Method of forming a reactive metal anode having an edge seal

• US 4,618,503 A
• Filed: 03/14/1985
• Issued: 10/21/1986
• Est. Priority Date: 03/14/1985
• Status: Expired due to Fees

• Current Assignee: Westinghouse Electric Corporation (Paramount Global (f/k/a ViacomCBS Inc.))
• Original Assignee: Gould, Inc. (Transdigm Group Incorporated)
• Inventors: Gordon, Arnold Z., Mason, Gary E., Morris, Jerry L.
• Primary Examiner(s): Childs, Sadie L.
• Application Number:
  US06/711,492
• Time in Patent Office: 586 Days
• Field of Search: 427/11, 427/58, 427/77, 427/284, 427/384, 427/385.5, 427/388.1, 427/421, 427/443, 156/306.3, 429/212
• US Class Current: 427/11
• CPC Class Codes: H01M 12/02 Details of electrodes H01M4/00; of non-active parts H01M50/00
• CPC Class Codes: H01M 4/12 of consumable metal or alloy electrodes use of alloy compositions as active materials H01M4/38
• CPC Class Codes: H01M 50/186 characterised by the disposition of the sealing members
• CPC Class Codes: H01M 50/193 Organic material
• CPC Class Codes: H01M 50/409 Separators, membranes or diaphragms characterised by the material
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

An edge seal for a lithium or other consumable metal anode comprises a hydrophobic, chemically inert polymer coating having a high ratio of flexural modulus to flexural strength, a low Izod impact value, and low elongation properties. The seal is applied to the edge of the anode under an atmosphere of gas which is non-reactive with the anodic metal.

Claims

1. A method of forming a sealed reactive metal anode useful in an electrochemical cell comprising said anode, a cathode and an electrolyte in which said anode and cathode are in operation during operation of said cell, said method comprising the steps of:

(a) providing an anode of said reactive metal, said anode defining a first surface which contacts said electrolyte and at least one additional surface at the perimeter of at least a portion of said first surface; and

,

(b) coating said additional surface with a hydrophobic polymer which is substantially chemically inert with respect to said reactive metal and said electrolyte and wherein;

(i) the ratio of the flexural modulus to the flexural strength of said polymer is at least about 25;

(ii) the Izod impact value of said polymer is less than or equal to about 2.0 ft.-lb./in.; and

,

(iii) the percent elongation of said polymer is less than or equal to about 20%, said first surface being substantially free of said hydrophobic polymer, and said coating step (b) being carried out in an atmosphere which is non-reactive with respect to said reactive metal.

2. The method of claim 1 wherein said additional surface is coated by a method selected from the group consisting of abrasion coating, solution coating, aerosol spraying and pressure application.

3. The method of claim 1 wherein said non-reactive atmosphere comprises a Noble gas.

4. The method of claim 3 wherein said Noble gas is selected from the group consisting of argon and helium.

5. The method of claim 1 wherein said non-reactive atmosphere comprises a rigorously dry gas.

6. The method of claim 5 wherein said dry gas is selected from the group consisting of dry air, oxygen, nitrogen and carbon dioxide.

7. The method of claim 1 wherein said polymer is selected from the group consisting of paraffins, polyolefins, polyacrylates, polystyrenes and polyethers.

8. The method of claim 1 wherein said polymer contains a filler.

9. The method of claim 8 wherein said filler is selected from the group consisting of pyrolized polyacrylonitrile fiber, glass, glass fiber, pyrolized pitch fiber, graphite fiber, aluminum flakes and mineral filler.

10. The method of claim 1 wherein the physical characteristics of said polymer further satisfy the equation:

##EQU2##

11. The method of claim 1 wherein said polymer is polymethylmethacrylate.

12. The method of claim 1 wherein said polymer is polystyrene.

13. The method of claim 1 wherein said reactive metal is an alkali metal.

14. The method of claim 13 wherein said alkali metal is lithium.

15. The method of claim 14 wherein said polymer is polymethylmethacrylate.

16. The method of claim 14 wherein said polymer is polystyrene.