Apparatus and method for use in thermoelectric power generation

• US 4,633,029 A
• Filed: 02/07/1985
• Issued: 12/30/1986
• Est. Priority Date: 02/07/1985
• Status: Expired due to Fees

• Current Assignee: Applied Automation, Inc. (Massman Automation Designs LLC)
• Original Assignee: Phillips Petroleum Company (ConocoPhillips)
• Inventors: Tillett, George C. Jr., Holland, Gary V.
• Primary Examiner(s): Terapane, John F.
• Assistant Examiner(s): Wallen, T. J.
• Application Number:
  US06/699,287
• Time in Patent Office: 691 Days
• Field of Search: 136/205-212, 431/350-352, 431/268
• US Class Current: 136/205
• CPC Class Codes: H10N 10/00 Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects integrated devices or assemblies of multiple devices H10N19/00

Abstract

An apparatus and method for generating thermoelectric power utilizes a hollow shell member having a cavity defined therein and a cartridge member disposed within the cavity, wherein the cartridge member has a combustion chamber defined therein. The cartridge member is mounted such that a space exists between the interior surface of the shell member and the exterior surface of the cartridge member. Thermoelectric elements are mounted to the exterior surface of the shell member such that no air spaces exist therebetween. A mixture of a combustible fuel and air is introduced into the chamber, the air/fuel ratio being less than the stoichiometric ratio for methane. Heat generated within the combustion chamber upon combustion of the fuel is transferred via the shell member to the thermoelectric elements which generate electrical energy in response thereto.

Claims

1. A thermoelectric generator apparatus comprising:

a hollow shell member having an interior surface and an exterior surface, said interior surface defining a cavity;

a hollow cartridge member disposed within said cavity, at least a portion of said cartridge member having an interior surface which defines a combustion chamber, said cartridge member also having an exterior surface and first and second radially extending generally annular flanges, each flange being in contact with said shell member interior surface around at least a portion of its circumference so as to define a generally annular space between said flanges and between said shell member interior surface and said cartridge member exterior surface;

a means for introducing a mixture of fuel and oxidant gas into said combustion chamber;

at least one thermoelectric element in direct thermal contact with the exterior surface of said shell member such that substantially no air spaces exist between said shall member exterior surface and said at least one thermoelectric element, said at least one thermoelectric element being adapted for generating electrical energy when receiving heat from said shell member.

2. An apparatus as recited in claim 1, wherein said space between said flanges extends around the circumference of said cartridge member portion.

3. An apparatus as recited in claim 2, wherein said space between said flanges extends along substantially the entire length of said cartridge member portion

4. An apparatus as recited in claim 3, wherein said cartridge member portion defining said chamber is denoted as a first cartridge member portion, and wherein said cartridge member includes a second portion, said second portion having at least one passage having a first end and a second end, said passage first end being in fluid communication with said chamber and said passage second end being in fluid communication with points beyond the apparatus.

5. An apparatus as recited in claim 4, wherein said cartridge member has an axis, a first end and a second end, said first portion axially extending from said cartridge member first end to said second portion and said second portion axially extending from said first portion to said cartridge member second end, and wherein said first flange extends from said cartridge member first end and said second flange extends from said cartridge member second end, and wherein points of contact between said flanges and said shell member interior surface are the sole points of contact between said cartridge member and said shell member.

6. An apparatus as recited in claim 5 wherein there are a plurality of passages through said cartridge member second portion.

7. An apparatus as recited in claim 1, wherein said chamber contains a catalyst for promoting the catalytic oxidation of the fuel.

8. A method of thermoelectric power generation comprising:

positioning a hollow cartridge member, having an interior surface and an exterior surface, within a hollow shell member also having an interior surface and an exterior surface, said hollow cartridge member having first and second generally annular radially extending flanges and also having a chamber defined by the interior surface of at least a portion of said cartridge member wherein said cartridge member is positioned so that each flange contacts said shell member interior surface around at least a portion of its circumference so as to define a generally annular space between said flanges and between said shell member interior surface and said cartridge member exterior surface;

generating heat within said chamber;

providing heat generated in said chamber to at least one thermoelectric element in direct thermal contact with the exterior surface of said shell member such that substantially no air spaces exist between said shell member exterior surface and said at least one thermoelectric element.

9. A method as recited in claim 8 wherein said heat generating step includes:

introducing a mixture of a combustible fuel and an oxidant gas into said chamber; and

combusting said mixture.

10. A method as recited in claim 9, wherein the oxidant gas is air, and the air/fuel ratio of the mixture is less than the stoichiometric ratio for methane.

11. An apparatus comprising:

a hollow shell member having an interior surface and an exterior surface;

a hollow cartridge member generally coaxially disposed within said shell member, said cartridge member having an exterior surface, an interior surface of which at least a portion defines a combustion chamber within said cartridge member, and at least one radially extending flange which contacts the interior surface of said shell member around at least a portion of the circumference of said at least one flange so that a space is defined by said flange and between said shell member interior surface and said cartridge member exterior surface, said space extending substantially around the circumference of said cartridge member;

a means for introducing a combustible mixture into said combustion chamber;

a means for igniting combustible mixture introduced to said combustion chamber so as to initiate combustion of said mixture to thereby generate heat;

at least one thermoelectric element in direct thermal contact with the exterior surface of said shell member, said thermoelectric element being adapted for generating electrical energy upon receiving heat from said shell member.

12. An apparatus as recited in claim 11, wherein points of contact between said at least one flange and said shell member interior surface are the sole points of contact between said cartridge member and said shell member.

13. An apparatus as recited in claim 12, wherein said cartridge member has a first portion, a second portion, a first open end and a second open end, the interior surface of said first portion defining said combustion chamber, wherein said first portion axially extends from said first end to said second portion and wherein said second portion axially extends from said first portion to said second end, said second portion having at leat one exhaust passage therethrough which communicates with said combustion chamber.

14. An apparatus as recited in claim 13, wherein said combustion chamber contains a bed of catalyst particles.

15. An apparatus as recited in claim 14, wherein said combustible mixture introducing means is adapted to introduce said mixture into said first open end for combustion of said mixture in said chamber and exhaust of gases through said at least one exhaust passage.

16. An apparatus as recited in claim 15, wherein at least a portion of said cartridge member interior surface defines a generally frustoconical passage positioned between and so as to communicate with said combustion chamber and said at least one exhaust passage.

17. An apparatus as recited in claim 16, wherein said combustible mixture introducing means includes:

a fuel gas inlet passage formed within said shell member;

a nozzle, having an orifice, positioned within said inlet passage for receiving fuel gas therethrough;

a venturi passage formed within said shell member and having a longitudinal axis which is generally aligned with said nozzle orifice, said venturi passage being in communication with said combustion chamber and said fuel gas inlet passage; and

an oxidant gas passage formed within said shell member and having one end connected to said venturi passage.

18. A method of thermoelectric power generation comprising:

positioning a hollow cartridge member generally coaxially within a hollow shell member, said cartridge member having a combustion chamber therein and at least one radially extending flange, said cartridge member being positioned so that said at least one flange contacts, around at least a portion of its circumference, the interior surface of said shell member so as to define a space between the exterior surface of said cartridge member and the interior surface of said shell member, the space extending around the circumference of said cartridge member;

combusting a combustible mixture in said combustion chamber to thereby generate heat;

providing said heat to at least one thermoelectric element in direct thermal contact with the exterior surface of said shell member, said element generating electrical energy.