Permanent gas refrigeration method

• US 4,608,067 A
• Filed: 08/02/1984
• Issued: 08/26/1986
• Est. Priority Date: 08/04/1983
• Status: Expired due to Term

• Current Assignee: BOC Group BV (Linde Plc)
• Original Assignee: BOC Group BV (Linde Plc)
• Inventors: Marshall, John
• Primary Examiner(s): NOT, DEFINED
• Assistant Examiner(s): Anderson, Andrew J.
• Application Number:
  US06/636,954
• Time in Patent Office: 754 Days
• Field of Search: 62/9, 62/38, 62/40, 62/36
• US Class Current: 62/613
• CPC Class Codes: F25J 1/0005 Light or noble gases F25J1/0012 takes precedence
• CPC Class Codes: F25J 1/0015 Nitrogen
• CPC Class Codes: F25J 1/0017 Oxygen
• CPC Class Codes: F25J 1/002 Argon
• CPC Class Codes: F25J 1/0022 Hydrocarbons, e.g. natural gas
• CPC Class Codes: F25J 1/0027 Oxides of carbon, e.g. CO2
• CPC Class Codes: F25J 1/0037 of a return stream
• CPC Class Codes: F25J 1/0208 in combination with an internal quasi-closed refrigeration loop, e.g. with deep flash recycle loop F25J1/021 takes precedence
• CPC Class Codes: F25J 1/0288 using work extraction by mechanical coupling of compression and expansion of the refrigerant, so-called companders
• CPC Class Codes: F25J 2215/32 Neon
• CPC Class Codes: F25J 2215/62 Ethane or ethylene
• CPC Class Codes: F25J 2245/02 Recycle of a stream in general, e.g. a by-pass stream
• CPC Class Codes: F25J 2270/06 with multiple gas expansion loops
• CPC Class Codes: F25J 2270/90 External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration

Abstract

In cooling a permanent gas stream (e.g. of nitrogen) at elevated pressure to below its critical temperature (e.g. in a process for the liquefaction of the permanent gas), the stream is heat exchanged with a main stream of working fluid (typically also nitrogen) that has been work-expanded in expansion turbine. The refrigeration provided by this stream is supplemented by that provided by at least two supplementary streams of work expanded working fluid. The temperatures at which the supplementary streams are introduced into heat exchange relationship with the permanent gas stream are in a defined range extending from 5° K. above the point at which the rate of change of the heat capacity (at constant pressure) of the gas per standard cubic meter increases by about 1% per Kelvin as the gas is cooled to 5° K. below the point at which the rate of change with temperature of the heat capacity (at constant pressure) of the gas per standard cubic meter is at a maximum.

Claims

1. A method of refrigerating a permanent gas by heat exchanging a stream of said gas at a relatively high pressure with a main stream of work-expanded working fluid flowing counter to said high pressure stream, and thereby reducing the temperature of said high pressure stream to its critical temperature or a temperature therebelow, wherein the said main stream is supplemented by at least two work-expanded streams of working fluid introduced into heat exchange the permanent gas stream on the gaseous transitional section of relationship with the permanent gas stream at temperatures of the temperature-enthalpy curve of the permanent gas stream or within 5°

K. beyond either end of such section, but with no work expanded stream of working fluid other than said main work expanded stream being used to refrigerate the permanent gas stream at its temperature more than 5°

K. below the lower limit of the gaseous transitional section whereby the temperature of the working fluid as it is heated is more closely matched to that of the permanent gas stream as it is cooled along the said gaseous transitional section.

2. A method as claimed in claim 1, in which at least one of the said supplementary streams of working fluid is introduced into heat exchange relationship with the permanent gas stream at a temperature of the permanent gas stream within plus or minus 5°

K. of the lower limit of the gaseous transitional section.

3. A method as claimed in claim 2, in which at least one of the said supplementary streams of working fluid is introduced into heat exchange relationship with the permanent gas stream at a temperature of the permanent gas stream within plus or minus 2°

K. of the lower limit of the gaseous transitional section.

4. A method as claimed in claim 1, in which just three or four work-expanded working fluid streams are employed, one being the said main stream.

5. A method as claimed in claim 4, in which four work-expanded working fluid streams are employed, three being introduced into heat exchange relationship with the permanent gas stream at temperatures of the permanent gas stream on the said gaseous transitional section or within 5°

K. beyond either limit of that section.

6. A method as claimed in claim 1, in which at least one of the supplementary working fluid streams is introduced into the main working fluid stream and returned to the warm end of the heat exchange system with the main working fluid stream.

7. A method as claimed in claim 6, in which some or all of the supplementary working fluid streams each flow through a circuit in which working fluid is compressed, cooled in the heat exchange means, work-expanded, reheated in the heat exchange means and returned to the compressor.

8. A method as claimed in claim 7, in which one of the supplementary working fluid streams is withdrawn from the heat exchange means at an intermediate location and is work expanded to a lower pressure to form another supplementary working fluid stream.

9. A method as claimed in claim 1, in which each working fluid is taken from permanent gas to be liquefied.

10. A method as claimed in claim 1, in which after the permanent gas has been cooled to its critical temperature or a temperature therebelow, the resultant liquefied permanent gas stream is passed through one or two expansion valves to form a liquid product at a storage pressure and flash gas.

11. A method as claimed in claim 10, in which the flash gas is heat exchanged countercurrently with the permanent gas stream.