Phase change compositions

• US 4,617,332 A
• Filed: 08/31/1984
• Issued: 10/14/1986
• Est. Priority Date: 08/31/1984
• Status: Expired due to Term

• Current Assignee: University of Dayton
• Original Assignee: University of Dayton
• Inventors: Salyer, Ival O., Griffen, Charles W.
• Primary Examiner(s): Lilling, Herbert J.
• Application Number:
  US06/646,402
• Time in Patent Office: 774 Days
• Field of Search: 106/85, 106/90, 106/100, 106/111, 524/8, 524/4, 524/5, 524/7
• US Class Current: 524/4
• CPC Class Codes: C04B 2103/00 Function or property of ingredients for mortars, concrete or artificial stone
• CPC Class Codes: C04B 24/00 Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
• CPC Class Codes: C08K 5/01 Hydrocarbons C08K5/0091 takes precedence
• CPC Class Codes: F28D 20/023 the latent heat storage material being enclosed in granular particles or dispersed in a porous, fibrous or cellular structure
• CPC Class Codes: Y02E 60/14 Thermal energy storage

Abstract

Compositions containing crystalline, long chain, alkyl hydrocarbons as phase change materials including cementitious compositions containing the alkyl hydrocarbons neat or in pellets or granules formed by incorporating the alkyl hydrocarbons in polymers or rubbers; and polymeric or elastomeric compositions containing alkyl hydrocarbons.

Claims

1. A composition useful in thermal energy storage comprising a cementitious matrix material selected from the group consisting of hydraulic cement, gypsum, lime, and plaster of paris;

and plurality of pellets or granules containing a crystalline straight chain alkyl hydrocarbon or a mixture of crystalline, straight chain, alkyl hydrocarbons, said hydrocarbon(s) having at least 14 carbon atoms and a heat of fusion greater than 30 cal/g., and said pellet or granule being formed by a process consisting essentially of dissolving or dispersing said alkyl hydrocarbon(s) in a polymer and grinding or cutting said polymer, said polymer being sufficiently compatible with said alkyl hydrocarbon such that said alkyl hydrocarbon can be dissolved or dispersed in said polymer.

2. The composition of claim 1, wherein said polymer is selected from the group consisting of natural rubber, butyl rubber, polybutadiene, co-poly(butadiene/styrene), co-poly(ethylene/propylene), nylons, polyesters, acrylate rubbers, methacrylate rubbers, polyvinyl alcohol, ethylene vinyl acetate co-polymers, polyvinyl acetate, vinyl chloride/vinyl acetate co-polymer, neoprene, and butadiene-acrylonitrile rubber.

3. The composition of claim 1, wherein said polymer is natural or synthetic rubber.

4. The composition of claim 3, wherein said alkyl hydrocarbon(s) has 16 to 18 carbon atoms.

5. The composition of claim 3, wherein said alkyl hydrocarbon(s) has a melting point in the range of about 16°

to 42°

C.

6. The composition of claim 3, wherein said alkyl hydrocarbon(s) has a melting point in the range of 5°

to 15°

C.

7. The composition of claim 3, wherein said alkyl hydrocarbon(s) has a melting point in the range of 42°

to 65°

C.

8. The composition of claim 1, wherein said pellet or granule contains up to 50% by weight of said hydrocarbon.

9. The composition of claim 1, wherein said pellets or granules have a particle size of approximately 0.25 to 3.0 mm.

10. The composition of claim 2 wherein said rubber is selected from the group consisting of natural rubber, butyl rubber, E&

DM, polybutadiene, and copoly(butadiene/styrene).