Fuel cell electrolyte

• US 4,622,276 A
• Filed: 07/02/1985
• Issued: 11/11/1986
• Est. Priority Date: 12/16/1983
• Status: Expired due to Fees

• Current Assignee: AKZO America Incorporated
• Original Assignee: Stauffer Chemical Company (Nouryon BV)
• Inventors: Walsh, Edward N.
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US06/751,119
• Time in Patent Office: 497 Days
• Field of Search: 429/46, 429/203
• US Class Current: 429/498
• CPC Class Codes: H01M 8/08 Fuel cells with aqueous electrolytes
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

This invention relates to a novel intermediate temperature fuel cell electrolyte, fuel cells containing this electrolyte and a process for operating these fuel cells.

The fuel cell electrolyte composition comprises one or more phosphonic acids. Typical phosphonic acids are compounds of the formula ##STR1## wherein R is a moiety derived from hydroxyalkyl, alkyl, phenyl, alkylphenyl, vinyl, haloalkyl, halophenyl, halomethylphenyl, vinyl, amine, ammonia and ##STR2## and m represents an integer from 1 to 3 and n represents 0 (zero) or the integer 1. This electrolyte composition can further comprise phosphoric acid.

The fuel cell electrolyte composition can include a gelling agent and can be effectively used in fuel cells wherein the fuel is hydrogen, the oxidizer is oxygen and the operating temperature is between about 100° C. and 250° C.

Claims

1. A fuel cell having an electrolyte composition comprising one or more phosphonic acids of the formula ##STR10## wherein m represents an integer from 1 to 3, n represents O or the integer 1, and R is a moiety derived from hydroxyalkyl, alkyl, phenyl, alkylphenyl, vinyl, halophenyl, halomethylphenyl, amine, ammonia and ##STR11##

2. The fuel cell of claim 1 having an electrolyte composition further comprising phosphoric acid.

3. A fuel cell having an electrolyte composition comprising one or more phosphonic acids of the formula ##STR12## wherein R'"'"' is hydroxyalkyl, alkyl, phenyl, alkylphenyl, vinyl, haloalkyl, halophenyl and halomethylphenyl.

4. The fuel cell of claim 3 having an electrolyte composition further comprising phosphoric acid.

5. The fuel cell of claim 4 wherein R is methyl in the electrolyte composition.

6. The fuel cell of claim 4 wherein R'"'"' is methylphenyl in the electrolyte composition.

7. The fuel cell of claim 4 wherein R'"'"' is hydroxymethyl in the electrolyte composition.

8. The fuel cell of claim 4 wherein R'"'"' is phenyl in the electrolyte composition.

9. The fuel cell of claim 4 having an electrolyte composition further comprising a gelling agent.

10. The fuel cell of claim 9 wherein the gelling agent in the electrolyte composition is selected from the group consisting of powdered graphite, boric acid, boronphosphate or mixtures thereof.

11. The fuel cell of claim 3 wherein R'"'"' is methyl in the electrolyte composition.

12. The fuel cell of claim 3 wherein R'"'"' is methylphenyl in the electrolyte composition.

13. The fuel cell of claim 3 wherein R'"'"' is hydroxymethyl in the electrolyte composition.

14. The fuel cell of claim 3 wherein R'"'"' is phenyl in the electrolyte composition.

15. The fuel cell of claim 4 having an electrolyte composition further comprising a gelling agent.

16. The fuel cell of claim 15 wherein the gelling agent in the electrolyte composition is selected from the group consisting of powdered graphite, boric acid, boronphosphate or mixtures thereof.

17. A fuel cell capable of operating at a temperature from about 100°

C. to about 250°

C. containing an electrolyte comprising one or more phosphonic acids of the formula ##STR13## wherein R'"'"' is hydroxyalkyl, alkyl, phenyl, alkylphenyl, vinyl, haloalkyl, halophenyl and halomethylphenyl which comprises an oxidizer and a gaseous fuel.

18. The fuel cell of claim 17 wherein said gaseous fuel is selected from the group consisting of gaseous saturated aliphatic hydrocarbons, carbon monoxide, hydrogen, methanol and mixtures thereof.

19. The fuel cell of claim 17 wherein said fuel is hydrogen and said oxidizer is oxygen.