Synthetic resin lens and antireflection coating

• US 4,609,267 A
• Filed: 12/22/1981
• Issued: 09/02/1986
• Est. Priority Date: 12/22/1980
• Status: Expired due to Term

• Current Assignee: Kabushiki Kaishi KOBE Seiko SHO, Matsushima Kogyo Kabushiki Kaisha
• Original Assignee: Seiko Epson Corporation (Seiko Group)
• Inventors: Kojima, Kenji, Mogami, Takao, Deguchi, Hirokazu
• Primary Examiner(s): Corbin, John K.
• Assistant Examiner(s): Sugarman, Scott J.
• Application Number:
  US06/333,519
• Time in Patent Office: 1,715 Days
• Field of Search: 350/164-166, 350/1.6, 350/1.7, 351/163, 351/166, 351/177, 427/294
• US Class Current: 351/163
• CPC Class Codes: G02B 1/115 Multilayers
• CPC Class Codes: G02C 2202/16 Laminated or compound lenses
• CPC Class Codes: G02C 7/108 Colouring materials

Abstract

A synthetic resin lens having a refractive index of at least 1.55 and an antireflection coating thereon is provided. The antireflection coating includes at least a hard coat layer formed of a dielectric substance having a refractive index n_h disposed on the lens having a refractive index n_s (n_s ≠n_h) and at least one antireflection layer of a dielectric or metallic material disposed between the lens and the hard coat layer. The antireflection layer has a refractive index n in the range represented by the formula: ##EQU1## and an optical film thickness of 4 (where denotes a wavelength in the range between about 450 nm to 650 nm) or two or more plies optically equivalent to a single layer of the antireflection material. The synthetic resin lens may be prepared by radical polmerization of a mixed monomer solution of styrene, 2,2-bis[3,5-dibromo-4-(2-methacryloloxyethoxy)phenyl]propane, and ultraviolet absorber and a light stabilizer. Such synthetic resin lenses generally have a refractive index of about 1.6 and a surface hardening layer usually SiO₂ has a refractive index of about 1.46. It is desirable to provide an antireflection layer having a refractive index of about 1.52 which may be provided by a first layer of silicon dioxide and another layer of an oxide selected from the group of oxides of ZrO₂, HfO₂, Ti₂ O₃ TiO₂, Ta₂ O₅, Si₃ N₄, Yb₂ O₃, Y₂ O₃ or Al₂ O₃. An outer antireflection layer is then disposed on the outer surface of the surface hardening layer.

Claims

1. A synthetic resin lens construction having a high refractive index and improved antireflective and mar resistant properties, comprising:

(1) a lens body formed of a cross-linked synthetic resin and having a refractive index n_s of at least 1.55;

(2) a dielectric substance for use as an antireflective layer having a refractive index n within the range represented by the formula;

##EQU7## and has an optical film thickness of λ

/4, wherein λ

denotes a wavelength in the range of from about 450 nm to 650 nm disposed on the surface of the lens body, and

(3) a hard coat layer of about 1 to 6 μ

m thick having a refractive index n_h disposed on the antireflective layer.

2. The synthetic resin lens construction of claim 1, wherein the first antireflective layer is a layer of two or more plies optically equivalent to said first antireflective layer.

3. The synthetic resin lens construction of claim 1 or 2, further including an outer antireflective layer disposed on the outer surface of the hard coat layer.

4. The synthetic resin lens construction of claim 3, wherein the outer antireflective layer has a refractive index suitable for a lens having a refractive index substantially equal to the refractive index of the hard coat layer.

5. The synthetic resin lens construction of claim 4, wherein the outer antireflective layer is of a three ply construction including a first ply of a material selected from the group consisting of ZrO₂, HfO₂, Ti₂ O₃, TiO₂, Ta₂ O₅, Y₂ O₃, Yb₂ O₃ or Si₃ N₄ disposed on said hard coat layer, a second ply of material selected from the group consisting of ZrO₂, HfO₂, Ti₂ O₃, TiO₂, Ta₂ O₅ or Si₃ N₄ disposed on said first ply, and a third ply of SiO₂ disposed on said second ply.

6. The synthetic resin lens construction of claim 5, wherein the outer antireflective layer is of a first ply of Yb₂ O₃, a second ply of ZrO₂ dispersed thereon and the third ply of SiO₂.

7. The synthetic resin lens construction of claim 1, wherein the lens body is formed by radical polymerization of a mixed monomer solution of from about 30 to 50 parts by weight of styrene, 40 to 70 parts by weight of 2,2-bis[3,5-dibromo-4-(2-methacryloyloxyethoxy)phenyl]propane, 0.01 to 2.0 parts by weight of an ultraviolet light absorber, and 0.01 to 2.0 parts by weight of a light stabilizer.

8. The synthetic resin lens construction of claim 7, wherein

(a) the first interposed antireflective layer on the lens body surface includes (i) a first ply of SiO₂ having an optical thickness of 0.05 to 0.15λ

₀, wherein λ

₀ is a wavelength of from 400 to 700 nm and (ii) a second ply having an optical thickness of 0.01 to 0.15λ

₀ disposed on said first ply and selected from the group consisting of ZrO₂, HfO₂, Ti₂ O₃, TiO₂, Ta₂ O₅, Y₂ O₃, Si₃ N₄ or Al₂ O₃ ;

(b) the hard coat layer disposed on the antireflective layer having a thickness of from 1 to 6 μ

m and being SiO₂ ; and

(c) an outer antireflective layer disposed on the hard coat layer, including;

(i) a fourth ply having an optical thickness of from 0.007 to 0.25λ

₀, and of a material selected from the group consisting of ZrO₂, HfO₂, Ti₂ O₃, TiO₂, Ta₂ O₅, Y₂ O₃, Yb₂ O₃ or Si₂ N₂₁ ;

(ii) a fifth ply disposed on the fourth ply having an optical thickness of 0.02 to 0.15λ

₀ and being SiO₂ ;

(iii) a sixth ply disposed on the fifth ply having an optical thickness of 0.20 to 0.50λ

₀ and being a material selected from the group consisting of ZrO₂, HfO₂, Ti₂ O₃, TiO₂, Ta₂ O₅ or Si₃ N₄ ; and

(iv) a seventh ply disposed on the sixth ply having an optical thickness of from 0.20 to 0.30λ

₀ and being of SiO₂.

9. A process of preparing a synthetic resin lens construction having a high refractive index and improved antireflective and mar resistant properties, comprising:

forming a lens body of a cross-linked synthetic resin for forming a lens body having a refractive index n_s of at least 1.55;

depositing an antireflection coating on the surface of the lens body by first depositing an interposed antireflective layer having a refractive index n within the range represented by the formula;

##EQU8## to an optical film thickness of λ

/4, wherein λ

denotes a wavelength in the range of from 450 nm to 650 nm on the surface of the lens body and depositing a hard coat layer of a dielectric substance having a refractive index n_h on the surface of the antireflective layer.

10. The process of preparing a synthetic lens construction of claim 9, including the step of forming the lens body by radical polymerization of a mixed monomer solution of from about 30 to 50 parts by weight of styrene, 40 to 70 parts by weight of 2,2-bis[3,5-dibromo-4-(2-methacryloyloxyethoxy)phenyl]propane, 0.01 to 2.0 parts by weight of an ultraviolet light absorber, and 0.01 to 2.0 parts by weight of a light stabilizer.

11. The process of preparing a synthetic lens construction of claims 9 or 10, further including a step of depositing an outer antireflection layer on the outer surface of the hard coat layer.

12. The process of preparing a synthetic resin lens construction of claim 11, wherein the antireflection layers are formed by vacuum deposition.