Carbon molecular sieves and a process for their preparation and use

• US 4,627,857 A
• Filed: 03/07/1985
• Issued: 12/09/1986
• Est. Priority Date: 12/13/1983
• Status: Expired due to Term

• Current Assignee: Calgon Carbon Corporation (Kuraray Company Limited)
• Original Assignee: Calgon Carbon Corporation (Kuraray Company Limited)
• Inventors: Sutt, Robert F. Jr.
• Primary Examiner(s): SPITZER, ROBERT H
• Application Number:
  US06/709,467
• Time in Patent Office: 642 Days
• Field of Search: 55/68, 55/74, 55/75, 55/387, 55/389, 55/70-73
• US Class Current: 95/128
• CPC Class Codes: B01D 15/00 Separating processes involving the treatment of liquids with solid sorbents using liquid sorbents B01D11/00; ion exchange processes or materials, sorbent materials in general B01J, e.g. sorbents for chromatography B01J20/281; for investigating or analysing materials G01N30/00; Apparatus therefor
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: B01J 20/20 comprising free carbon; comprising carbon obtained by carbonising processes

Abstract

The present invention relates to a process for separating mixtures of gases or liquids containing at least two different molecular characteristics which comprise passing the liquid or gas through a carbon molecular sieve prepared from a naturally occurring substrate and selected from the group consisting of molecular sieves having:

a. an oxygen diffusivity of 800×10^-8 cm² /sec or less and a diffusivity ratio of oxygen to nitrogen of 15 to 100;

b. an oxygen diffusivity of 600×10^-8 cm² /sec or less and a diffusivity ratio of oxygen to nitrogen greater than 100; and

c. an oxygen diffusivity greater than 800×10^-8 cm² /sec and a diffusivity ratio of oxygen to nitrogen greater than 5;

where the diffusivity is measured using a starting gas pressure of one atmosphere (+/-5%) at a temperature of 25° +/-5% for 30 seconds.

Claims

1. A process for separating gas mixtures containing components of at least two different molecular diameters, molecular weights or molecular shapes comprising passing the gas through a carbon molecular sieve prepared from a naturally occurring substrate and selected from the group consisting of molecular sieves having:

(a)

(i) an oxygen diffusivity of 800×

10^-8 cm² /sec or less; and

(ii) a diffusivity ratio of oxygen to nitrogen of 15 to 100;

(b)

(i) an oxygen diffusivity of 600×

10^-8 cm² /sec or less; and

(ii) a diffusivity ratio of oxygen to nitrogen greater than 100; and

(c)

(i) an oxygen diffusivity greater than 800×

10^-8 cm² /sec; and

(ii) a diffusivity ratio of oxygen to nitrogen greater than 5;

here the diffusivity is measured using a starting gas pressure of one atmosphere (+/-5%) at a temperature of 25°

+/-5% for 30 seconds.

2. The process of claim 1, wherein said gas mixtures are selected from the group consisting of oxygen and nitrogen, oxygen and carbon dioxide, carbon dioxide and methane, oxygen and argon, ammonia and nitrogen, ammonia and methane, carbon dioxide and ethane, ammonia and argon, nitrogen and methane, carbon dioxide and argon, carbon dioxide and hydrogen sulfide, ethylene and ethane, and propylene and propane.

3. The process of claim 2, wherein said gas mixture is oxygen and nitrogen.

4. The process of claim 2, wherein said gas ixture is oxygen and carbon dioxide.

5. The process of claim 2, wherein said gas mixture is carbon dioxide and methane.

6. The process of claim 2, wherein said gas mixture is oxygen and argon.

7. The process of claim 2, wherein said gas mixture is ammonia and nitrogen.

8. The process of claim 2, wherein said gas mixture is ammonia and methane.

9. The process of claim 2, wherein said gas mixture is carbon dioxide and ethane.

10. The process of claim 2, wherein said gas mixture is ammonia and and argon.

11. The process of claim 2, wherein said gas mixture is nitrogen and methane.

12. The process of claim 2, wherein said gas mixture is carbon dioxide and argon.

13. The process of claim 2, wherein said gas mixture is carbon dioxide and hydrogen sulfide.

14. The process of claim 2, wherein said gas mixture is ethylene and ethane.

15. The process of claim 2 wherein said gas mixture is propylene and propane.

16. The process of claim 1, wherein said carbon molecular sieve has an oxygen diffusivity of 500×

10^-8 to 750×

10^-8 cm² /sec and a diffusivity ratio of oxygen to nitrogen of 15 to 75.

17. The process of claim 1, wherein said carbon molecular sieve has an oxygen diffusivity of 50×

10^-8 to 500×

10^-8 cm² /sec and a diffusivity ratio of oxygen to nitrogen of 100 to 4000.

18. The process of claim 1, wherein said carbon molecular sieve has an oxygen diffusivity of 800×

10^-8 to 3000×

10^-8 cm² /sec and a diffusivity ratio of oxygen to nitrogen of 9 to 400.

19. The process of claim 1, wherein said carbon molecular sieve has an oxygen diffusivity of greater than 800×

10^-8 cm² /sec, a diffusivity ratio of oxygen to nitrogen greater than 5 and a carbon dioxide diffusivity greater than 200×

10^-8 cm² /sec.

20. The process of claim 19, wherein said carbon molecular sieve has an oxygen diffusivity of greater than 800×

10^-8 cm² /sec, a diffusivity ratio of oxygen to nitrogen greater than 5 and a methane diffusivity greater than 0.01×

10^-8 cm² /sec.