Detergent gel compositions in hexagonal liquid crystal form

• US 4,615,819 A
• Filed: 02/21/1985
• Issued: 10/07/1986
• Est. Priority Date: 02/29/1984
• Status: Expired due to Fees

• Current Assignee: Lever Brothers Company (Unilever PLC)
• Original Assignee: Lever Brothers Company (Unilever PLC)
• Inventors: Leng, Francis J., Reed, David A., Machin, David, Erkey, Ozalp
• Primary Examiner(s): WILLIS JR, PRINCE E
• Application Number:
  US06/703,631
• Time in Patent Office: 593 Days
• Field of Search: 252/550, 252/551, 252/553, 252/547, 252/554, 252/558, 252/559, 252/532, 252/533, 252/535, 252/539, 252/540, 252/528, 252/121, 252/DIG. 16, 252/557, 252/538, 252/110 , 252/117, 252/174
• US Class Current: 510/396
• CPC Class Codes: C11D 17/0026 Structured liquid compositions, e.g. liquid crystalline phases or network containing non-Newtonian phase
• CPC Class Codes: C11D 17/003 Colloidal solutions, e.g. gels; Thixotropic solutions or pastes

Abstract

Detergent compositions comprising stable transparent, translucent or opaque hexagonal phase gels contain an anionic or cationic surfactant which is "secondary", i.e. its polar head group is either positioned non-terminally on a hydrophobic chain or carries two or more hydrophobic chains; optionally a further surfactant which is nonionic or non-"secondary"; a material (the "additive") capable of forcing the surfactant system into hexagonal phase; optionally builder, perfume, coloring or other adjuncts; and water. A solid such as abrasive or insoluble builder may be suspended in the gel. Preferred gels of the invention contain alkylbenzene sulphonate or dialkyl sulphosuccinate as the "secondary" surfactant and urea as the "additive". The compositions may be used inter alia for manual dishwashing.

Claims

1. A detergent composition comprising a gel wholly or predominantly in hexagonal liquid crystal form, said gel comprising:

(a) from 15 to 70% by weight of a surfactant system having a Krafft point below ambient temperature, said system being incapable of forming hexagonal phase spontaneously, and consisting essentially of;

(i) 30 to 100% by weight of an anionic or cationic surfactant, having a polar head group and one or more linear or branched aliphatic or araliphatic hydrocarbon chains containing in total at least 8 aliphatic carbon atoms, the polar head group being positioned non-terminally in a single hydrocarbon chain or carrying more than one hydrocarbon chain;

or two or more such surfactants of the same charge type; and

(ii) 0 to 70% by weight of a further surfactant selected from surfactants of the same charge type as (i) but having a polar head group positioned terminally in a linear or branched aliphatic or araliphatic hydrocarbon chain containing at least 8 aliphatic carbon atoms;

nonionic surfactants; and

mixtures thereof;

(b) from 1 to 45% by weight of an additive which is a water-soluble non-micelle-forming or weakly micelle-forming material capable of forcing the surfactant system (a) into hexagonal phase, said additive having at most 6 aliphatic carbon atoms and being selected from the group consisting of aryl or alkylaryl sulfonates, ammonium salts, amides and mixtures thereof, the additive being nonionic or of the same charge type as the surfactant (a) (i); and

(c) at least 20% by weight of water.

2. A detergent composition as claimed in claim 1, wherein the hydrocarbon chains of the surfactant (a)(i) contain in total from 10 to 28 aliphatic carbon atoms.

3. A detergent composition as claimed in claim 1, wherein the hydrocarbon chain of the surfactant (a)(ii) contains from 10 to 18 aliphatic carbon atoms.

4. A detergent composition as claimed in claim 1, wherein the additive (b) has a hydrocarbon chain containing at most 4 aliphatic carbon atoms.

5. A detergent composition as claimed in claim 1, wherein the additive (b) is area.

6. A detergent composition as claimed in claim 1, wherein the gel contains from 25 to 60% by weight of the surfactant system (a).

7. A detergent composition as claimed in claim 1, wherein the gel contains from 5 to 35% by weight of the additive (b).

8. A detergent composition as claimed in claim 1, wherein the gel contains from 25 to 55% by weight of water.

9. A detergent composition as claimed in claim 1, wherein the surfactant system (a) comprises from 10 to 65% by weight of the further surfactant (a)(ii).

10. A detergent composition as claimed in claim 1, wherein the surfactant (a)(i) is anionic.

11. A detergent composition as claimed in claim 10, wherein the surfactant (a)(i) comprises a linear or branched alkylbenzene sulphonate containing an average of from 8 to 15 alkyl carbon atoms.

12. A detergent composition as claimed in claim 10, wherein the surfactant (a)(i) comprises a linear or branched alkylbenzene sulphonate containing an average of from 10 to 13 alkyl carbon atoms.

13. A detergent composition as claimed in claim 10, wherein the surfactant system (a) consists essentially of:

(i) from 45 to 100% by weight of one or more linear or branched C₈ -C₁₅ alkylbenzene sulphonates, and

(ii) from 0 to 55% by weight of one or more further surfactants selected from alkyl ether sulphates, ethoxylated nonionic surfactants, fatty acid soaps and mixtures thereof, and

(iii) from 0 to 25% by weight of one or more fatty acid mono- or diethanolamides or mixtures thereof.

14. A detergent composition as claimed in claim 10, wherein the surfactant (a)(i) comprises a liner or branched di(C₄ -C₁₀) alkyl sulphosuccinate.

15. A detergent composition as claimed in claim 10, wherein the surfactant (a)(i) comprises a linear di(C₆ -C₈) alkyl sulphosuccinate.

16. A detergent composition as claimed in claim 10, wherein the surfactant system (a) consists essentially of

(a)(i) from 30 to 60% by weight of one or more di(C₄ -C₁₀) alkyl sulphosuccinates, and

(a)(ii) from 40 to 70% by weight of one or more further surfactants selected from alkyl ether sulphates, ethoxylated nonionic surfactants, and and mixtures thereof, and

(a)(iii) from 0 to 25% by weight of one or more fatty acid mono- or diethanolamides or mixtures thereof.

17. A detergent composition as claimed in claim 1, wherein the gel contains a buffering amount, less than 3% by weight, of boric acid.

18. A detergent composition as claimed in claim 17, wherein the gel comprises from 1 to 2% by weight of boric acid.

19. A detergent composition as claimed in claim 10, wherein the anionic surfactant (a)(i) is present at least partially in trialkanolamine salt form.

20. A detergent composition as claimed in claim 10, which additionally comprises up to 15% by weight of a water-soluble inorganic or organic detergency builder.

21. A detergent composition as claimed in claim 1, which additionally comprises a solid suspended in the gel, the weight ratio of solid to gel not exceeding 1.5:

1, said suspended solid being a detergency builder or an abrasive.

22. A detergent composition as claimed in claim 1, which is transparent or translucent.

23. A detergent composition as claimed in claim 1, comprising a gel consisting essentially of

(a)(i) from 20 to 55% by weight of one or more linear or branched C₈ -C₁₅ alkylbenzene sulphonates,

(a)(ii) from 0 to 20% by weight of alkyl ether sulphate or ethoxylated nonionic surfactant or soap,

(a)(iii) from 0 to 10% by weight of fatty acid diethanolamide,

(b) from 8 to 30% by weight of urea or sodium toluene sulphonate,

(c) from 0 to 15% by weight of water-soluble phosphate builder,

(d) from 0 to 2% by weight of boric acid,

(e) from 20 to 45% by weight of water.

24. A detergent composition as claimed in claim 23, further comprising a suspended water-insoluble builder or abrasive, in a weight ratio of solid to gel not exceeding 0.43:

1.

25. A detergent composition as claimed in claim 1, comprising a gel consisting essentially of

(a)(i) from 15 to 20% by weight of one or more linear or branched di(C₄ -C₁₀)alkyl sulphosuccinates,

(a)(ii) from 20 to 25% by weight of alkyl ether sulphate,

(b) from 10 to 20% by weight of urea,

(c) from 40 to 50% by weight of water.