Process for removing acidic gases from gaseous mixtures using aqueous scrubbing solutions containing heterocyclic nitrogen compounds

• US 4,624,838 A
• Filed: 04/29/1985
• Issued: 11/25/1986
• Est. Priority Date: 04/29/1985
• Status: Expired due to Fees

• Current Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Original Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Inventors: Savage, David W., Pan, Yen-Chi
• Primary Examiner(s): HELLER, GREGORY
• Application Number:
  US06/728,410
• Time in Patent Office: 575 Days
• Field of Search: 423/226, 423/228, 423/243, 423/227
• US Class Current: 423/226
• CPC Class Codes: B01D 53/1456 Removing acid components
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: C01B 32/50 Carbon dioxide
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

Disclosed is a process for removing acid gases from gaseous streams by contacting the stream with an aqueous scrubbing solution containing a heterocyclic nitrogen compound comprised of either a five-- or six--membered ring having a pKa no greater than about 8. Imidazole is a preferred heterocyclic nitrogen compound.

Claims

1. A process for removing acid gases selected from hydrogen sulfide and carbon dioxide from gaseous feeds which process comprises:

contacting the feed with an aqueous scrubbing solution comprising water and 1 to 11 moles of a heterocyclic nitrogen compound per liter of solution which compound is selected from the group consisting of imidazole, a C₁ -C₃ alkyl-substituted imidazole where the alkyl groups are bonded to at least one carbon atom, and a C₁ -C₃ alkyl- or C₁ -C₃ hydroxyalkyl-substituted piperazine where the alkyl or hydrozyalkyl groups are bonded to both nitrogen atoms of the ring, the compound having a pKa no greater than about 8, at conditions whereby acid gases are absorbed by said scrubbing solution.

2. The process of claim 1 wherein the amount of heterocyclic compound in the scrubbing solution is from about 3 to 5.5 moles per liter of solution.

3. The process of claim 1 wherein the heterocyclic compound is imidazole, 4-methyl imidazole, or N,N'"'"'-piperazine diethanol.

4. The process of claim 3 wherein the heterocyclic compound is imidazole.

5. The process of claim 1 wherein the scrubbing solution additionally contains an additive selected from the group consisting of surfactants, antifoaming agents, antioxidants, corrosion inhibitors and mixtures thereof.

6. The process of claim 1 wherein the contacting is conducted at a temperature ranging from about 0°

to about 100°

C. and at a pressure ranging from about 200 to about 1500 psia.

7. The process of claim 1 wherein the regenerating is conducted at a temperature in the range from about 20°

to about 200°

C. and at a pressure ranging from about 15 to about 200 psia.

8. The process of claim 1 wherein the scrubbing solution is regenerated by desorption of acid gases.

9. The process of claim 7 wherein the scrubbing solution is regenerated by desorption of acid gases.

10. A process for removing carbon dioxide from a normally gaseous feed, which process comprises:

contacting the feed with an aqueous scrubbing solution comprising water and 1-11 moles of one or more heterocyclic compounds per mole of solution which compounds are selected from imidazole, 4-methyl imidazole, and N,N-piperazine diethanol, at conditions whereby carbon dioxide is absorbed by the scrubbing solution.

11. The process of claim 10 wherein the scrubbing solution is regenerated by desorbing carbon dioxide.

12. The process of claim 11 wherein the amount of heterocyclic compound in the scrubbing solution is from about 3 to 5.5 moles per liter of solution.

13. The process of claim 10 wherein the heterocyclic compound is imidazole.

14. The process of claim 13 wherein the heterocyclic compound is imidazole.

15. The process of claim 11 wherein the scrubbing solution additionally contains an additive selected from the group consisting of surfactants, antifoaming agents, antioxidants, corrosion inhibitors and mixtures thereof.

16. A process for substantially completely removing carbon dioxide from a normally gaseous feed, which process comprises, in sequential steps:

(a) contacting the feed with an aqueous scrubbing solution comprising water and imidazole wherein the total imidazole concentration in the solution is in the range from about 1 to about 11 moles per liter, said contacting being conducted at a temperature ranging from about 0°

to 100°

C. and at a pressure from about 200 to 1500 psia, thereby to absorb the carbon dioxide containing acidic gas in said scrubbing solution, and

(b) regenerating said scrubbing solution at a temperature in the range from about 20°

to 200°

C. and at a pressure ranging from about 15 to 200 psia thereby to desorb the carbon dioxide containing acidic gas from the scrubbing solution.

17. The process of claim 16 wherein the imidazole is present in a molar concentration of greater than 5 and the absorption step and desorption step are carried out simultaneously in one of two adjacent reactors wherein each reactor absorption and regeneration in sequence and alternately with the other reactor.

18. The process of claim 16 wherein the imidazole is present in a molar concentration of greater than 5 and the absorption step and desorption step are carried out simultaneously in one of two reactors which are both connected to an absorption unit and flash unit which units are interconnected via a line for recycling regenerated scrubbing solution to the absorption unit, wherein each reactor undergoes adsorption and regeneration in sequence and alternately with the other reactor, changing the steps automatically when the scrubbing solution becomes saturated with carbon dioxide and the solution, rich in carbon dioxide, becomes regenerated.