Transversely reinforced piezoelectric composites

• US 4,613,784 A
• Filed: 12/21/1984
• Issued: 09/23/1986
• Est. Priority Date: 12/21/1984
• Status: Expired due to Fees

• Current Assignee: the united states of america as represented by the secretary of the navy
• Original Assignee: the united states of america as represented by the secretary of the navy
• Inventors: Haun, Michael J., Newnham, Robert E., Schulze, Walter A.
• Primary Examiner(s): Bell, James J.
• Application Number:
  US06/684,529
• Time in Patent Office: 641 Days
• Field of Search: 428/221, 428/113, 428/413, 428/417, 428/423.1, 310/358, 310/357, 310/359
• US Class Current: 310/358
• CPC Class Codes: H10N 30/852 Composite materials, e.g. having 1-3 or 2-2 type connectivity
• CPC Class Codes: Y10T 428/24124 Fibers
• CPC Class Codes: Y10T 428/249921 Web or sheet containing structurally defined element or component
• CPC Class Codes: Y10T 428/31511 Of epoxy ether
• CPC Class Codes: Y10T 428/31525 Next to glass or quartz
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]

Abstract

Piezoelectric PZT-polymer composites of 1-3 and 1-3-0 connectivity are trversely reinforced with glass fibers to increase the hydrostatic piezoelectric charge and voltage coefficients (d_h and g_h) for possible use in hydrophone applications. These composites consisted of a foamed (with porosity) or non-foamed (no porosity) polymer matrix with PZT rods aligned parallel to the poling direction and glass fibers in the remaining two transverse directions. Because of the small percentage of PZT required, these composites have densities near that of water, and much lower dielectric constants than solid PZT, resulting in large increases in the hydrostatic piezoelectric voltage coefficient g_h. By increasing the d_h and g_h coefficients, the d_h g_h product, used as the figure of merit, is greatly enhanced.

Claims

1. A PZT-glass-polymer composite material of 1-2-3 connectivity which comprises:

a matrix of a polymer;

a plurality of generally parallel PZT-rods aligned in the direction of a poling electric field secured in said matrix of the polymer;

means for electrically poling said plurality of PZT-rods in said matrix of the polymer;

3. The PZT-glass-polymer composite material of claim 1 wherein said composite material is in the form of a foam and has a connectivity pattern of 1-2-3-0.

4. The PZT-glass-polymer composite material of claim 1 wherein said plurality of PZT-rods are dispersed in said polymer.

5. The PZT-glass-polymer composite material of claim 3 wherein said first plurality of glass-fibers are dispersed in said polymer.

6. The PZT-glass-polymer composite material of claim 4 wherein said second plurality of glass fibers are dispersed in said polymer.

7. The PZT-glass-polymer composite material of claim 1 wherein said polymer is an epoxy.

8. The PZT-glass-polymer composite material of claim 1 wherein said polymer is a polyurethane.

9. The PZT-glass-polymer composite material of claim 1 wherein said first plurality of glass fibers and second plurality of glass fibers are made of E-glass.

2. a first plurality of glass-fibers aligned in a direction perpendicular to said plurality of PZT-rods;

and

a second plurality of glass-fibers aligned in a direction perpendicular both to the direction of said plurality of PZT-rods and to the direction of said first plurality of glass fibers.

10. The PZT-glass-polymer composite material wherein said plurality of PZT-rods are of variable diameter for obtaining desired characteristics of said composite material.

11. The PZT-glass-polymer composite material wherein said first plurality of glass-fibers and said second plurality of glass fibers are of variable diameter for obtaining desired characteristics of said composite material.