Dispersion of solvent-suspendible pressure sensitive adhesive particles and pressure sensitive adhesive sheet utilizing the properties of the dispersion

• US 4,647,504 A
• Filed: 12/17/1985
• Issued: 03/03/1987
• Est. Priority Date: 12/22/1984
• Status: Expired due to Term

• Current Assignee: Lintec Corporation
• Original Assignee: Hoechst Gosei Kabushiki Kaisha
• Inventors: Shimokawa, Wataru, Kimimura, Kyomi, Igarashi, Toshibumi
• Primary Examiner(s): VAN BALEN, WILLIAM
• Application Number:
  US06/809,972
• Time in Patent Office: 441 Days
• Field of Search: 428/327, 428/402, 526/271, 526/273
• US Class Current: 428/327
• CPC Class Codes: C08L 2205/18 Spheres
• CPC Class Codes: C09J 133/08 Homopolymers or copolymers of acrylic acid esters
• CPC Class Codes: C09J 2301/302 the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
• CPC Class Codes: Y10T 428/254 Polymeric or resinous material
• CPC Class Codes: Y10T 428/2982 Particulate matter [e.g., sphere, flake, etc.]

Abstract

A dispersion of solvent-suspendible pressure sensitive adhesive particles, which comprises (A) pressure sensitive adhesive particles comprising an internally cross-linked copolymer and having a particle size of 5 to 200 microns and an organic solvent; the copolymer being prepared by copolymerizing

(a) 2 to 10% by weight of at least one member selected from the group consisting of methyl acrylate, styrene and a methacrylate of alcohol having 1 to 5 carbon atoms,

(b) 98 to 90% by weight of at least one member selected from the group consisting of a acrylate of alcohol having 2 to 12 carbon atoms and a methacrylate of alcohol having 6 to 12 carbon atoms;

(c) 0.1 to 2.0% by weight of maleic anhydride, and

(d) 0.05 to 1.0% by weight of at least one member selected from the group consisting of tetraallyloxyethane, triallyl cyanurate and triallyl isocyanurate and a dispersion of solvent-suspendible pressure sensitive adhesive particles prepared by dispersing 2 to 20 parts by weight (as sold matter) of a styrene-containing polymer having a styrene content of 5 to 70% by weight and having a particles size of 0.02 to 3 microns in a 100 parts by weight of the above dispersion, and the pressure sensitive adhesive sheet utilizing the above mentioned dispersions. The pressure sensitive adhesive sheet can be repeatedly adhered and removed. Moreover the pressure sensitive adhesive sheet does not cause the paper-tearing phenomenon nor the adhesive migration phenomenon in case the styrene containing emulsion is employed as a binder.

Claims

1. A dispersion of solvent-suspendible pressure sensitive adhesive particles, which comprises (A) pressure sensitive adhesive particles comprising an internally cross-linked copolymer and having a particle size of 5 to 200 microns and

an organic solvent;

said internally cross-linked copolymer being prepraed by copolymerizing

(a) 2 to 10% by weight of at least one member selected from the group consisting of methyl acrylate, styrene and a methacrylate of alcohol having 1 to 5 carbon atoms,

(b) 98 to 90% by weight of at least one member selected from the group consisting of an acrylate of alcohol having 2 to 12 carbon atoms and a methacrylate of alcohol having 6 to 12 carbon atoms,

(c) 0.1 to 2.0% by weight of maleic anhydride, and

(d) 0.05 to 1.0% by weight of at least one member selected from the group consisting of tetraallyloxyethane, triallyl cyanurate and triallyl isocyanurate.

2. A pressure sensitive adhesive sheet prepared by coating a sheet with a dispersion of solvent-suspendible pressure sensitive adhesive particles, which comprises

(A) pressure sensitive adhesive particles comprising an internally cross-linked copolymer and having a particle size of 5 to 200 microns and

an organic solvent;

said internally cross-linked copolymer being prepared by copolymerizing

(a) 2 to 10% by weight of at least one member selected from the group consisting of methyl acrylate, styrene and a methacrylate of alcohol having 1 to 5 carbon atoms,

(b) 98 to 90% by weight of at least one member selected from the group consisting of an acrylate of alcohol having 2 to 12 carbon atoms and a methacrylate of alcohol having 6 to 12 carbon atoms,

(c) 0.1 to 2.0% by weight of maleic anhydride, and

(d) 0.05 to 1.0% by weight of at least one member selected from the group consisting of tetraallyloxyethane, triallyl cyanurate and triallyl isocyanurate.

3. The pressure sensitive adhesive sheet of claim 2, wherein said substrate sheet has an anchor coating layer placed on a surface thereof.

4. A dispersion of solvent-suspendible pressure sensitive adhesive particles, which comprises

(A) 100 parts by weight of pressure sensitive adhesive particles comprising an internally cross-linked copolymer and having a particle size of 5 to 200 microns,

(B) 2 to 20 parts by weight (as solid matter) of a binder for said pressure sensitive adhesive particles which is a styrene-containing polymer having a styrene content of 5 to 70% by weight and having a particle size of 0.02 to 3 microns,

and an organic solvent;

said internally cross-linked copolymer being prepared by copolymerizing

(a) 2 to 10% by weight of at least one member selected from the group consisting of methyl acrylate, styrene and a methacrylate of alcohol having 1 to 5 carbon atoms,

(b) 98 to 90% by weight of at least one member selected from the group consisting of an acrylate of alcohol having 2 to 12 carbon atoms and a methacrylate of alcohol having 6 to 12 carbon atoms,

(c) 0.1 to 2.0% by weight of maleic anhydride, and

(d) 0.05 to 1.0% by weight of at least one member selected from the group consisting of tetraallyloxyethane, triallyl cyanurate and triallyl isocyanurate.

5. A pressure sensitive adhesive sheet prepared by coating a sheet with a dispersion of solvent-suspendible pressure sensitive adhesive particles, which comprises

(A) 100 parts by weight of pressure sensitive adhesive particles comprising an internally cross-linked copolymer and having a particle size of 5 to 200 microns,

(B) 2 to 20 parts by weight (as solid matter) of a binder for said pressure sensitive adhesive aprticles which is a styrene-containing polymer having a styrene content of 5 to 70% by weight and having a particle size of 0.02 to 3 microns,

and an organic solvent;

said internally cross-linked copolymer being prepared by copolymerizing

(a) 2 to 10% by weight of at least one member selected from the group consisting of methyl acrylate, styrene and a methacrylate of alcohol having 1 to 5 carbon atoms,

(b) 98 to 90% by weight of at least one member selected from the group consisting of an acrylate of alcohol having 2 to 12 carbon atoms and a methacrylate of alcohol having 6 to 12 carbon atoms,

(c) 0.1 to 2.0% by weight of maleic anhydride, and

(d) 0.05 to 1.0% by weight of at least one member selected from the group consisting of tetraallyloxyethane, triallyl cyanurate and triallyl isocyanurate.

6. The pressure sensitive adhesive sheet of claim 5, wherein said substrate sheet has an anchor coating layer placed on a surface thereof.