Thermoset microporous polymer lubricating composition and method for forming the same

• US 4,623,472 A
• Filed: 04/05/1985
• Issued: 11/18/1986
• Est. Priority Date: 04/05/1985
• Status: Expired due to Fees

• Current Assignee: PHY MET Incorporated
• Original Assignee: Armco Inc. (Cleveland-Cliffs Steel Holding Corp.)
• Inventors: Stull, Dean P., Jamison, Warren E., Guzzetta, Franklin H.
• Primary Examiner(s): Howard, Jacqueline V.
• Application Number:
  US06/720,518
• Time in Patent Office: 592 Days
• Field of Search: 252/12, 252/12.2, 252/51, 252/52, 252/56 S
• US Class Current: 508/100
• CPC Class Codes: B29C 2037/92 Lubricating
• CPC Class Codes: B29C 39/003 characterised by the choice of material
• CPC Class Codes: B29L 2031/04 Bearings
• CPC Class Codes: C10M 177/00 Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
• CPC Class Codes: F02F 7/0085 Materials for constructing engines or their parts
• CPC Class Codes: F16C 33/6648 in a porous or resinous body, e.g. a cage impregnated with the liquid
• CPC Class Codes: F16C 33/6688 Lubricant compositions or properties, e.g. viscosity

Abstract

Thermoset microporous polymer lubricating compositions and methods for forming the same are disclosed. Each thermoset composition disclosed includes a thermosetting polymer that is formed into a microporous matrix capable of receiving a lubricating oil in the interconnected microscopic pores of the matrix during formation thereof, with the lubricating oil being thereafter retained in the pores until released through capillary draw, externally applied forces or elevated temperatures. Thermosetting polymers are set forth utilizing a number of different thermosetting resins, among which are polyurethanes that include an isocyanate (such as a diisocyanate), a polyol (such as a polyether-based polyol or a polyester-based polyol), and a catalyst (such as an amine or a metal salt) for forming a polyurethane polymer matrix the pores of which are filled with lubricating oil (such as a mineral oil or an ester-based synthetic oil), with surface energy modifiers (such as emulsifiers and foaming agents) also being utilized in some formulations to promote interconnected pore formation. The polyurethane matrix is formed by mixing the lubricating oil, catalyst and surface energy modifiers (if used) with the polyol to form an initial mixture, thereafter mixing the initial mixture with the isocyanate to form a final mixture, and then pouring the final mixture into a mold or utilization device (such as a bearing) where the final mixture is allowed to cure to thus form the polyurethane polymer matrix the pores of which are filled with the lubricating oil.

Claims

1. A thermoset microporous polymer lubricating composition, comprising:

a lubricating oil; and

a thermosetting polymer formed into a matrix having interconnected microscopic pores to receive said lubricating oil during formation of said matrix and with said matrix having sufficient structural integrity to thereafter retain said lubricating oil and to release said retained lubricating oil from said matrix during subsequent use of said composition for lubricating elements external to said matrix.

2. The composition of claim 1 wherein said interconnected pores of said matrix have pore dimensions sufficient to receive and retain a quantity of lubricating oil equal to at least about 30% of said thermosetting polymer.

3. The composition of claim 1 wherein said interconnected pores have a pore diameter of between about 1 and 10 microns.

4. The composition of claim 1 wherein said lubricating oil comprises between about 30% and 80% of said thermosetting polymer.

5. The composition of claim 1 wherein said thermosetting polymer is selected from the group consisting of a urethane, an epoxy, a polyester, a silicone, and a hybrid system having a polyester resin and a polyester elastomer.

6. The composition of claim 1 wherein said composition includes a surface energy modifier for acting on the surfaces of said matrix and oil to enhance said pore formation and receipt of said oil therein.

16. The composition of claim 6 wherein said composition includes a surface energy modifier.

17. The composition of claim 16 wherein said surface energy modifier is one of an emulsifier and a foaming agent.

7. A thermoset microporous polymer lubricating composition, comprising:

a lubricating oil;

a thermosetting polymer comprising between about 30% to 95% of said lubricating oil, said thermosetting polymer formed into a matrix having interconnected pores with pore diameter of between about 1 and 10 microns to receive said lubricating oil during formation of said matrix and with said matrix having sufficient structural integrity to thereafter retain said lubricating oil and to release said retained lubricating oil from said matrix during subsequent use of said composition for lubricating elements external to said matrix; and

a surface energy modifier for acting on the surfaces of said matrix and said oil to thereby enhance creation of said interconnected pores in said matrix during formation thereof.

8. The composition of claim 7 wherein said surface energy modifier is one of an emulsifier and a foaming agent.

9. A thermoset microporous polymer lubricating composition, comprising:

a polyurethane matrix formed from an isocyanate, a polyol, and a catalyst capable of interacting to form interconnected microscopic pores in said matrix at formation of said matrix; and

a lubricating oil compatible with said matrix and received in said pores of said matrix during formation of said matrix whereby said lubricating oil is maintainable in said matrix and lubricating oil so retained is releasable from said matrix during subsequent use of said composition for lubricating elements external to said matrix.

10. The composition of claim 9 wherein said isocyanate is selected from the group consisting of a methylene diisocyanate, a tolulene diisocyanate, a hexamethylene diisocyanate, and a naphthalene diisocyanate.

11. The composition of claim 9 wherein said polyol is selected from the group consisting of an ether, an ester of adipic acid, and phthalic anhydride.

12. The composition of claim 9 wherein said polyol also is selected from the group consisting of glycol, triol, hydroquinone and pentaerythritol as reaction modifiers.

13. The composition of claim 9 wherein said catalyst is selected from the group consisting of an amine and a metal salt.

14. The composition of claim 13 wherein said amine is selected from the group consisting of triethyl amine, triethylene diamine and aniline, and wherein said metal salt is selected from the group consisting of stannous chloride, di-n-butyl tin dilaurate, stannous octoate and zinc napthanate.

15. The composition of claim 9 wherein said lubricating oil is selected from the group consisting of a mineral oil, a synthesized hydrocarbon, an ester-based oil, and a silicone oil.

18. The composition of claim 9 wherein said composition includes additives to modify the mechanical, physical and lubricating properties of said composition.

19. A thermoset microporous polymer lubricating composition, comprising:

a polyurethane matrix formed from a urethane resin made by combining a methylene diisocyanate, a polyol and a catalyst, said matrix having interconnected microscopic pores therein with the diameter of said pores being between about 1 and 10 microns; and

a lubricating oil received and retained in said microscopic pores of said matrix, with said composition including about 30% to 60% lubricating oil and 40% to 70% urethane resin, and with said retained lubricating oil being releasable from said matrix during subsequent use of said composition for lubricating elements external to said matrix.

20. The composition of claim 19 wherein said polyol is selected from the group consisting of an ether, an ester of adipic acid, and phthalic anhydride, wherein said catalyst is selected from the group consisting of an amine and a metal salt, and wherein said lubricating oil is selected from the group consisting of mineral oil, a synthesized hydrocarbon, an ester-based oil, and a silicone oil.

21. A method for forming a thermoset microporous polymer lubricating composition, said method comprising:

providing a lubricating oil;

providing a thermosetting polymer capable of being formed into a matrix;

mixing said lubricating oil with said thermosetting polymer to form a mixture thereof;

placing said mixture into a forming area; and

allowing said mixture to cure at said forming area to form thereat a mixture from said polymer with said matrix having interconnected pores therein that receive and retain said lubricating oil, and with said retained lubricating oil being releasable during subsequent use of said composition for lubricating elements external to said matrix.

22. The method of claim 21 wherein said method includes adding a surface energy modifier to said mixture to enhance formation of said pores.

23. The method of claim 21 wherein said mixture is cured in a mold.

24. The method of claim 21 wherein said mixture is cured in a utilization device.

25. The method of claim 24 wherein said utilization device is one of a bearing, a wire rope, and a power transmission device.

26. A method for forming a thermoset microporous polymer lubricating composition, said method comprising:

providing a lubricating oil;

providing an isocyanate, a polyol and a catalyst capable of reacting to form a matrix having interconnected microscopic pores;

mixing said lubricating oil with said polyol and catalyst to form an initial mixture;

mixing said first mixture with said isocyanate to form a final mixture;

placing said final mixture into a forming area; and

allowing said final mixture to cure at said forming area to form thereat said matrix having said interconnected pores filled with said lubricating oil, said lubricating oil being retained in said interconnected pores and being releasable during subsequent use of said composition for lubricating elements external to said matrix.

27. The method of claim 26 wherein said method comprises providing said isocyanate and polyol near stoichiometric ratios of isocyanate to polyol, and providing lubricating oil in the range of about 30% to 60% of said isocyanate, polyol and catalyst.

28. The method of claim 26 wherein said isocyanate, polyol and catalyst are selected to cause the microscopic pores of said matrix to be of sufficient size to receive a sufficiently large quantity of lubricating oil in said pores for adequate lubricating purposes during use of said composition but without adversely effecting the structural integrity of said matrix so as to cause premature release of lubricating oil from said matrix.

29. The method of claim 26 wherein said final mixture is cured in a utilization device that is one of a bearing, a wire rope, and a power transmission.

30. The method of claim 26 wherein said method includes adding a surface energy modifier, that is one of an emulsifier and a foaming agent, to said initial mixture to enhance subsequent formation of said pores.