Gelatinous elastomeric optical lens, light pipe, comprising a specific block copolymer and an oil plasticizer

• US 4,618,213 A
• Filed: 01/18/1984
• Issued: 10/21/1986
• Est. Priority Date: 03/17/1977
• Status: Expired due to Term

• Current Assignee: Applied Elastomerics Incorporated
• Original Assignee: Applied Elastomerics Incorporated
• Inventors: Chen, John Y.
• Primary Examiner(s): Lilling, Herbert J.
• Application Number:
  US06/572,172
• Time in Patent Office: 1,007 Days
• Field of Search: 524/476, 524/505, 350/409, 350/286, 350/96.34, 446/385, 446/486
• US Class Current: 385/144
• CPC Class Codes: A61C 15/041 Dental floss chemical aspects A61Q11/00
• CPC Class Codes: C08K 5/01 Hydrocarbons C08K5/0091 takes precedence
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C08L 51/00 Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds for ABS polymers C08L55/02; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 53/02 of vinyl-aromatic monomers and conjugated dienes
• CPC Class Codes: C08L 53/025 modified

Abstract

A novel gelatinous composition is disclosed which contains an intimate melt blend admixture of poly(styrene-ethylene-butylene-styrene) triblock copolymer having said styrene end block to ethylene and butylene center block ratio within the range of from between 31:69 to 40:60, and high levels of a plasticizing oil.

The gelatinous composition is transparent and have a novel combination of properties including unexpectedly high elongation and tensile strength and excellent shape retention after extreme deformation under high-velocity impact and stress conditions. The gelatinous products of this invention are soft, flexible, and have elastic memory, characterized by a gel rigidity of from about 20 gram to about 700 gram Bloom. These and other properties are particularly essential for the gelatinous composition to have utility as toys, therapeutic hand exercising grips, shock absorbers, acoustical isolators, and other uses.

Claims

1. A gelatinous elastomer composition consisting essentially of:

(a) 100 parts by weight of triblock copolymer of the general configuration poly(styrene-ethylene-butylene-styrene) wherein said styrene end block to ethylene and butylene center block ratio is within the range of from between 31;

69 to 40;

60;

(b) from about 300 to about 1,600 parts by weight of a plasticizing oil;

(c) said gelatinous elastomer composition having a gel rigidity of about 20 gram to about 700 gram Bloom.

2. A gelatinous elastomer composition of claim 1, wherein said plasticizing oil is selected from the group consisting of petroleum paraffinic oils, petroleum naphthenic oils, and mixtures thereof.

3. A gelatinous elastomer composition of claim 1, wherein said plasticizing oil is selected from the group consisting of synthetic polybutene oils, synthetic polypropene oils, synthetic polyterpene oils and mixtures thereof.

4. A gelatinous elastomer composition of claim 1, wherein said plasticizing oil is selected from the group consisting of petroleum paraffinic oils, petroleum naphthenic oils, synthetic polybutene oils, synthetic polypropylene oils, synthetic polyterpene oils and mixtures thereof;

said oils having an average molecular weight of between about 200 to about 700.

5. A gelatinous elastomer composition of claim 4, wherein said styrene end block to ethylene and butylene center block ratio is about 32:

68 to about 38;

62.

6. A gelatinous elastomer composition of claim 4, wherein said styrene end block to ethylene and butylene center block ratio is about 32:

68 to about 36;

64.

7. A gelainous elastomer composition of claim 4, wherein said styrene end block to ethylene and butylene center block ratio is about 32:

68 to about 34;

66.

8. A gelatinous elastomer composition of claim 2, wherein said oils having an average molecular weight of between about 200 to about 700.

9. A gelatinous elastomer composition of claim 3, wherein said oils having an average molecular weight of between about 200 to about 700.

10. A toy solid hemisphere article formed from a gelatinous elastomer composition according to claim 1 wherein said article exhibits high creep, craze, tear, and crack resistance and is substantially free from oil bleedout.

11. A flexible toy rod formed from a gelatinous elastomer composition according to claim 2 wherein said article exhibits high creep, craze, tear, and crack resistance and is substantially free from oil bleedout.

12. An article formed from a gelatinous elastomer composition according to claim 3.

13. A cladding for optical fiber made from a gelatinous elastomer composition according to claim 4 wherein said article exhibits high creep, craze, tear, and crack resistance and is substantially free from oil bleedout.

14. A prism formed from a gelatinous elastomer composition according to claim 7 wherein said article exhibits high creep, craze, tear, and crack resistance and is substantially free from oil bleedout.

15. A gelatinous elastomer composition of claim 1, wherein said styrene end block to ethylene and butylene center block ratio is about 32:

68 to about 38;

62.

16. A gelatinous elastomer composition of claim 1, wherein said styrene end block to ethylene and butylene center block ratio is about 32:

68 to about 36;

64.

17. A gelatinous elastomer composition of claim 1, wherein said styrene end block to ethylene and butylene center block ratio is about 32:

68 to about 34;

66.

18. A article formed from a gelatinous elastomer composition according to claim 1 wherein said article exhibits high creep, craze, tear, and crack resistance and is substantially free from oil bleedout.

19. A article formed from a gelatinous elastomer composition according to claim 16 wherein said article exhibits high creep, craze, tear, and crack resistance and is substantially free from oil bleedout.

20. A article formed from a gelatinous elastomer composition according to claim 15 wherein said article exhibits high creep, craze, tear, and crack resistance and is substantially free from oil bleedout.

21. A transparent lens formed from a gelatinous elastomer composition of claim 1, 2, 3 or 4 wherein said article exhibits high creep, craze, tear, and crack resistance and is substantially free from oil bleedout.

22. A light conducting rod formed from a gelatinous elastomer composition according to claim 1, 2, 3, or 4 wherein said article exhibits high creep, craze, tear, and crack resistance and is substantially free from oil bleedout.