Process for producing reinforced microporous membrane

• US 4,645,602 A
• Filed: 09/17/1984
• Issued: 02/24/1987
• Est. Priority Date: 12/18/1981
• Status: Expired due to Term

• Current Assignee: Cuno Incorporated (3M Company)
• Original Assignee: Cuno Incorporated (3M Company)
• Inventors: Meyering, Mark T., Barnes, Robert G. Jr.
• Primary Examiner(s): SPEAR JR, FRANK
• Application Number:
  US06/651,376
• Time in Patent Office: 890 Days
• Field of Search: 210/490, 210/489, 210/491, 210/346, 210/500.2, 210/500.38, 427/244, 427/245, 427/246, 264/41, 264/175, 264/45.1
• US Class Current: 210/490
• CPC Class Codes: A61L 2/022 Filtration
• CPC Class Codes: B01D 2313/22 Cooling or heating elements
• CPC Class Codes: B01D 61/147 Microfiltration
• CPC Class Codes: B01D 63/00 Apparatus in general for separation processes using semi-permeable membranes
• CPC Class Codes: B01D 69/108 Inorganic support material
• CPC Class Codes: B01D 69/1213 Laminated layers
• CPC Class Codes: B01D 69/1216 Three or more layers
• CPC Class Codes: B01D 71/56 Polyamides, e.g. polyester-amides
• CPC Class Codes: B29B 15/122 with a matrix in liquid form, e.g. as melt, solution or latex
• CPC Class Codes: B29C 70/086 and with one or more layers of pure plastics material, e.g. foam layers applying a non-preformed coating, e.g. a gel-coat, B29C37/0025; with foam blocks B29C70/86
• CPC Class Codes: B29K 2105/04 cellular or porous
• CPC Class Codes: B29K 2105/045 with open cells
• CPC Class Codes: B29L 2009/00 Layered products
• CPC Class Codes: B29L 2031/14 Filters optical filters B29L2011/0066, sieves or screens B29L2031/737
• CPC Class Codes: B29L 2031/755 Membranes, diaphragms
• CPC Class Codes: B32B 27/12 next to a fibrous or filamentary layer

Abstract

A process for producing an integral single layer polymeric microporous filter membrane within which a reinforcing web is embedded. The process comprises passing a reinforcing web through a first reservoir of casting solution of polymer and then simultaneously calendering both sides of the coated web to provide for penetration of the solution into the web and to remove substantially all entrapped air from the web. The calendered reinforcing web is then passed through a second reservoir of casting solution and then through a quenching bath to form micropores throughout the coatings.

Claims

1. A process for producing an integral single layer polymeric microporous filter membrane within which a reinforcing web is embedded, comprising:

(a) preparing a first and second reservoir of a casting solution of a polymer in a solvent system comprising a mixture of at least one solvent and one non-solvent for the polymer, the amount of non-solvent being no greater than an amount required to induce nucleation of the solution to obtain a visible precipitate;

(b) passing a reinforcing web through the first reservoir, completely surrounding the web with casting solution and depositing a sufficient amount of the solution onto the web to completely coat the web;

(c) directly passing the coated web from step (b) through a calendering means to simultaneously calender both sides of the coated web under conditions sufficient to provide for the penetration of the solution into the web and to remove substantially all entrapped air from the web; and

(d) passing the calendered reinforcing web from step (c) through the second reservoir, completely surrounding the web with casting solution and depositing a sufficient amount of the solution onto the web to again completely coat the web; and

(e) passing the coated web from step (d) through a quenching bath comprising a non-solvent system for the polymer for a time sufficient to form micropores throughout the coatings to thereby form a single layer microporous filter membrane within which a reinforcing web is embedded.

2. The process of claim 1 wherein:

(i) the polymer is nylon;

(ii) the solvent is formic acid;

(iii) the non-solvent is selected from the group consisting of methanol, methyl formate, water and glycerol; and

(iv) the non-solvent system is a mixture of methanol and water or formic acid and water.

3. The process of claim 1, wherein the membrane has a pore size of at least 0.05 microns.

4. The process of claim 1, wherein the membrane is symmetrical and isotropic.

5. The process of claim 1, wherein the polymer is nylon.

6. The process of claim 1, wherein the reinforcing web is wettable by the casting solution.

7. An integral single layer polymeric microporous filter membrane within which a reinforcing web is embedded produced by the process of claims 1, 2 or 5.