Epoxy resin composition

• US 4,632,970 A
• Filed: 12/02/1985
• Issued: 12/30/1986
• Est. Priority Date: 04/01/1985
• Status: Expired due to Term

• Current Assignee: Yokohama Rubber Company Limited
• Original Assignee: Yokohama Rubber Company Limited
• Inventors: Hiza, Misao, Yamazaki, Hajime, Omote, Shigeo
• Primary Examiner(s): Welsh, Maurice J.
• Application Number:
  US06/803,701
• Time in Patent Office: 393 Days
• Field of Search: 528/27, 525/460
• US Class Current: 528/27
• CPC Class Codes: C08G 18/10 Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
• CPC Class Codes: C08G 18/2845 Monohydroxy epoxy compounds
• CPC Class Codes: C08G 18/58 Epoxy resins C08G18/42, C08G18/48 take precedence; reaction products of epoxy resins with at least equivalent amounts of compounds containing active hydrogen C08G18/6407, with at least equivalent amounts of amines C08G18/6415; polymeric products of isocyanates or isothiocyanates with epoxy compounds having no active hydrogen C08G18/003
• CPC Class Codes: C08G 18/61 Polysiloxanes
• CPC Class Codes: C08G 59/02 Polycondensates containing more than one epoxy group per molecule
• CPC Class Codes: C08G 59/28 containing acyclic nitrogen atoms
• CPC Class Codes: C08G 59/306 containing silicon
• CPC Class Codes: C08G 77/42 Block-or graft-polymers containing polysiloxane sequences polymerising aliphatic unsaturated monomers on to a polysiloxane C08F283/12

Abstract

An epoxy resin composition comprising:

(a) a urethane modified epoxy resin obtained by reacting a compound having both epoxy and hydroxy groups with a urethane bond containing compound having an isocyanate group at the end thereof, which is obtained from (i) an organopolysiloxane compound having a molecular weight of 500 to 10000 and having at least two hydroxy groups per one molecule in the main chain or side chain thereof and (ii) a polyisocyanate compound; and

(b) an active organic curing agent.

Claims

1. An epoxy resin composition comprising:

(a) a urethane modified epoxy resin obtained by reacting a compound having both epoxy and hydroxy groups with a urethane bond containing compound having an isocyanate group at the end thereof, which is obtained from (i) an organopolysiloxane compound having a molecular weight of 500 to 10000 and having at least two hydroxy groups per one molecule in the main chain or side chain thereof and (ii) a polyisocyanate compound; and

(b) an active organic curing agent.

2. An epoxy resin composition as claimed in claim 1, wherein the organopolysiloxane compound has the following general formula:

##STR2## wherein R¹ and R² are independently H, CH₃, C₆ H₅, or CF₃ CH₂ CH₂ and R³ is an alkylene group or an oxyalkylene group having 1 to 10 carbon atoms.

3. An epoxy resin composition as claimed in claim 1, wherein the polyisocyanate compound has two or more isocyanate groups in the molecule.

4. An epoxy resin composition as claimed in claim 1, wherein the ratio of the hydroxy group of the organopolysiloxane compound to the isocyanate group of the polyisocyanate is from 0.75 to 0.95.

5. An epoxy resin composition as claimed in claim 1, wherein the compound having both epoxy and hydroxy groups has 1 to 3 epoxy groups and 1 to 2 hydroxy groups.

6. An epoxy resin composition as claimed in claim 5, wherein the molecular weight of the compound is 50 to 2000.

7. An epoxy resin composition as claimed in claim 1, wherein the ratio of the hydroxy group of said compound having both epoxy and hydroxy groups to the isocyanate group of said urethane bond containing compound is from 1.0 to 1.2.

8. An epoxy resin composition as claimed in claim 1, wherein the curing agent is at least one member selected from the group consisting of aliphatic amines, aromatic amines, alicyclic polyamides, polyamides, amino resins, acid anhydrides, and modified aromatic polyamines.

9. An epoxy resin composition as claimed in claim 8, wherein the amount of said curing agent is 0.1 to 1.2 amine equivalent based on one epoxy equivalent of the urethane modified epoxy resin.