Galvanic cells having ion exchange resin in their cathode mix

• US 4,608,279 A
• Filed: 12/27/1984
• Issued: 08/26/1986
• Est. Priority Date: 12/27/1984
• Status: Expired due to Fees

• Current Assignee: Eveready Battery Company Incorporated (Energizer Holdings, Inc.)
• Original Assignee: Union Carbide Corporation (Dow, Inc.)
• Inventors: Schumm, Brooke Jr.
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US06/686,750
• Time in Patent Office: 607 Days
• Field of Search: 429/224, 429/209, 429/212, 429/215, 429/216, 429/232, 429/229
• US Class Current: 429/224
• CPC Class Codes: H01M 4/06 Electrodes for primary cells
• CPC Class Codes: H01M 4/62 Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
• CPC Class Codes: H01M 6/06 Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid

Abstract

Galvanic cells of the Leclanche and zinc chloride type which employ cathode mixes having relatively high ratios of EMD to conductive material and which include a minor amount of ion exchange resin in their cathode mixes exhibit enhanced light drain service and comparable heavy drain service relative to conventional cells having lower EMD to conductive material ratios.

Claims

1. A galvanic cell comprising

an anode;

an acidic electrolyte; and

a wet cathode mix comprising electrolytic manganese dioxide and a conductive material in a ratio of greater than about 7;

1 by weight, and an ion exchange resin in an amount between about 0.5 and 4.0 weight percent of said wet cathode mix.

2. The galvanic cell of claim 1 wherein the ion exchange resin comprises between about 0.5 and about 1.0 weight percent of the wet cathode mix.

3. The galvanic cell of claim 1 wherein said cell is a Leclanche cell.

4. The cell of claim 1 wherein said ion exchange resin is an acid ion exchange resin.

5. The cell of claim 1 wherein said ion exchange resin is a base ion exchange resin.

6. The cell of claim 1 wherein said ion exchange resin is a macroreticular resin.

7. The cell of claim 1 wherein said ion exchange resin is a coarse powder, about 90 weight percent of which will pass through a 20 Tyler mesh screen.

8. The galvanic cell of claim 1 wherein the conductive material is at least one material selected from the group consisting of carbon black, acetylene black, and graphite.

9. The galvanic cell of claim 1 wherein the anode is composed of zinc.

10. The galvanic cell of claim 1 wherein the wet cathode mix additionally includes a surfactant.

11. The galvanic cell of claim 1 wherein the wet cathode mix additionally includes gum karaya.