Electrochemical cells

• US 4,622,277 A
• Filed: 09/30/1985
• Issued: 11/11/1986
• Est. Priority Date: 09/30/1985
• Status: Expired due to Term

• Current Assignee: Duracell Incorporated (Berkshire Hathaway Incorporated)
• Original Assignee: Duracell Incorporated (Berkshire Hathaway Incorporated)
• Inventors: Moses, Peter R., Taylor, Alwyn H., Reise, Terrence F., Patel, Bhupendra, Bedder, Paul L.
• Primary Examiner(s): LeFevour, Charles F.
• Application Number:
  US06/781,836
• Time in Patent Office: 407 Days
• Field of Search: 429/94, 429/234, 429/228, 429/220, 429/221, 429/223, 429/219, 429/218, 429/196, 429/121, 429/122, 429/7
• US Class Current: 429/94
• CPC Class Codes: H01M 10/4235 Safety or regulating additives or arrangements in electrodes, separators or electrolyte H01M10/4242 takes precedence
• CPC Class Codes: H01M 2200/00 Safety devices for primary or secondary batteries
• CPC Class Codes: H01M 2200/30 Preventing polarity reversal
• CPC Class Codes: H01M 50/534 characterised by the material of the leads or tabs
• CPC Class Codes: H01M 6/10 with wound or folded electrodes
• CPC Class Codes: H01M 6/16 with organic electrolyte H01M6/18 takes precedence
• CPC Class Codes: H01M 6/5005 Auxiliary electrodes
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

This invention provides a design for spirally wound electrochemical cells which improves their safety during abuse such as voltage reversal. The invention comprises coupling a first segment of inert conductive metal to the cathode and a dendrite target comprised of an inert conductive metal to the anode. When these electrodes are spirally wound together the two segments of inert conductive metal face each other, held in physical separation by the separator, whereby during voltage reversal a dendrite grows from said first segment to said dendrite target.

Claims

1. An electrochemical cell having a positive terminal, a negative terminal, and at least two electrodes comprising:

an anode connected to the negative terminal;

a cathode connected to the positive terminal;

a separator interposed between said anode and cathode;

a nonaqueous electrolyte;

a first segment of exposed inert conductive metal coupled mechanically and electrically to the cathode; and

an inert metal dendrite target comprised of a second segment of exposed inert conductive metal coupled mechanically and electrically to the anode;

wherein the position of said first segment of inert metal coupled to the cathode and the position of said second segment of inert metal coupled to the anode are such that said first segment and said second segment face each other and are held in physical separation by the separator, whereby during voltage reversal a dendrite will grow from said first segment toward said dendrite target and come in contact with said dendrite target.

2. The cell recited in claim 1 wherein said anode is comprised of an alkali or alkaline earth metal having a length substantially greater than width;

wherein said cathode is comprised of a cathode material compressingly adhered to a conductive metal grid and said cathode has a length substantially greater than width;

wherein said anode and said cathode have lengths such that the cathode is longer than the anode, such that when said anode, cathode, and separator are spirallly wound together a length of anode protrudes from between a first and a second outermost spirals of cathode, said protruding length being no greater than 25% of the circumference of the cell, and said protruding length being the location of said dendrite target.

3. The cell recited in claim 2 wherein said first segment of inert metal coupled to the cathode is an exposed segment, on just one side of the cathode, of the conductive metal grid, said area of exposure being no greater than 5%, but not less than 1%, of the cathode surface area on that side of the cathode.

4. The cell recited in claim 3 wherein said dendrite target of inert metal coupled to the anode is comprised of a strip of metal positioned so that its lengthwise direction is perpendicular to the lengthwise direction of the anode, said target having a thickness greater than 1 mil but less than one half the thickness of the cathode, said target also functioning as an anode tab for connection to the negative terminal of the cell.

5. The cell recited in claim 4 wherein said dendrite target coupled to the anode is selected from the group consisting of nickel, nickel plated cold rolled steel, copper, stainless steel, and cold rolled steel.

6. The cell recited in claim 3 wherein said dendrite target of inert metal coupled to the anode is comprised of a piece of metal having an area not greater than 5% of the anode surface area but less than the surface area of the exposed metal grid of the cathode, said target having a thickness greater than 1 mil but less than one half the thickness of the cathode, said target fixed onto the surface of the anode such that it does not extend beyond any edge of the anode, and located behind and aligned with said target on the other side of the anode is an anode tab.

7. The cell recited in claim 6 wherein said dendrite target coupled to the anode is selected from the group consisting of nickel, nickel plated cold rolled steel, copper, stainless steel, and cold rolled steel.

8. The cell recited in claim 6 wherein the anode is comprised of lithium and the nonaqueous electrolyte comprises a cathode active material of SO₂.

9. The cell recited in claim 3 wherein the conductive metal grid is comprised of a metal selected from the group consisting of metals or alloys that form an alloy with lithium.

10. The cell recited in claim 3 wherein the conductive metal grid is comprised of a metal selected from the group consisting of titanium, tantalum, niobium, aluminum, stainless steel, or nickel.

11. The cell recited in claim 3 wherein the anode is lithium or alloys thereof.

12. The cell recited in claim 3 wherein the cathode material is selected from the group consisting of carbons, metal oxides, carbon fluorides, metal sulfides, transition metal polysulfides, metal halides, and mixtures thereof.

13. The cell recited in claim 3 wherein the cathode material is selected from the group consisting of MnO₂, CFx, V₂ O₅, WO₃, MoO₃, MoS₂, lead oxides, cobalt oxides, copper oxides, CuS, CuS₂, In₂ O₃, iron sulfides, NiS, Ag₂ CrO₄, Ag₃ PO₄, TiS₂, transition metal polysulfides, CoCl₂, NiCl₂, FeBr₃, PbCl₂, CuCl₂, CuBr₂, and mixtures thereof.

14. The cell recited in claim 3 wherein the cathode material is comprised of carbon and the nonaqueous electrolyte comprises a cathode active material selected from the group consisting of SO₂, SOCl₂, and SO₂ Cl₂.

15. The cell recited in claim 1 wherein the anode is comprised of lithium and the nonaqueous electrolyte comprises a cathode active material of SO₂.