Expandable polypropylene interpolymer particles

• US 4,622,347 A
• Filed: 04/07/1986
• Issued: 11/11/1986
• Est. Priority Date: 04/07/1986
• Status: Expired due to Term

• Current Assignee: ARCO Chemical Technology LP A Partnership of de
• Original Assignee: Atlantic Richfield Company Incorporated (BP PLC)
• Inventors: Fudge, Kent D.
• Primary Examiner(s): Foelak, Morton
• Application Number:
  US06/848,560
• Time in Patent Office: 218 Days
• Field of Search: 521/79, 521/81, 521/59, 521/60, 521/139
• US Class Current: 521/81
• CPC Class Codes: C08F 212/08 Styrene
• CPC Class Codes: C08F 255/02 on to polymers of olefins having two or three carbon atoms
• CPC Class Codes: C08J 2351/06 grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
• CPC Class Codes: C08J 9/18 by impregnating polymer particles with the blowing agent

Abstract

A process for producing a polypropylenepolystyrene interpolymer which can be impregnated with a blowing agent and can then be expanded under normal conditions for polystyrene particles to low density, fine cell structure foams. The interpolymer must be viscbroken, lubricated and stress relaxed in order to foam at 100° C. to densities less than 2.0 pcf.

Claims

1. A process for producing expandable polypropylene particles comprising (a) suspending in an aqueous medium, a copolymer of propylene and sufficient olefin comonomers to give said copolymer a melting peak of less than 140°

C., with the aid of a suitable suspending agent system;

(b) adding to said suspension vinyl aromatic monomer and a catalyst system such that the amount of monomer is 40 to 80% by weight based on copolymer plus monomer;

(c) polymerizing said monomer in the interior of said copolymer to form a polypropylene-polyvinylaromatic monomer interpolymer;

(d) separating said interpolymer from said suspension by acidifying, filtering, washing with water and drying in air;

(e) extruding said interpolymer in admixture with a lubricant and cell control agent and a peroxide, if used, to viscbreak said interpolymer to a melt flow (condition L) of at least 10, under conditions to minimize orientation stress in the final extrudate;

(f) impregnating said extrudate with a blowing agent to give expandable polypropylene-polyvinyl aromatic monomer interpolymers which can be expanded at 100°

C. to fine cell structure foams of density less than 2.0 pounds per cubic foot.

2. The process of claim 1 wherein said olefin comonomer may be ethylene.

3. The process of claim 1 wherein said olefin comonomers may be ethylene and butene.

4. The process of claim 1 wherein said vinyl aromatic monomer is at least one monomer selected from the group consisting of styrene, alpha-methylstyrene, nuclearmethylstyrene, p-tert-butylstyrene, chlorostyrene, bromostyrene, and mixtures thereof.

5. The process of claim 1 wherein said vinyl aromatic monomer and catalysts are added as an emulsion of monomer and catalysts in water.

6. The process of claim 1 wherein said vinyl aromatic monomer and catalysts are added as a solution of catalyst in monomer.

7. The process of claim 1 wherein said lubricant and cell control agent is 2-4% by weight ethylene-bis-stearamide based on interpolymer.

8. The process of claim 1 wherein said lubricant and cell control agent is 2-4% by weight ethylene-bis-stearamide and 0.2-0.4% by weight zinc stearate based on interpolymer.

9. The process of claim 1 wherein said conditions to minimize orientation stress comprise slow air cool of the extrudate.

10. The process of claim 1 wherein said conditions to minimize orientation stress comprise cooling in a blob followed by grinding to small particles.

11. The process of claim 1 wherein said conditions to minimize orientation stress comprise slow cool with warm water.

12. The process of claim 1 wherein said blowing agent is selected from the group consisting of aliphatic hydrocarbons, cycloaliphatic hydrocarbons, and halogenated hydrocarbons.