Flame retarded polyester molding composition with improved electrical performance

• US 4,636,544 A
• Filed: 02/25/1985
• Issued: 01/13/1987
• Est. Priority Date: 02/25/1985
• Status: Expired due to Term

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Hepp, Leonard R.
• Primary Examiner(s): Ivy, C. Warren
• Application Number:
  US06/705,446
• Time in Patent Office: 687 Days
• Field of Search: 524/605, 524/413, 524/411, 524/281, 524/371, 524/537
• US Class Current: 524/411
• CPC Class Codes: C08K 3/2279 of antimony
• CPC Class Codes: C08L 67/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds C08L67/06 takes precedence

Abstract

Titanium dioxide is disclosed to improve the comparative tracking index of flame retarded poly(1,4-butylene terephthalate) resin molding compositions.

Claims

1. A flame retarded poly(1,4-butylene terephthalate) resin molding composition having an improved comparative tracking index consisting essentially of:

(a) poly(1,4-butylene terephthalate) resin;

(b) a flame retarding amount of halogenated aromatic flame retardant;

(c) an effective amount of antimony compound synergist; and

(d) an effective amount of titanium dioxide powder to raise the comparative tracking index of said molding composition, said effective amount being from about 3.5 to about 6.5 parts by weight of said titanium dioxide powder for each 85 parts by weight of said poly (1,4-butylene terephthalate) resin and said halogenated aromatic flame retardant.

2. The molding composition of claim 1 wherein said halogenated aromatic flame retardant is an aromatic carbonate homopolymer.

3. The molding composition of claim 1 which additionally contains a reinforcing amount of glass fiber.

4. The molding composition of claim 1 which additionally contains an impact modifying amount of impact modifier.

5. The molding composition of claim 1 which additionally contains up to 80 weight parts of another thermoplastic resin per 20 weight parts poly(1,4-butylene terephthalate) resin.

6. A flame retarded poly(1,4-butylene terephthalate) resin molding composition having an improved comparative tracking index consisting essentially of:

(a) poly(1,4-butylene terephthalate) resin;

(b) a flame retarding amount of halogenated aromatic flame retardant;

(c) an effective amount of antimony compound synergist;

(d) from about 3.5 to about 6.5 parts by weight titanium dioxide for each 85 parts by weight resin and halogenated aromatic flame retardant; and

(e) a reinforcing amount of glass fiber.

7. A flame retarded poly(1,4-butylene terephthalate) resin molding composition having an improved comparative tracking index consisting essentially of:

(a) poly(1,4-butylene terephthalate) resin;

(b) a flame retarding amount of halogenated aromatic flame retardant;

(c) an effective amount of antimony compound synergist; and

(d) an amount of titanium dioxide powder effective to raise the comparative tracking index of said molding composition to at least 575 volts, said effective amount of titanium dioxide powder being from about 3.5 to about 6.5 parts by weight for each 85 parts by weight of said poly(1,4-butylene terephthalate) resin and said halogenated aromatic flame retardant.