, wherein the maximum value (Ftmax) among the values (Ft'"'"'s) of integration of the force parallel to the sheet plane as appearing upon heating said sheet at a temperature above the melting point thereof over the time period during which said force is observed falls within the range of 1-20 kg.minute/cm².

8. A polypropylene sheet having a thickness of at least 200 μ

m characterized in that the base material is a propylene-based polymer having a melt flow rate of not more than 5 and a propylene unit content of not less than 70% by weight, that the average notched Izod impact strength of said sheet at 0°

C. is at least 50 kg.cm/cm, and that the average notched Izod impact strength at -30°

C. is at least 30 kg·

cm/cm.

9. The sheet of claim 8, wherein the propylene-based polymer constituting said sheet has a crystallinity of at least 65% and wherein the orientation function (fc) is not more than 0.4.

10. The sheet of claim 8, wherein the ratio (RIzo) between notched izod impact strength values measured at 0°

C. in directions at right angles to each other on the sheet plane is not more than 3.

11. The sheet of claim 10, wherein the percentage increase in sheet thickness as found upon heating said sheet to 120°

C. is not more than 5%.

12. The sheet of claim 11, wherein the maximum value (Ftmax) among the values (Ft'"'"'s) of integration of the force parallel to the sheet plane as appearing upon heating said sheet at a temperature above the melting point thereof over the time period during which said force is observed falls within the range of 0.5-45 kg.minute/cm² and wherein the ratio (RFt) between Ft'"'"'s measured in directions at right angles to each other on the sheet plane is not more than 10.

13. The sheet of claim 12, wherein the maximum value (Ftmax) among the values (Ft'"'"'s) of integration of the force parallel to the sheet plane as appearing upon heating said sheet at a temperature above the melting point thereof over the time period during which said force is observed falls within the range of 1-20 kg·

minute/cm².

14. A polypropylene sheet having a thickness of at least 200 μ

m having a base material which is a propylene-based polymer having a melt flow rate of not less than 5 and a propylene unit content of not less than 70% by weight, characterized in that said sheet is a product of pressure-spreading of said polymer in the vicinity of the melting point thereof, that the average notched Izod impact strength of said sheet at 0°

C. is at least 50 kg·

cm/cm, and that the average notched Izod impact strength at -30°

C. is at least 30 kg.cm/cm.

15. The sheet of claim 14, wherein the propylene-based polymer constituting said sheet has a crystallinity of at least 65% and wherein the orientation function (fc) is not more than 0.4.

16. The sheet of claim 15, wherein the ratio (RIzo) between notched izod impact strength values measured at 0°

C. in directions at right angles to each other on the sheet plane is not more than 3.

17. The sheet of claim 16, wherein the dimensional change in sheet thickness as measured at 120°

C. is not more than 5%.

18. The sheet of claim 17, wherein the maximum value (Ftmax) among the values (Ft'"'"'s) of integration of the force parallel to the sheet plane as appearing upon heating said sheet at a temperature above the melting point thereof over the time period during which said force is observed falls within the range of 0.5-45 kg.minute/cm² and wherein the ratio (RFt) between Rt'"'"'s measured in directions at right angles to each other on the sheet plane is not more than 10.

19. The sheet of claim 19, wherein the maximum value (Ftmax) among the values (Ft'"'"'s) of integration of the force parallel to the sheet plane as appearing upon heating said sheet at a temperature above the melting point thereof over the time period during which said force is observed is within the range of 1-20 kg·

minute/cm².