Membrane remover/etchant

• US 4,608,086 A
• Filed: 08/27/1984
• Issued: 08/26/1986
• Est. Priority Date: 01/19/1983
• Status: Expired due to Fees

• Current Assignee: Tennant Company
• Original Assignee: Tennant Company
• Inventors: Dodge, Paul D.
• Primary Examiner(s): Morris, Theodore
• Application Number:
  US06/644,856
• Time in Patent Office: 729 Days
• Field of Search: 252/142, 252/143, 106/12, 106/311, 427/136
• US Class Current: 106/12
• CPC Class Codes: C04B 41/5353 Wet etching, e.g. with etchants dissolved in organic solvents
• CPC Class Codes: C04B 41/72 involving the removal of part of the materials of the treated articles, e.g. etching

Abstract

The present invention relates to a membrane remover/etchant solution including an organic solvent, a strong ionizable acid, a weak acid and an acid stable surfactant. The present invention further includes a method for removing a membrane and etching a concrete surface in which the membrane remover/etchant solution is in an organic solvent system and is applied to the concrete in an inactive acid form and then water is applied to activate the acid. The resulting materials are then picked up and the surface is rinsed with water.

Claims

1. A precoating membrane remover/etchant composition for treating concrete covered with a thin moistureproof organic membrane, first to dissolve the membrane and, after dissolving the membrane, to etch the concrete provided an etching acid in said solution is activated for the concrete etching role, said composition comprising by weight (a) from 1 to 10 parts organic solvent, and 30 to 50 parts a co-solvent therefor, for dissolving the membrane, and said co-solvent also serving the role of a strong acid inhibitor;

(b) 5 to 20 parts concentrated weak carboxylic organic acid and 20 to 30 parts concentrated strong mineral acid together with a water content which is insufficient in combination with said solvents to allow substantial ionization of the acid to the effective concrete etching state;

said weak acid along with said co-solvent also serving the role of inhibitor for the strong acid; and

said solution further comprising (c) a surfactant to induce uniform wetting of the solution when applied to the membrane;

said solution being capable of dissolving an organic membrane on a concrete slab, whereafter by adding additional water to said solution the acids become activated effectively to etch the exposed concrete.

2. The solution of claim 1 wherein said water content is 20% or lower.

3. The solution of claim 1 wherein said water content is about 13%.

4. The solution of claim 1 wherein said strong acid is a member selected from the group consisting of hydrochloric acid, sulfuric acid, nitric acid, and sulfurous acid.

5. The etchant of claim 1 wherein said weak organic acid is hydroxyacetic acid.

6. The etchant of claim 2 wherein said weak organic acid is hydroxyacetic acid.

13. Composition according to claim 1 wherein the strong acid is a mineral acid including hydrochloric acid, wherein the weak acid is hydroxy acetic acid, and wherein the solvent remover includes a hydrocarbon solvent of KB value at least 89.

15. Composition according to claim 1 in which the first-named solvent comprises methylene chloride, ethylene dichloride, trichloroethylene, propylene, dichloride, perchloroethylene, o-dichlorobenzene, benzene, toluene, or xylene and, as co-solvent therewith, butoxyethanol, isobutyl alcohol, octyl alcohol, isopropyl alcohol, methyl alcohol, carbitol, or di-propylene methyl ether;

in which the strong acid comprises hydrochloric acid, sulfuric acid, sulfurous acid, or nitric acid; and

in which the weak acid comprises hydroxyacetic acid, oxalic acid, acetic acid, dichloroacetic acid or sulfonic acid.

7. A precoating membrane remover/etchant concentrate for treating a concrete surface first to remove an organic membrane thereon and then to etch the concrete, said concentrate consisting essentially in parts by weight of from 1 to 10 parts methylene chloride and 30 to 50 parts butoxyethanol to remove the membrane;

1 to 5 parts acid stable surfactant to assure uniform distribution of the concentrate and wetting of the surface;

5 to 20 parts hydroxyacetic acid and 20 to 30 parts strong acid, said strong acid being a member selected from the group consisting of hydrochloric acid, sulfuric acid, nitric acid, and sulfurous acid, said hydroxyacetic acid being a weak acid which inhibits ionization of the strong acid until sufficient water is added to activate the acid to its concrete etching role.

8. The concentrate of claim 7 wherein an equal amount of an aromatic solvent having a KB value of at least 89 is combined.

9. The concentrate of claim 7 wherein said hydroxyacetic acid is present in an amount of 15 parts and said hydrochloric acid is present in an amount of 27 parts, by weight.

10. The etchant concentrate of claim 7 wherein said detergent is nonionic and is present in an amount of 3 parts, by weight.

11. The concentrate of claim 7 wherein said methylene chloride is present in an amount of 10 parts by weight.

12. The etchant concentrate of claim 7 wherein said methylene chloride is 10 parts, said butoxyethanol is 45 parts, said detergent is 3 parts, said hydroxyacetic acid is 15 parts and said hydrochloric acid is 27 parts, by weight.

14. The etchant concentrate of claim 7 including by weight 10 parts methylene chloride, 15 parts 2-butoxyethanol, 6 parts nonionic surfactant, 15 parts hydroxyacetic acid and 25 parts hydrogen chloride.

16. A composition to remove thin membrane film material applied to freshly poured concrete to effect moisture retention and optimize the cure of the concrete, and at the same time to prepare the concrete for subsequent application of a finish coating by acid etching the concrete surface in a one-step continuous process, said composition comprised of three component parts (A, B, C),

Part A:

(1) from 1-10 parts by weight of chlorinated liquid hydrocarbon solvent selected from the group consisting of methylene chloride, ethylene dichloride, trichloroethylene, propylene dichloride, perchloroethylene, and ortho dichlorobenzene;

(2) from 6-40 parts by weight of a concentrated inorganic acid selected from the group consisting of hydrochloric, sulfuric, nitric, sulfurous, phosphoric, and sulfonic acids;

(3) from 10-48 parts by weight of a concentrated water soluble carboxylic aacid having 2-6 carbon atoms and selected from the group consisting of hydroxyacetic, acetic, and citric acids;

(4) from 8-45 parts by weight of a cosolvent selected from the group consisting of mono and dialkyl ethers of diethylene and propylene glycol and their derivatives and lower alcohols up to C-8;

(5) from 1-5 parts by weight of a wetting agent;

Part B;

from 10-100 parts of an aromatic hydrocarbon solvent with a KB value at least 89;

Part C;

from 13-100 parts water, wherein when said parts A and B are applied to said surface, said solvents loosen and dissolve said membrane film, and subsequently, the part C addition of water activates said acids to etch the said concrete surface and ready it for application of the finish coating.

17. The composition of claim 16 wherein the chlorinated liquid hydrocarbon solvent is methylene chloride, the inorganic acid is hydrochloric acid, and the carboxylic acid is hydroxyacetic acid.

18. The composition of claim 16 consisting essentially of:

Part A;

(1) from 1-10 parts by weight of methylene chloride;

(2) from 6-40 parts by weight of hydrochloric acid;

(3) from 10-48 parts by weight of hydroxyacetic acid;

(4) from 8-45 parts by weight of 2-butoxyethanol;

Part B;

from 10-100 parts by weight of aromatic hydrocarbon C-8 or higher solvent;

Part C;

from13-100 parts water.

19. The composition of claim 16 consisting essentially of:

Part A;

(1) from 1-10 parts by weight of methylene chloride;

(2) from 10-30 parts by weight of hydrochloric acid;

(3) from 10-20 parts by weight of hydroxyacetic acid;

(4) from 30-45 parts by weight of 2-butoxyethanol;

Part B;

from 60-100 parts by weight of aromatic hydrocarbon C-8 or higher solvent;

Part C;

from 13-100 parts water.

20. The composition of claim 16 in which subdivision (5) of Part A is 1-5 parts by weight of a wetting agent selected from the group consisting of a nonylphenol with 4-14 moles of ethylene oxide adducts, a polyethylene glycol ether with 4-15 moles of ethylene glycol adducts;

polyethoxylated straight chain alcohols, isopropylomine dodecylbenzene sulfonate, an ethoxylate of chain length 4-18 carbon atoms, cycloaliphatic C-21 dicarboxylic acids, straight chain dodecylbenzene and free acid complex organic phosphate ethers.

21. The composition of claim 19 in which the wetting agent of PART A includes from 1-2 parts by weight of a mixture of nonylphenol with 6 moles of ethylene oxide adduct and from 1-3 parts by weight of nonylphenol with 4 moles of ethylene oxide adduct.

22. A coating remover/etchant concentrate for removing an organic coating, such as a chlorinated rubber membrane, from a concrete surface and for subsequently etching the concrete surface, said concentrate consisting essentially of a sufficient amount of an organic solvent to disintegrate the coating and a mineral concentrated strong acid combined with a weak carboxylic organic acid by which the strong acid is inhibited against ionization, insufficient water in the concentrate to activate the acids, but said acids being capable of being activated by the addition of water, and said acids being present in an amount sufficient, when activated, to etch the concrete surface.