Internal protective coatings for sensitive resinous laminae

• US 4,645,708 A
• Filed: 08/13/1984
• Issued: 02/24/1987
• Est. Priority Date: 08/13/1984
• Status: Expired due to Term

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: LeGrand, Donald G.
• Primary Examiner(s): SLUBY, PATRICIA
• Application Number:
  US06/639,711
• Time in Patent Office: 925 Days
• Field of Search: 428/215, 428/412, 428/522, 428/524, 156/106, 156/327
• US Class Current: 428/215
• CPC Class Codes: B32B 17/1033 Laminated safety glass or glazing containing temporary protective coatings or layers
• CPC Class Codes: B32B 2307/554 Wear resistance
• CPC Class Codes: B32B 2307/584 Scratch resistance
• CPC Class Codes: B32B 2307/714 Inert, i.e. inert to chemical degradation, corrosion
• CPC Class Codes: B32B 2605/006 Transparent parts other than made from inorganic glass, e.g. polycarbonate glazings
• CPC Class Codes: B32B 33/00 Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: Y10T 428/24967 Absolute thicknesses specified
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/31515 As intermediate layer
• CPC Class Codes: Y10T 428/31518 Next to glass or quartz
• CPC Class Codes: Y10T 428/31576 Ester monomer type [polyvinylacetate, etc.]
• CPC Class Codes: Y10T 428/31594 Next to aldehyde or ketone condensation product [phenol-aldehyde, etc.]
• CPC Class Codes: Y10T 428/3163 Next to acetal of polymerized unsaturated alcohol [e.g., formal butyral, etc.]
• CPC Class Codes: Y10T 428/31935 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31942 Of aldehyde or ketone condensation product

Abstract

Thermoplastic laminae are given scratch and mar resistance on an external face as well as protection from incompatible additives of adjacent adhesive layers on an internal face by a single cross-linked protective coating.

Claims

1. A method for preventing damage in a laminate or multi-layer composite to a sensitive resinous lamina or layer by incompatible additives of adjoining plastic laminae or layers which method comprises:

(a) coating at least one surface of a sensitive resinous sheet with a polymerized cross-linkable protective coating mixture selected from the group consisting of an acrylic based copolymer containing at least a predominance of acrylic moieties or an amine-aldehyde resin;

(b) curing said polymerized crosslinkable protective coating mixture to form a cross-linked protective coating;

(c) positioning said sensitive resinous sheet so that said protective coating is interposed to separate the resulting sensitive resinous lamina or layer from the resulting adjacent plastic lamina or layer; and

(d) bonding said laminate or multi-layer composite.

2. The method of claim 1 wherein said coating step further requires that said protective coating mixture be applied in such an amount to produce a cured protective coating having a thickness of from about 0.01 mil to about 1 mil.

3. The method of claim 1 wherein said coating step further requires that said polymerizable, cross-linkable, mixture is a polymerizable cross-linkable acrylic based copolymer.

4. The method of claim 1 wherein said coating step further requires that said polymerizable, cross-linkable, protective coating mixture is a polymerizable, cross-linkable, amine-aldehyde resin.

5. The method of claim 1 wherein said positioning step further requires that at least one of said adjacent plastic lamina or layer is plasticized polyvinyl butyral.

6. The method of claim 1 wherein said coating and positioning steps further require that said sensitive resinous lamina or layer be a polycarbonate lamina or layer.

7. The method according to claim 1 wherein said coating step further requires that both surfaces of said sensitive resinous sheet be coated and said positioning step further requires that said sensitive resinous sheet be externally positioned in said laminate.

8. The method according to claim 7 which additionally requires the steps following said curing step of

(i) coating one face of said coated sheet with an additional coat of an uncured hard coat material;

(ii) curing said uncured hard coat material to produce a two layer mar, scratch and chemical solvent resistant coating;

and wherein said positioning step further requires that said twice coated face be the externally positioned face.

9. A laminate or multi-layer composite comprising at least one lamina or layer of sensitive resin having adhered thereto on at least one internal face a polymerized, cross-linked, protective coating selected from the group consisting of an acrylic based copolymer containing at least a predominance of acrylic moieties or an amine-aldehyde resin, said protective coating having adhered thereto on the face opposite said lamina of sensitive resin an incompatible additive containing adhesive interlayer.

10. The laminate or multi-layer composite of claim 9 wherein said protective coating is from about 0.01 mil to about 1 mil in thickness.

11. The laminate or multi-layer composite of claim 9 wherein said protective coating is an acrylic based copolymer.

12. The laminate or multi-layer composite of claim 9 wherein said protective coating is an amine-aldehyde resin.

13. The laminate or multi-layer composite of claim 9 wherein said adhesive interlayer is a plasticizer containing polyvinyl butyral.

14. The laminate or multi-layer composite of claim 9 wherein said sensitive resin is polycarbonate.

15. The laminate or multi-layer composite of claim 9 wherein at least one of said at least one lamina or layer of sensitive resin is externally positioned and is coated on both its internal and external face with said polymerixable cross-linkable protective coating.

16. The laminate or multi-layer composite of claim 15 wherein said polymerizable cross-linkable protective coating of said external face has adhered thereto a second scratch and mar resistant hard coat.