Hazardous waste removal method and apparatus

• US 4,632,690 A
• Filed: 06/04/1985
• Issued: 12/30/1986
• Est. Priority Date: 06/04/1985
• Status: Expired due to Fees

• Current Assignee: Ronald Nelson
• Original Assignee: Glenn L. Shira, Robert E. Colwell Jr
• Inventors: Colwell, Robert E. Jr., Shira, Glenn L.
• Primary Examiner(s): LINDSAY JR, ROBERT
• Application Number:
  US06/741,246
• Time in Patent Office: 574 Days
• Field of Search: 65/134, 65/135, 65/136, 65/335, 65/347, 422/168, 501/155
• US Class Current: 588/314
• CPC Class Codes: B09B 3/29 involving a melting or softening step
• CPC Class Codes: C03B 5/005 of glass-forming waste materials disposal or transformation of solid waste in general B09B; treatment of radioactive waste G21F9/00
• CPC Class Codes: C03B 5/04 in tank furnaces C03B5/02 takes precedence
• CPC Class Codes: C03B 5/235 Heating the glass C03B5/02, C03B5/18, C03B5/225 take precedence
• CPC Class Codes: G21F 9/14 by incineration; by calcination, e.g. desiccation
• CPC Class Codes: G21F 9/32 by incineration

Abstract

A method and apparatus for the high temperature destruction by pyrolysis and incineration of organic and inorganic gaseous, liquid, and solid toxic and hazardous compounds. The apparatus has a melting chamber and a combustion chamber wherein solid, sludge liquid and gaseous compounds are separately or simultaneously eliminated. In the melting chamber of the apparatus, a molten mass media operates at temperatures between 2200 and 2900 degrees F. Directly above the molten mass a flame impinges upon the molten surface at a temperature of 3000 degrees F. and above. Solid, liquid, and gaseous hazardous wastes are introduced into the melting chamber either on or beneath the surface of the molten mass wherein the waste is destroyed. Due to the operating sequence of the apparatus, the liquid and solid waste compounds may be in the molten mass in excess of eight hours. In addition, hazardous liquids may be mixed with liquid fuels and introduced into the upper combustion chamber as the combustion media at temperatures of 3000 degrees F. Hazardous gases and particulate may also be introduced into the upper combustion chamber and mixed with the gases in the combustion media and are in the chamber in excess of four seconds. The final product is cooled and may be reused in part in a subsequent charging batch.

Claims

1. In a glass making furnace having a melting chamber for melting and heating materials contained therein, a refining chamber connected to said melting chamber via a ventilated throat in a bridge wall and having a glass exit port, a first doghouse for entering materials into said melting chamber, a burner unit for melting said raw materials into a molten mass and for heating said molten mass, a first and second primary checkers chamber connected to said combustion chamber via a respective air port, a divider structure separating said primary checkers chambers and respective air ports corresponding thereto, at least one secondary checkers chamber coupled to said primary checkers chambers and to at least one stack including a flue for causing circulation of air flow in alternate directions through the combustion chamber,

the improvement comprising:

at least one hazardous gas injection port coupling to each said primary checkers chamber for injecting gaseous hazardous waste thereto;

at least one hazardous liquid injection port coupling to said melting chamber for injecting liquid hazardous wastes directly into said melting chamber.

2. A furnace according to claim 1 further comprising:

a second doghouse for entering materials into said melting chamber;

said first doghouse being located on one side of an imaginary axis coaxial with said divider structure, and adjacent a side wall of said melting chamber;

said second doghouse being located on an opposing side of said imaginary axis, and also adjacent a side wall of said melting chamber.

3. A furnace according to claim 1 or 2 further comprising a combustion chamber directly above a surface of molten mass in the melting chamber;

said burner having a first and second fuel injection nozzle respectively located on opposing sides of an imaginary axis coaxial with said divider structure, and pointed at an angle towards said surface and said bridge wall;

said first and second nozzles being activated in alternate succession to produce a series of extended flames together with air flow from a corresponding checkers chamber, in opposite directions at least partially around said combustion chamber.

4. A furnace according to claim 1 wherein there is at least one said hazardous liquid injection port on each side of an imaginary axis coaxial with said divider structure.

5. In a regenerator type glass furnace having a melting chamber, a refining chamber, a doghouse, a plurality of checkers chambers and a stack, a process for neutralizing hazardous or toxic waste material comprising the steps of:

generating a flame in a combustion chamber immediately above said melting chamber, said flame directly impinging on a surface of molten mass contained in said melting chamber and said molten mass being largely comprised of raw materials for making glass;

injecting into said molten mass in said melting chamber solid or sludge type hazardous or toxic waste material through said doghouse;

continuing heating said molten mass by said flame while circulating said molten mass in said melting chamber;

transferring said molten mass from said melting chamber to said refining chamber upon destruction of certain hazardous or toxic waste material embodied therein; and

recovering a resultant glass product from said refining chamber.

6. A process according to claim 5 wherein said flame has an average temperature of approximately 3000 degrees F. and said molten mass has a temperature of from approximately 2300 degrees F. to 2900 degrees F.

7. A process according to claim 6 and further comprising:

injecting liquid hazardous waste material into said molten mass via at least one liquid injection port in said melting chamber of said furnace.

8. A method according to claim 7 further comprising:

directing air flow from one of said checkers chamber through said combustion chamber to another of said checkers chamber, by means of said stack; and

injecting gaseous hazardous waste material into said one of said checkers chambers for introduction to said combustion chamber through at least one gaseous waste injection port.

9. A process according to claim 8 and further comprising:

reversing direction of said air flow at regular intervals.

10. A process according to claim 9 wherein said flame extends in a direction corresponding to current air flow.

11. A process according to claim 5, 7 or 8 and further comprising:

mixing combustion fuel with liquid hazardous or toxic waste material;

spraying said mixture from at least one fuel nozzle into said combustion chamber.

12. A process according to claim 5 or 8 further comprising the following step:

recycling at least a portion of said recovered glass product into said melting chamber via said at least one doghouse.

13. A process according to claim 5 or 8 further comprising the following step:

recycling said recovered glass product into said melting chamber via said at least one doghouse.

14. A process according to claim 5 further comprising the following step:

ventilating said molten mass as it passes from said melting chamber to said refining chamber.

15. A process according to claim 8 wherein said furnace comprises two doghouses spaced across said melting chamber and whereby said injecting step for solid or sludge type hazardous or toxic waste material comprising the further step of:

selectively employing a respective one of said two doghouses depending on which one is upstream of said air flow.

16. A process according to claim 8 whereby the dwell time of said injected gaseous waste material in said furnace is at least 8 seconds.

17. A process according to claim 12 wherein said recovered glass product is cooled prior to recycling.