Control of polymerization reaction

• US 4,619,901 A
• Filed: 02/21/1985
• Issued: 10/28/1986
• Est. Priority Date: 02/21/1985
• Status: Expired due to Fees

• Current Assignee: Phillips Petroleum Company (ConocoPhillips)
• Original Assignee: Phillips Petroleum Company (ConocoPhillips)
• Inventors: Webb, Don W., Bard, William B.
• Primary Examiner(s): Marcus, Michael S.
• Application Number:
  US06/704,104
• Time in Patent Office: 614 Days
• Field of Search: 422/62, 422/110, 422/111, 436/55, 436/142, 364/499, 364/500, 526/59
• US Class Current: 436/55
• CPC Class Codes: B01J 19/0033 Optimalisation processes, i.e. processes with adaptive control systems adaptive control systems per se G05B13/00
• CPC Class Codes: C08F 2/00 Processes of polymerisation
• CPC Class Codes: C08F 2400/02 Control or adjustment of polymerization parameters
• CPC Class Codes: Y10T 436/12 Condition responsive control
• CPC Class Codes: Y10T 436/216 Unsaturated [e.g., ethylene, diene, etc.]

Abstract

A desired unreacted monomer concentration is maintained in the reaction effluent removed from a polymerization reactor by manipulating the catalyst feed rate to the polymerization reactor based on a non-linear control signal derived from a comparison of actual and desired unreacted monomer concentration.

Claims

1. A method for maintaining a desired unreacted monomer concentration in the reaction effluent withdrawn from a polymerization reactor, wherein monomer is provided as a feed to said polymerization reactor, wherein catalyst is provided periodically through a catalyst feeder valve to said polymerization reactor and wherein said reaction effluent contains polymer and unreacted monomer, said method comprising the steps of:

establishing a first signal representative of the actual unreacted monomer concentration in said reaction effluent;

establishing a second signal representative of the desired unreacted monomer concentration in said reaction effluent;

using a linear controller to compare said first signal and said second signal and to establish a third signal which is responsive to the difference between said first signal and said second signal, wherein said third signal is scaled so as to be representative of the number of times said catalyst feeder valve should be actuated per unit time in order to maintain the magnitude of said first signal substantially equal to the magnitude of said second signal if said catalyst has a constant activity and the same amount of said catalyst is introduced into said polymerization reaction by each actuation of said catalyst feeder valve;

establishing a fourth signal representative of the exponential of said third signal, wherein the conversion of said third signal to an exponential compensates for variations in the activity of said catalyst and variations in the amount of said catalyst introduced into said polymerization reactor each time said catalyst feeder valve is actuated; and

actuating said catalyst feeder valve in response to said fourth signal.

2. A method in accordance with claim 1 additionally comprising the steps of:

providing said reaction effluent as a feed to a flashtank;

widthdrawing an overhead stream from said flashtank;

withdrawing a bottoms stream containing polymer from said flashtank;

establishing said first signal based on an analysis of the overhead stream withdrawn from said flashtank.

4. Apparatus in accordance with claim 1 additionally comprising:

a flashtank;

means for providing said reaction effluent as a feed to said flashtank;

means for withdrawing an overhead stream from said flashtank; and

means for withdrawing a bottoms stream containing polymer from said flashtank, wherein said first signal is established based on an analysis of the overhead stream withdrawn from said flashtank.

3. Apparatus comprising:

a polymerization reactor;

means for providing monomer to said polymerization reactor;

a catalyst feeder valve for periodically introducing catalyst into said polymerization reactor;

means for removing the reaction effluent containing polymer and unreacted monomer from said polymerization reactor;

means for establishing a first signal representative of the actual unreacted monomer concentration in said reaction effluent;

means for establishing a second signal representative of the desired unreacted monomer concentration in said reaction effluent;

a linear controller for comparing said first signal and said second signal and for establishing a third signal which is responsive to the difference between said first signal and said second signal, wherein said third signal is scaled so as to be representative of the number of times said catalyst feeder valve should be actuated per unit time in order to maintain the magnitude of said first signal substantially equal to the magnitude of said second signal if said catalyst has a constant activity and the same amount of said catalyst is introduced into said polymerization reaction by each actuation of said catalyst feeder valve;

means for establishing a fourth signal representative of the exponential of said third signal, wherein the conversion of said third signal to an exponential compensates for variations in the activity of said catalyst and variations in the amount of said catalyst introduced into said polymerization reactor each time said catalyst feeder valve is actuated; and

means for actuating said catalyst feeder valve in response to said fourth signal.