Electrocatalytic gas diffusion electrode employing thin carbon cloth layer

• US 4,647,359 A
• Filed: 10/16/1985
• Issued: 03/03/1987
• Est. Priority Date: 10/16/1985
• Status: Expired due to Fees

• Current Assignee: WALTER JUDA AND Walter Juda Associates, Inc./OR WALTER JUDA ASSOCIATES
• Original Assignee: Prototech AS
• Inventors: Lindstrom, Robert W.
• Primary Examiner(s): Chapman, Terryence
• Application Number:
  US06/787,920
• Time in Patent Office: 503 Days
• Field of Search: 204/98, 204/128, 204/294, 156/280, 156/292, 156/298, 429/42
• US Class Current: 204/294
• CPC Class Codes: C25B 11/031 Porous electrodes
• CPC Class Codes: C25B 11/043 Carbon, e.g. diamond or graphene
• CPC Class Codes: H01M 4/96 Carbon-based electrodes
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y10T 156/109 Embedding of laminae within face of additional laminae

Abstract

An improved electrocatalytic gas diffusion electrode comprising an open pore carbon cloth carrying on one side a first uniform mixture of noble-metal-catalyzed carbon and a hydrophobic binder adhered within the cloth pores and to the yarns of the cloth to a depth less than the thickness of the cloth, and a second uniform mixture of non-catalytic carbon and a hydrophobic binder adhered to the remaining open pore portion on the other side of said cloth; and method of preparation.

Claims

1. A method of preparing an electrocatalytic gas diffusion electrode with an open pore carbon cloth, comprising the steps of depositing a first uniform mixture of noble-metal-catalyzed carbon and a hydrophobic binder on one side of said cloth and adhering said first mixture within the cloth pores and to the yarns of the cloth to a depth less than the thickness of the cloth, and similarly depositing a second uniform mixture of non-catalytic carbon and a hydrophobic binder to the remaining open pore portion on the other side of said cloth and adhering said second mixture within the cloth pores and to the yarns of the cloth to a depth less than the thickness of the cloth.

2. The method of claim 1 wherein said mixtures together substantially fill the thickness of said cloth.

3. The method of claim 1 wherein conducting carbon is inserted into the interior of the cloth between said two mixtures to provide improved conductive contact of the mixtures within the cloth.

4. The method of claim 1 and in which said depositing steps comprise preforming a sheet of one or both of the catalyzed and non-catalytic carbons in the hydrophobic binder and press-fitting the same against the respective sides of the cloth.

5. The method of claim 4 and in which conducting carbon is inserted into the interior of the cloth between said sheets to improve conductive contact of the same within the cloth.

6. An electrocatalytic gas diffusion electrode comprising an open pore carbon cloth carrying on one side a first uniform mixture of noble-metal-catalyzed carbon and a hydrophobic binder adhered within the cloth pores and to the yarns of the cloth to a depth less than the thickness of the cloth, and carrying on the other side of said cloth a second uniform mixture of non-catalytic carbon and a hydrophobic binder adhered within the cloth pores and to the yarns of the cloth to a depth less than the thickness of the cloth.

7. An electrode as claimed in claim 6 wherein said mixtures together substantially fill the thickness of said cloth.

8. An electrode as claimed in claim 6 wherein conducting carbon is inserted into the interior of the cloth between said two mixtures to provide improved conductive contact of the mixtures within the cloth.

9. An electrode as claimed in claim 6 and in which said adhered mixtures comprise preformed sheets of one or both of the catalyzed and non-catalytic carbons in the hydrophobic binder press-fitted against the respective sides of the cloth.

10. An electrode as claimed in claim 9 and in which conducting carbon is inserted into the interior of the cloth to provide improved conductive contact of the sheets within the cloth.

11. A method of preparing an electrocatalytic gas diffusion electrode with an open pore carbon cloth, comprising the steps of rigidizing said cloth by forming a carbonizing coating on the yarns thereof, depositing a first uniform mixture of noblemetal-catalyzed carbon and a hydrophobic binder on one side of the rigidized carbonized cloth and adhering said first mixture within the cloth pores and to the carbonized yarns of the cloth to a depth less than the thickness of the cloth, and similarly depositing a second uniform mixture of non-catalytic carbon and a hydrophobic binder to the remaining open pore portion on the other side of said rigidized carbonized cloth and adhering said second mixture within the cloth pores and to the yarns of the cloth to a depth less than the thickness of the cloth.

12. An electrocatalytic gas diffusion electrode comprising an open pore carbon cloth the yarns of which are coated with a rigidizing carbonized coating and carrying on one side a first uniform mixture of noble-metal-catalyzed carbon and a hydrophobic binder adhered within the cloth pores and to the rigidized carbonized yarns of the cloth to a depth less than the thickness of the cloth, and carrying on the other side of said cloth a second uniform mixture of non-catalytic carbon and a hydrophobic binder adhered within the cloth pores and to the yarns of the cloth to a depth less than the thickness of the cloth.