Process for drying a chelating agent

• US 4,636,336 A
• Filed: 11/02/1984
• Issued: 01/13/1987
• Est. Priority Date: 11/02/1984
• Status: Expired due to Fees

• Current Assignee: Rockwell International Corporation
• Original Assignee: Rockwell International Corporation
• Inventors: Grantham, LeRoy F., Gay, Richard L.
• Primary Examiner(s): Lechert, Jr., Stephen J.
• Assistant Examiner(s): Locker, Howard J.
• Application Number:
  US06/667,784
• Time in Patent Office: 802 Days
• Field of Search: 252/626, 252/631, 252/632, 252/628, 252/629, 159/47.3, 159/DIG. 12, 501/152, 110/237, 110/238, 110/342, 110/346, 110/343, 110/345
• US Class Current: 588/18
• CPC Class Codes: G21F 9/14 by incineration; by calcination, e.g. desiccation
• CPC Class Codes: Y10S 159/12 Radioactive

Abstract

A process is described for reducing the volume of a liquid waste containing an organic amine chelating agent in which a finely atomized spray of the liquid waste is contacted with a gas stream having a temperature in excess of the thermal decomposition temperature of the chelating agent. The proportions of the hot gas stream and liquid waste are controlled to rapidly evaporate water from the liquid waste and cool the gas to a temperature below the decomposition temperature of the chelating agent in a time of less than about 6 seconds to produce a dry, flowable powder product including the chelating agent.

Claims

1. A process for reducing the volume of a low-level radioactive liquid waste containing an organic amine chelating agent comprising:

burning a fuel and an oxygen-containing gas to produce a hot gas stream having a temperature in excess of the thermal decomposition temperature of the chelating agent;

introducing the hot gas stream into a spray drying zone;

introducing a finely atomized spray of said liquid waste into said spray drying zone and into intimate contact with said hot gas stream;

controlling the proportions of said hot gas stream and said liquid waste to rapidly evaporate water from said liquid waste and cool said hot gas to a temperature below the decomposition temperature of said chelating agent in a time of less than six seconds to produce (a) a dry, flowable powder product including said chelating agent, and (b) a product gas substantially free of any gaseous products of said chelating agent and volatile fission products of the radioactive constituents of said liquid waste; and

separating said powder product from said product gas.

2. The process of claim 1 wherein said chelating agent is an organic amine acid compound.

3. The process of claim 2 wherein said chelating agent is selected from the group consisting of EDTA, DTPA, HEDTA and NTA.

4. The process of claim 3 wherein said hot gas stream has a temperature within the range of 250°

to 400°

C.

5. The process of claim 4 wherein said hot gas is cooled to a temperature of from about 150°

to 200°

C. in a time within the range of from about 1 to 6 seconds.

6. The process of claim 5 wherein said time is within the range of from about 1.5 to 3 seconds.

7. The process of claim 6 wherein said chelating agent is EDTA.

8. The process of claim 5 wherein the gas is further cooled to a temperature of less than about 90°

C. prior to separating said powder product from said product gas.