Method of making yttrium silicon oxy compound

• US 4,640,826 A
• Filed: 12/24/1985
• Issued: 02/03/1987
• Est. Priority Date: 12/24/1985
• Status: Expired due to Fees

• Current Assignee: Ceradyne Advanced Products, Inc.
• Original Assignee: Ford Motor Company
• Inventors: Williams, Robert M., Beckwith, Elaine C.
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US06/813,168
• Time in Patent Office: 406 Days
• Field of Search: 423/263, 423/326
• US Class Current: 423/263
• CPC Class Codes: C01B 33/20 Silicates persilicates C01B15/14 ; containing aluminium C01B33/26

Abstract

A method is disclosed of making yttrium silicon oxy compounds, comprising: (a) mixing powdered hydrated metal nitrate with silica in molar equivalent amounts to yield upon heating a desired duo metal oxy compound; (b) agitatingly heating said mixture to melt and decomposition temperatures for the nitrate (e.g., 340°-370° C.), the melt encapsulating the silica particles; and (c) heating the sludge to a temperature (1300°-1550° C.) for a period of time (2-5 hours) effective to stimulate chemical reaction between the decomposed nitrate and silica to form yttrium silicon oxide.

Claims

1. A method of making a duo metal oxy compound, comprising:

(a) mixing a powdered hydrated nitrate of a metal selected from the group consisting of cerium and yttrium with silica in molar equivalent amounts to yield, upon heating, a dual oxide compound of silicon and said metal;

(b) agitatingly heating said mixture to the melt and the decomposition temperature of the nitrate; and

(c) heating said mixture resulting from step (b) to a temperature from 1300°

to 1550°

C. and for a period of time from 2 to 5 hours, and sufficient for the silica and decomposed metal nitrate to chemically react and form a dual oxide compound of silicon and said metal.

2. The method as in claim 1, in which said metal nitrate is yttrium nitrate.

3. The method as in claim 2, in which said molar equivalent amounts for said nitrate and SiO₂ are in a ratio of 2:

1 in order to form Y₂ SiO₅.

4. The method as in claim 2, in which the molar equivalent amounts for said nitrate and silica are in a ratio of 1:

1 to form Y₂ Si₂ O₇.

5. The method as in claim 2, in which said heating of step (b) is carried out to the temperature range of 340°

-370°

C. for a period of 50-75 minutes in order to drive off water vapor and mixed nitrogen oxides from said nitrate thereby decomposing said nitrate and leaving a melted residue.

6. The method as in claim 5, in which said decomposed nitrate is YN_a O_b where a is 1-2 and b is 1, 2 or 4.

7. The method as in claim 1, in which the powder mixture is intimately mixed.

8. The method as in claim 1, in which said hydrated metal nitrate is selected from the group consisting of tri, tetra and hexahydrated yttrium nitrate, and tri and hexahydrated cerium nitrate.

9. The method as in claim 1, in which the heating in step (c) is under inert conditions and at a pressure just above atmospheric pressure.

10. The method as in claim 1, in which the reaction of step (c) is complete essentially to 90%.