Method and device for compensating temperature-dependent characteristic changes in ion-sensitive FET transducer

• US 4,641,249 A
• Filed: 06/19/1984
• Issued: 02/03/1987
• Est. Priority Date: 06/22/1983
• Status: Expired due to Term

• Current Assignee: Kuraray Company Limited No 1621 Sakazu Kurashiki-Shi Okayama-Ken
• Original Assignee: Kuraray Company Limited
• Inventors: Gion, Hidenori, Nakamura, Michihiro, Yano, Makoto, Kubota, Kenji
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US06/622,250
• Time in Patent Office: 959 Days
• Field of Search: 364/496, 364/497, 364/571, 364/550, 204/406, 204/408, 204/412, 204/416, 357/25, 324/438, 324/425, 324/459, 128/635
• US Class Current: 702/25
• CPC Class Codes: G01N 27/4148 Integrated circuits therefor, e.g. fabricated by CMOS processing CMOS processing per se H01L21/82

Abstract

An ion activity monitoring device is disclosed, having a semi-conductor device including an ion-sensitive field-effect transistor, for detecting the activity of ions in a liquid medium of interest, and a temperature sensor, for detecting the temperature of the liquid medium of interest, a constant current circuit for supplying a drain current of a particular value to the transistor, and a processing circuit for calculating the concentration of the ions in the liquid medium of interest. The drain current is of a value satisfying the relationship of |Id/β|≦0.10 volt², wherein Id represents the drain current and β represents the channel characteristic value of the ion-sensitive field-effect transistor. A method for operating the transistor is also disclosed.

Claims

1. An ion activity monitoring device which comprises:

a semi-conductor device including,

an ion-sensitive field-effect transistor for detecting the activity of ions in a liquid medium of interest, and developing an ion activity signal indicative thereof, and

a temperature sensor for detecting the temperature of the liquid medium of interest and developing a temperature signal indicative thereof;

a constant current circuit for supplying to the ion-sensitive field-effect transistor a drain current satisfying the following relationship;

space="preserve" listing-type="equation">|Id/β

|≦

0.10 volt.sup.2

wherein Id represents the drain current and β

represents the channel characteristic value of the ion-sensitive field-effect transistor during the operation thereof; and

a processing circuit, responsive to both the ion activity signal from the ion-sensitive field-effect transistor and the temperature signal from the temperature sensor, for calculating the concentration of the ions in the liquid medium of interest, said processing circuit including,

temperature zero-adjustment compensating means for effecting a zero adjustment to the ion activity signal from the ion-sensitive field-effect transistor, and a zero adjustment to the temperature, signal from the temperature sensor, and

temperature sensitivity compensating means for adjusting the sensitivity of the monitoring device to the ion activity, based on both the ion activity signal and the temperature signal.

2. A device as claimed in claim 1, wherein said processing circuit is a digital processor.

3. A device as claimed in claim 1, wherein said processing circuit is an analog processor.

4. The device of claim 1, wherein said zero-adjustment compensating means includes:

difference signal generator means for producing a first difference signal V_s -Vsoo indicative of a difference between an electric potential, Vs, at a source of said ion-sensitive field-effect transistor, Vs being indicative of a measured pH value at a measured temperature T, and a reference electric potential, Vsoo, indicative of a reference pH value at a reference temperature To; and

temperature zeroing means for producing a temperature difference signal D-Do, said temperature difference signal being indicative of a difference between the measured temperature T and the reference temperature To.

5. The device of claim 4 wherein said zero-adjustment compensating means further includes:

a multiplexer selectively applying either said first difference signal or said temperature difference signal to an input of an analog to digital converter, said analog to digital converter producing an output signal that is a digital representation of the selected input to the analog to digital converter.

6. The device of claim 5 wherein said temperature sensitivity compensating means includes:

digital processing means for storing a plurality of reference values and for producing a display of the ion activity of the liquid medium based on receipt of the output signal of the analog to digital converter and said plurality of reference values stored in the digitial processing means.

7. The device of claim 4 wherein said zero-adjustment compensating means further includes:

first converter means for converting said temperature difference signal D-Do into a second difference signal dT;

multiplying means for multiplying said second difference signal by a predetermined temperature constant signal, A, to produce a signal AdT; and

adding means for adding said first difference signal and said signal AdT to produce zero-adjustment output signal Vs-Vsoo-AdT.

8. The device of claim 7 wherein said temperature sensitivity compensating means includes;

second converter means for converting said second difference signal, dT, by multiplying dT by a sensitivity correcting coefficient signal, Ko to produce a product signal and dividing the product signal by the reference temperature signal To, thereby producing second converter means output KodT/To;

second adding means for adding said sensitivity correcting coefficient signal Ko to said second converter means output to produce a second adding means output signal Ko(1+dT/To); and

dividing means for producing a temperature sensitivity compensating output signal by dividing said zero-adjustment output signal by said second adding means output signal, said temperature sensitivity compensating output signal being equal to (Vs-Vsoo-AdT)/Ko(1+dT/To).

9. The device of claim 8 wherein said processing circuit further includes:

an ion concentration processing circuit providing the concentration of ions in the liquid medium as a pH value from said temperature sensitivity compensating output signal by adding a reference pH value signal (pH)o to said temperature sensitivity compensating output signal.