Electrochemical apparatus and method of manufacturing the same

• US 4,634,514 A
• Filed: 02/07/1986
• Issued: 01/06/1987
• Est. Priority Date: 02/14/1985
• Status: Expired due to Term

• Current Assignee: NGK Insulators Limited
• Original Assignee: NGK Insulators Limited
• Inventors: Shibata, Kazuyoshi, Nishizawa, Hitoshi
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US06/827,107
• Time in Patent Office: 333 Days
• Field of Search: 204/406, 204/425, 204/1 S, 204/412, 29/592 R
• US Class Current: 204/406
• CPC Class Codes: G01N 27/4065 Circuit arrangements specially adapted therefor
• CPC Class Codes: G01N 27/407 for investigating or analysing gases G01N27/411 takes precedence
• CPC Class Codes: G01N 27/417 using cells , i.e. more than one cell and probes with solid electrolytes
• CPC Class Codes: Y10T 29/49002 Electrical device making

Abstract

In an electrochemical apparatus utilizing an electrochemical cell having a solid-electrolyte and at least one pair of porous electrodes arranged in contact with the solid-electrolyte, wherein one electrode of the pair of electrodes is exposed through a diffusion means having a diffusion resistance with respect to a gas to be measured in a space in which the gas to be measured is present, and an atmosphere near one of the electrodes is controlled by an electrode reaction due to a current flowing through the pair of electrodes, a first branch conductor and a second branch conductor are formed by dividing one of conductors respectively connected to the electrodes, and at least one adjustable first resistive means and at least one second resistive means are respectively formed in the first branch conductor and the second branch conductor. Therefore, a predetermined current flows through either the first or second resistive means, and thus it is possible to obtain the electrochemical apparatus which maintains a constant quality in large scale manufacturing.

Claims

1. An electrochemical apparatus utilizing an electrochemical cell having a solid-electrolyte and at least one pair of porous electrodes arranged in contact with said solid-electrolyte, wherein one of said pair of electrodes is exposed through a diffusion means having a diffusion resistance to a gas to be measured to a space in which the gas to be measured is present, and an atmosphere near said one of the electrode is controlled by an electrode reaction due to a current flowing through said one pair of electrodes, comprising:

a first branch conductor and a second branch conductor formed by dividing one of conductors respectively connected to said electrodes and arranged connectably to an external power source;

at least one first resistive means formed in said first branch conductor, a resistive value of which can be arbitrarily adjusted; and

at least one second resistive means formed in said second branch conductor;

whereby a predetermined current corresponding to a predetermined concentration of the gas to be measured flows through one of said first or second resistive means.

2. An electrochemical apparatus according to claim 1, further comprising a current measurement means for measuring the current flowing through one of said first resistive means and second resistive means, whereby an output of said current measurement means is used for a detection of gas concentration of the gas to be measured.

3. An electrochemical apparatus according to claim 1, further comprising a current measurement means connected in series to one of said first resistive means and second resistive means, whereby an output of said current measurement means is used for detecting gas concentration of the gas to be measured.

4. An electrochemical apparatus according to claim 1, wherein said first resistive means and said second resistive means are integrally formed on said solid electrolyte.

5. An electrochemical apparatus according to claim 1, wherein temperature coefficients of respective first resistive means and second resistive means are substantially equal to each other.

6. An electrochemical apparatus according to claim 1, further comprising a second solid-electrolyte and a second electrochemical cell having a pair of porous electrodes and arranged in contact with said second solid-electrolyte, such that one of said pair of electrodes is exposed through said diffusion means to a space in which the gas to be measured is present.

7. A method of manufacturing an electrochemical apparatus utilizing an electrochemical cell having a solid-electrolyte and at least one pair of porous electrodes arranged in contact with said solid-electrolyte, wherein one of said pair of electrodes is exposed through a diffusion means having a diffusion resistance to a gas to be measured in a space in which the gas to be measured is existent, and an atmosphere near said one of the electrodes is controlled by an electrode reaction due to a current flowing through said one pair of electrodes, comprising the steps of:

forming a first branch conductor and a second branch conductor by dividing one of conductors respectively connected to said electrodes;

forming at least one first resistive means in said first branch conductor, a resistive value of which can be arbitrarily adjusted;

forming at least one second resistive means in said second branch conductor; and

adjusting the resistive value of said first resistive means to a predetermined value so as to obtain a predetermined output in response to a component concentration of the gas to be measured from a current through one of said first branch conductor and second branch conductor.

8. A method of manufacturing the electrochemical cell according to claim 7, wherein said first resistive means and said second resistive means are integrally formed on said solid-electrolyte.

9. A method of manufacturing the electrochemical cell according to claim 7, wherein temperature coefficients of respective first resistive means and second resistive means are substantially equal to each other.

10. An electrochemical apparatus including a connector portion for use in connection with an external power source and an electrochemical cell having a solid-electrolyte arranged in contact with said solid-electrolyte, wherein one of said pair of electrodes is exposed through a diffusion means having a diffusion resistnce with respect to a gas to be measured to a space in which the gas to be measured is existent, and an atmosphere near said one of the electrodes is controlled by an electrode reaction due to a current flowing through said one pair of electrodes, comprising:

a first branch conductor and a second branch conductor formed by dividing one of conductors respectively connected to said electrodes and arranged connectably to the external power source through said connector portion;

at least one first resistive means arranged between said electrochemical cell and said connector portion, a resistive value of which can be arbitrarily adjusted; and

at least one second resistive means formed in said second branch conductor, whereby a predetermined current corresponding to a predetermined concentration of the gas to be measured flows through one of said first or second resistive means.

11. An electrochemical apparatus according to claim 10, wherein both said first resistive means and said second resistive means are arranged between said electrochemical cell and said connector portion.

12. An electrochemical apparatus according to claim 10, wherein said a portion of the resistive means and the branch conductor arranged between said electrochemical cell and said connector portion are arranged in a protective cover of said electrochemical cell.

13. An electrochemical apparatus according to claim 10, wherein a portion of the resistive means and the branch conductor arranged between said electrochemical cell and said connector portion are arranged in said connector cell.

14. An electrochemical apparatus according to claim 10, wherein a portion of the resistive means and branch conductor arranged between said electrochemical cell and said connector portion are arranged in a connection line between said electrochemical cell and said connector portion.