Polyphenylene oxide membrane having chemically bonded coating

• US 4,652,283 A
• Filed: 06/30/1983
• Issued: 03/24/1987
• Est. Priority Date: 06/30/1983
• Status: Expired due to Fees

• Current Assignee: Permea Incorporated
• Original Assignee: Monsanto Company (Bayer AG)
• Inventors: Zampini, Anthony, Malon, Raymond F.
• Primary Examiner(s): SPITZER, ROBERT H
• Application Number:
  US06/509,633
• Time in Patent Office: 1,363 Days
• Field of Search: 55/16, 55/68, 55/158, 210/500.2
• US Class Current: 96/13
• CPC Class Codes: B01D 2323/30 Cross-linking
• CPC Class Codes: B01D 67/0093 Chemical modification
• CPC Class Codes: B01D 69/12 Composite membranes; Ultra-thin membranes
• CPC Class Codes: B01D 69/1214 Chemically bonded layers, e.g. cross-linking
• CPC Class Codes: B01D 71/52 Polyethers
• CPC Class Codes: B01D 71/5223 Polyphenylene oxide, phenyl ether polymers or polyphenylethers

Abstract

A coated membrane for gas separations wherein the membrane is made up of an amine cross-linked poly(phenylene oxide) substrate membrane having about 1 to about 7 weight percent nitrogen and a coating on the substrate membrane. The coating is a polymer containing groups capable of reacting with amine groups at the surface of the substrate membrane to ionically or covalently bond the coating to the substrate.

Claims

1. A coated membrane for gas separations, comprising

a. a cross-linked poly(phenylene oxide) polymer substrate membrane containing about 1 to about 7 weight percent nitrogen, and

b. a coating on the substrate membrane, said coating being a polymer having groups capable of reacting with the amine groups in the polymer of the substrate membrane to ionically bond the coating to the substrate, said coating being ionically bonded to said substrate.

2. The membrane of claim 1 wherein the coating polymer is a sulfonated poly(phenylene oxide) polymer.

3. The membrane of claim 2 wherein the coating polymer is a poly(phenylene oxide) polymer having --SO₃ H groups as a substituent.

4. The membrane of claim 2 wherein the polymer of the substrate membrane is poly(2,6-dimethyl-1,4-phenylene oxide).

5. The membrane of claim 4 wherein the polymer aryl groups have 3 and 5 positions linked to substituents selected from the group consisting of hydrogen, halogen, nitro, aliphatic hydrocarbons having 1 to 4 carbon atoms and acyl radicals having at least two carbon atoms.

6. The membrane of claim 1 wherein the coating is made up of 100 parts of dimethyl siloxane diol and 1 to 20 parts of a silicone compound containing epoxy, chloropropyl or isocyanato functional groups.

7. The membrane of claim 6 wherein the silicone compound is selected from the group consisting of glycidoxypropyl trimethoxy silane, chloropropyl trimethoxysilane, isocyanatopropyl triethoxysilane and 3,4-epoxycyclothexyl ethyl trimethoxy silane.

8. A coated membrane for gas separations, comprising

a. a cross-linked poly(phenylene oxide) polymer substrate membrane containing about 1 to about 7 weight percent nitrogen, and

b. a coating on the substrate membrane, said coating being a polymer having groups capable of reacting with the amine groups in the polymer of the substrate membrane to covalently bond the coating to the substrate, said coating being covalently bonded to said substrate.

9. The membrane of claim 8 wherein the coating polymer is selected from the group consisting of a chloroacetylated poly(phenylene oxide) polymer, a benzyl halogenated aryl polymer and a silicone compound having epoxy, chloropropyl or isocyanato functional groups.

10. The membrane of claim 9 wherein the coating is a poly(phenylene oxide) polymer having --COCH₂ Cl groups as a substituent.

11. The membrane of claim 9 wherein the coating is a poly(phenylene oxide) polymer having bromine as a substituent.

12. The membrane of claim 9 wherein the coating is a poly(phenylene oxide) polymer having chlorine as a substituent.

13. The membrane of claim 9 wherein the polymer of the substrate membrane has at least 0.01 substituent per monomeric unit of a halogenated alkyl or acyl of from 1 to 4 carbon atoms.

14. The membrane of claim 9 wherein the polymer of the substrate membrane is poly(2,6-dimethyl-1,4-phenylene oxide).

15. The membrane of claim 14 wherein the 3 and 5 positions of the aryl group are linked to substituents selected from the group consisting of hydrogen, halogen, nitro, aliphatic hydrocarbon radicals having 1 to 4 carbon atoms and acyl radicals having at least two carbon atoms.

16. The membrane of claim 8 wherein the coating is made up of 100 parts of dimethyl siloxane diol and 1 to 20 parts of a silicone compound containing epoxy, chloropropyl or isocyanato functional groups.

17. The membrane of claim 16 wherein the silicone compound is selected from the group consisting of glycidoxypropyl trimethoxy silane, chloropropyl trimethoxysilane, isocyanatopropyl triethoxysilane and 3,4-epoxycyclothexyl ethyl trimethoxy silane.