Moisture curable polyurethane polymers
First Claim
1. A method for making a moisture curable polyurethane polymer having terminal isocyanate groups and pendant silane groups having at least one hydrolyzable alkoxy group bonded to silicon, which method comprises reacting(1) an isocyanatosilane adduct having at least two isocyanato groups and(2) an isocyanate different from (1) and having at least two isocyanato groups with(3) a polyol,said isocyanatosilane adduct being the reaction product of an isocyanate having at least three isocyanato groups with an organofunctional alkoxysilane.
4 Assignments
0 Petitions
Accused Products
Abstract
Methods for making a moisture curable polyurethane polymer having terminal isocyanate groups and pendant alkoxysilane groups by reacting an isocyanatosilane adduct, having terminal isocyanate groups and at least one hydrolyzable alkoxy group bonded to silicon, with a polyisocyanate and a polyol; moisture curable polymers made by said methods; sealant compositions directly adherent to a non-porous substrate such as glass or metal without the use of a primer, said compositions comprising such a moisture curable polymer in combination with a filler; and methods for curing and using such sealant compositions.
-
Citations
18 Claims
-
1. A method for making a moisture curable polyurethane polymer having terminal isocyanate groups and pendant silane groups having at least one hydrolyzable alkoxy group bonded to silicon, which method comprises reacting
(1) an isocyanatosilane adduct having at least two isocyanato groups and (2) an isocyanate different from (1) and having at least two isocyanato groups with (3) a polyol, said isocyanatosilane adduct being the reaction product of an isocyanate having at least three isocyanato groups with an organofunctional alkoxysilane. - View Dependent Claims (2, 4, 10, 11, 12, 13, 14, 15, 16, 17, 18)
-
11. A method as in claim 10 wherein said organofunctional silane is
N,N-bis[(3-trimethoxysilyl)propyl]amine. -
12. A method as in claim 10 wherein said organofunctional silane is gamma-mercaptopropyl trimethoxy silane.
-
13. A method as in claim 1 wherein said polyol is a polyether polyol.
-
14. A method as in claim 1 wherein said polyether polyol is a mixture of a polyether diol and a polyether triol.
-
15. A method as in claim 14 wherein said polyether diol is a polyoxyalkylene diol and said polyether triol is a polyoxyalkylene triol.
-
16. A moisture curable polyurethane polymer made by the method of claim 1.
-
17. A moisture curable sealant composition comprising a polymer as in claim 16 in combination with at least one filler.
-
18. The method of accelerating the moisture cure of a sealant composition as in claim 17 which comprises mixing said sealant composition with a paste containing filler and sufficient water to react with isocyanate and alkoxysilane groups present in said composition.
-
3. A method for making a moisture curable polyurethane polymer having terminal isocyanate groups and pendant silane groups having at least one hydrolyzable alkoxy group bonded to silicon, which method comprises reacting
(1) an isocyanatosilane adduct having at least two isocyanato groups and (2) an isocyanate different from (1) and having at least two isocyanato groups with (3) a polyether polyol, said isocyanato adduct being the reaction product of an isocyanate having at least three isocyanato groups with an organofunctional mercaptoalkoxysilane or aminoalkoxysilane, the number of said pendant silane groups being from 2 to 50 equivalent percent of the total number of isocyanato groups theoretically available in said isocyanate having at least three isocyanato groups and said isocyanate (2) having at least two isocyanato groups.
Specification