Integrated process and apparatus for the primary and secondary catalytic steam reforming of hydrocarbons

• US 4,650,651 A
• Filed: 06/09/1983
• Issued: 03/17/1987
• Est. Priority Date: 06/09/1983
• Status: Expired due to Term

• Current Assignee: UOP Des Plaines IL A NY General Partnership
• Original Assignee: Union Carbide Corporation (Dow, Inc.)
• Inventors: Fuderer, Andrija
• Primary Examiner(s): Richman, Barry S.
• Assistant Examiner(s): NOT, DEFINED
• Application Number:
  US06/502,580
• Time in Patent Office: 1,377 Days
• Field of Search: 422/191, 422/194, 422/197, 422/202, 422/208, 422/312, 422/196, 48/196 A, 252/373
• US Class Current: 422/628
• CPC Class Codes: B01J 12/005 carried out at high temperatures, e.g. by pyrolysis
• CPC Class Codes: B01J 2208/00088 Flow rate measurement
• CPC Class Codes: B01J 2208/00274 involving reactant vapours
• CPC Class Codes: B01J 2208/00309 with two or more reactions in heat exchange with each other, such as an endothermic reaction in heat exchange with an exothermic reaction
• CPC Class Codes: B01J 2208/00495 using insulating materials or refractories
• CPC Class Codes: B01J 2208/0053 Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
• CPC Class Codes: B01J 2219/00777 horizontal
• CPC Class Codes: B01J 8/067 Heating or cooling the reactor B01J8/062 takes precedence
• CPC Class Codes: C01B 3/382 Multi-step processes
• CPC Class Codes: Y02P 20/10 Process efficiency

Abstract

Integrated primary-secondary reforming operations are carried out with the partly reformed product effluent from the reformer tubes of the primary reforming zone passing to a catalyst-free reaction space at the feed end of a catalyst bed in the secondary reforming zone. The exothermic heat of reaction generated in said reaction space supplies the necessary heat for the endothermic reforming reaction that occurs in the catalyst bed of the secondary reforming zone, and the still hot secondary product effluent leaving the secondary reforming zone is passed in the shell side of the primary reformer zone to supply the endothermic heat of reaction required in said primary reforming zone. Essentially autothermal operating conditions are thereby achieved so as to essentially eliminate the necessity for employing an external fuel-fired primary reformer and/or for consuming a portion of the hydrocarbon feed material for fuel purposes.

Claims

1. An apparatus for the essentially autothermal, integrated primary and secondary reforming of hydrocarbons comprising:

(a) an internally insulated outer reactor shell adapted for the positioning of primary and secondary reforming zones therein;

(b) means defining a primary reforming zone within said outer reactor shell and having a plurality of catalyst-containing reformer tubes positioned therein, said primary reforming zone not requiring an external fuel fired source of heat for the endothermic primary reforming reaction occuring therein;

(c) means for introducing a fluid hydrocarbon feed stream and steam to said outer reactor shell for passage through said plurality of reformer tubes in said primary reforming zone;

(d) means defining a secondary reforming zone within said outer reactor shell comprising a secondary reforming catalyst bed, a catalyst-free reaction space defining a feed end adjacent to said catalyst bed and a discharge end at the opposite side of said secondary reforming catalyst bed to said feed end;

(e) conduit means positioned entirely within said outer reactor shell and extending through said secondary reforming catalyst bed for passing partly reformed product effluent from the primary reforming zone to said catalyst-free reaction space in the secondary reforming zone;

(f) means for introducing an oxygen-containing gas to said catalyst-free reaction space;

(g) means for introducing secondary product effluent gas removed from said discharge end of the catalyst bed in said secondary reforming zone to the shell side of the primary reforming zone without passage of said secondary product effluent outside of said outer reactor shell; and

(h) discharge means for removing secondary product effluent from the shell side of the primary reforming zone after passage therethrough and passage thereof through said outer reactor shell and away from said integrated primary and secondary reformer,

whereby the exothermic heat of said secondary product effluent can effectively supply the endothermic heat requirements of the primary reforming zone with essentially no fuel requirement and no external fuel-fired primary steam reformer being required for the overall primary-secondary reformation operations.

2. The apparatus of claim 1 and including means for preheating the hydrocarbon feed and the oxygen-containing gas being introduced to said integrated primary-secondary reformer.

3. The apparatus of claim 1 and including an external fuel-fired primary reformer unit and means for bypassing a portion of said hydrocarbon feed and steam to said external primary reformer unit, together with means for passing the product effluent from said unit to said catalyst free reaction space.

4. The apparatus of claim 3 in which said means for passing product effluent from said external primary reformer unit to the catalyst-free reaction space in said secondary reforming zone passes through said secondary reforming catalyst bed.

5. The apparatus of claim 1 and including means for bypassing a portion of said hydrocarbon feed and steam being passed to said primary reforming zone to said secondary reforming zone.

6. The apparatus of claim 5 in which said means for bypassing hydrocarbon feed and steam to said secondary reforming zone are adapted to deliver said hydrocarbon feed and steam to said catalyst-free reaction space in said secondary reforming zone.

7. The apparatus of claim 6 in which said means for bypassing hydrocarbon feed and steam are adapted to introduce said reactants onto an upper portion of said catalyst-free reaction space.

8. The apparatus of claim 1 in which said secondary reforming zone is positioned above the primary reforming zone.

9. The apparatus of claim 8 in which said plurality of primary reforming tubes are substantially vertical, the hydrocarbon feed/steam reaction mixture to said zone being introduced to the lower end of said tubes at a bottommost inlet portion thereof, the partly reformed product effluent leaving the reformer tubes at the upper end thereof.

10. The apparatus of claim 9 in which said catalyst-free reaction space at the feed end of the catalyst bed is positioned above said catalyst bed.

11. The apparatus of claim 10 in which said conduit means is positioned concentrically within said means defining a secondary reforming zone.

12. The apparatus of claim 10 in which said means for introducing an oxygen-containing gas to said catalyst-free reaction space introduces said gas into an upper portion of said reaction space.

13. The apparatus of claim 10 in which said outer reactor shell has a layer of refractory material supported thereon.

14. The apparatus of claim 13 in which said outer reactor shell comprises a double shell and including means for passing a coolant fluid through an annular space defined between the inner and outer shells.