Rubber-metal adhesion promoters

• US 4,605,693 A
• Filed: 01/24/1985
• Issued: 08/12/1986
• Est. Priority Date: 02/27/1984
• Status: Expired due to Term

• Current Assignee: Goodyear Tire & Rubber Company
• Original Assignee: Goodyear Tire & Rubber Company
• Inventors: Mowdood, Syed K.
• Primary Examiner(s): Schofer, Joseph L.
• Assistant Examiner(s): Sarofim, N.
• Application Number:
  US06/694,380
• Time in Patent Office: 565 Days
• Field of Search: 524/239, 524/534, 524/535, 152/565, 156/124, 156/910, 428/295
• US Class Current: 524/239
• CPC Class Codes: C08F 230/02 containing phosphorus
• CPC Class Codes: C08F 279/02 on to polymers of conjugated dienes
• CPC Class Codes: C08J 2321/00 Characterised by the use of unspecified rubbers
• CPC Class Codes: C08J 5/10 characterised by the additives used in the polymer mixture
• CPC Class Codes: C08K 5/17 Amines; Quaternary ammonium compounds
• CPC Class Codes: C08K 5/3437 condensed with carbocyclic rings
• CPC Class Codes: C08K 5/521 Esters of phosphoric acids, e.g. of H3PO4
• CPC Class Codes: C08K 5/524 Esters of phosphorous acids, e.g. of H3PO3
• CPC Class Codes: C08L 21/00 Compositions of unspecified rubbers
• CPC Class Codes: Y10S 156/91 Bonding tire cord and elastomer: improved adhesive system

Abstract

Good adhesion of rubber to metal is very important in rubber articles containing metal reinforcement. For example, in a steel belted tire good adhesion between the tire rubber and the metal tire cord is of utmost importance. Good metal to rubber adhesion is also of great importance in a variety of other rubber products, including power transmission belts, conveyor belts, and rubber hoses containing metal reinforcements. This invention reveals the use of certain adhesion promoters that are useful in rubber products containing metal reinforcements. More specifically, this invention discloses the use of allyl phosphite esters, allyl phosphate esters, 5-nitro isatoic anhydride, iminodiacetic acids, N-substituted iminodiacetic acids, salts of N-substituted iminodiacetic acids, and salts of iminodiacetic acids as adhesion promoters in composites containing rubber and metal.

Claims

1. A composite comprising a rubber composition with a metal reinforcing element embedded therein, wherein said rubber composition contains from about 0.05 to about 10 parts per hundred parts of rubber by weight of at least one adhesion promoter selected from the group consisting of iminodiacetic acids, N-substituted iminodiacetic acids, salts of N-substituted iminodiacetic acids, and salts of iminodiacetic acids.

2. A composite as specified in claim 1 wherein said metal reinforcing element is a brass plated carbon steel.

3. A composite as specified in claim 2 wherein said rubber composition contains from 0.1 to 5 parts of said adhesion promoter per hundred parts of rubber by weight.

4. A composite as specified in claim 2 wherein said rubber composition contains from 0.5 to 2 parts of said adhesion promoter per hundred parts of rubber by weight.

5. A composite as specified in claim 1 wherein said rubber composition contains from 0.1 to 5 parts of said adhesion promoter per hundred parts of rubber by weight.

6. A composite as specified in claim 5 wherein said adhesion promoter has the structural formula:

##STR7## wherein n is an integer from 1 to 10 inclusive.

7. A composite as specified in claim 5 wherein said adhesion promoter is a member selected from the group consisting of ethylene diamine tetraacetic acid, iminodiacetic acid, oleoyl iminodiacetic acid, lauroyl iminodiacetic acid, nitrilotriacetic acid, diethylene triamine pentaacetic acid, the trisodium salt of iminodiacetic acid, the disodium salt of ethylene diamine tetraacetic acid, and the trisodium salt of n-hydroxyethyl ethylene diamine triacetic acid.

8. A composite as specified in claim 7 wherein said rubber composition contains from 0.5 to 2 parts of said adhesion promoter per hundred parts of rubber by weight.

9. A composite as specified in claim 8 wherein said composite is in the form of a tire.

10. A composite as specified in claim 3 wherein said rubber is at least one member selected from the group consisting of natural rubber, styrene-butadiene rubber, synthetic polyisoprene, polychloroprene, cyclene rubbers, polybutadiene, nitrile rubbers, carboxylated nitrile rubbers, butyl rubbers, isoprene/styrene copolymers, halogenated butyl rubbers, EPDM rubbers, EPR rubbers, polyisobutylene, norbornene rubbers, and thiokol rubbers.

11. A composite as specified in claim 3 wherein said rubber is at least one member selected from the group consisting of natural rubber and synthetic polyisoprene.

12. A composite as specified in claim 3 wherein said composite is in the form of a tire.

13. A composite as specified in claim 3 wherein said composite is in the form of a belt.