Thermoset microporous polymer lubricating composition and method for forming the same
First Claim
1. A thermoset microporous polymer lubricating composition, comprising:
- a lubricating oil; and
a thermosetting polymer formed into a matrix having interconnected microscopic pores to receive said lubricating oil during formation of said matrix and with said matrix having sufficient structural integrity to thereafter retain said lubricating oil and to release said retained lubricating oil from said matrix during subsequent use of said composition for lubricating elements external to said matrix.
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Accused Products
Abstract
Thermoset microporous polymer lubricating compositions and methods for forming the same are disclosed. Each thermoset composition disclosed includes a thermosetting polymer that is formed into a microporous matrix capable of receiving a lubricating oil in the interconnected microscopic pores of the matrix during formation thereof, with the lubricating oil being thereafter retained in the pores until released through capillary draw, externally applied forces or elevated temperatures. Thermosetting polymers are set forth utilizing a number of different thermosetting resins, among which are polyurethanes that include an isocyanate (such as a diisocyanate), a polyol (such as a polyether-based polyol or a polyester-based polyol), and a catalyst (such as an amine or a metal salt) for forming a polyurethane polymer matrix the pores of which are filled with lubricating oil (such as a mineral oil or an ester-based synthetic oil), with surface energy modifiers (such as emulsifiers and foaming agents) also being utilized in some formulations to promote interconnected pore formation. The polyurethane matrix is formed by mixing the lubricating oil, catalyst and surface energy modifiers (if used) with the polyol to form an initial mixture, thereafter mixing the initial mixture with the isocyanate to form a final mixture, and then pouring the final mixture into a mold or utilization device (such as a bearing) where the final mixture is allowed to cure to thus form the polyurethane polymer matrix the pores of which are filled with the lubricating oil.
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Citations
30 Claims
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1. A thermoset microporous polymer lubricating composition, comprising:
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a lubricating oil; and a thermosetting polymer formed into a matrix having interconnected microscopic pores to receive said lubricating oil during formation of said matrix and with said matrix having sufficient structural integrity to thereafter retain said lubricating oil and to release said retained lubricating oil from said matrix during subsequent use of said composition for lubricating elements external to said matrix. - View Dependent Claims (2, 3, 4, 5, 6, 16, 17)
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7. A thermoset microporous polymer lubricating composition, comprising:
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a lubricating oil; a thermosetting polymer comprising between about 30% to 95% of said lubricating oil, said thermosetting polymer formed into a matrix having interconnected pores with pore diameter of between about 1 and 10 microns to receive said lubricating oil during formation of said matrix and with said matrix having sufficient structural integrity to thereafter retain said lubricating oil and to release said retained lubricating oil from said matrix during subsequent use of said composition for lubricating elements external to said matrix; and a surface energy modifier for acting on the surfaces of said matrix and said oil to thereby enhance creation of said interconnected pores in said matrix during formation thereof. - View Dependent Claims (8)
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9. A thermoset microporous polymer lubricating composition, comprising:
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a polyurethane matrix formed from an isocyanate, a polyol, and a catalyst capable of interacting to form interconnected microscopic pores in said matrix at formation of said matrix; and a lubricating oil compatible with said matrix and received in said pores of said matrix during formation of said matrix whereby said lubricating oil is maintainable in said matrix and lubricating oil so retained is releasable from said matrix during subsequent use of said composition for lubricating elements external to said matrix. - View Dependent Claims (10, 11, 12, 13, 14, 15, 18)
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19. A thermoset microporous polymer lubricating composition, comprising:
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a polyurethane matrix formed from a urethane resin made by combining a methylene diisocyanate, a polyol and a catalyst, said matrix having interconnected microscopic pores therein with the diameter of said pores being between about 1 and 10 microns; and a lubricating oil received and retained in said microscopic pores of said matrix, with said composition including about 30% to 60% lubricating oil and 40% to 70% urethane resin, and with said retained lubricating oil being releasable from said matrix during subsequent use of said composition for lubricating elements external to said matrix. - View Dependent Claims (20)
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21. A method for forming a thermoset microporous polymer lubricating composition, said method comprising:
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providing a lubricating oil; providing a thermosetting polymer capable of being formed into a matrix; mixing said lubricating oil with said thermosetting polymer to form a mixture thereof; placing said mixture into a forming area; and allowing said mixture to cure at said forming area to form thereat a mixture from said polymer with said matrix having interconnected pores therein that receive and retain said lubricating oil, and with said retained lubricating oil being releasable during subsequent use of said composition for lubricating elements external to said matrix. - View Dependent Claims (22, 23, 24, 25)
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26. A method for forming a thermoset microporous polymer lubricating composition, said method comprising:
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providing a lubricating oil; providing an isocyanate, a polyol and a catalyst capable of reacting to form a matrix having interconnected microscopic pores; mixing said lubricating oil with said polyol and catalyst to form an initial mixture; mixing said first mixture with said isocyanate to form a final mixture; placing said final mixture into a forming area; and allowing said final mixture to cure at said forming area to form thereat said matrix having said interconnected pores filled with said lubricating oil, said lubricating oil being retained in said interconnected pores and being releasable during subsequent use of said composition for lubricating elements external to said matrix. - View Dependent Claims (27, 28, 29, 30)
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Specification