Adsorbent and substrate products and method of producing same

• US 4,656,156 A
• Filed: 01/21/1986
• Issued: 04/07/1987
• Est. Priority Date: 01/21/1986
• Status: Expired due to Term

• Current Assignee: Almatis AC, Inc. (BASF SE)
• Original Assignee: Aluminum Company of America (Howmet Aerospace, Inc.)
• Inventors: Misra, Chanakya
• Primary Examiner(s): SHINE, WILLIAM
• Application Number:
  US06/820,166
• Time in Patent Office: 441 Days
• Field of Search: 502/174, 502/414, 502/415, 502/439
• US Class Current: 502/415
• CPC Class Codes: B01J 20/041 Oxides or hydroxides
• CPC Class Codes: B01J 20/08 comprising aluminium oxide or hydroxide; comprising bauxite
• CPC Class Codes: B01J 20/2803 Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
• CPC Class Codes: B01J 20/3042 Use of binding agents; addition of materials ameliorating the mechanical properties of the produced sorbent
• CPC Class Codes: B01J 20/3071 Washing or leaching
• CPC Class Codes: B01J 20/3078 Thermal treatment, e.g. calcining or pyrolizing
• CPC Class Codes: C01F 7/785 Hydrotalcite
• CPC Class Codes: C01P 2002/22 layered hydroxide-type, e.g. of the hydrotalcite-type
• CPC Class Codes: C01P 2002/72 by d-values or two theta-values, e.g. as X-ray diagram
• CPC Class Codes: C01P 2002/88 by thermal analysis data, e.g. TGA, DTA, DSC
• CPC Class Codes: C01P 2004/03 obtained by SEM
• CPC Class Codes: C01P 2006/10 Solid density
• CPC Class Codes: C01P 2006/12 Surface area
• CPC Class Codes: C01P 2006/14 Pore volume
• CPC Class Codes: C01P 2006/16 Pore diameter

Abstract

Novel adsorbent and substrate compositions are formed by mixing activated aluminas and synthetic hydrotalcite produced by reacting activated magnesia with an aqueous solution containing aluminate, carbonate, and hydroxyl ions. Activated magnesia used in this method is formed by heating a magnesium compound such as magnesium carbonate or magnesium hydroxide to a temperature between about 500°-900° C. The method is suited to producing synthetic hydrotalcite from industrial Bayer liquor. The synthetic hydrotalcite so formed can be heated to a temperature of about 500°-600° C. to form a highly porous and adsorbent product either before or after mixing with activated aluminas to form the composite of the present invention.

Claims

1. A composition useful as an adsorbent or substrate comprising about 20%-80% by weight hydrotalcite mixed with about 80%-20% by weight activated alumina, wherein said composition has been activated by heating the hydrotalcite to a temperature of about 500°

-60020 C. or after mixing with the activated alumina.

2. A composition as set forth in claim 1 wherein said hydrotalcite is formd synthetically by reacting activated magnesia with an aqueous alkali solution containing ions of aluminate, carbonate, and hydroxyl at a temperature of about 80°

-100°

C. to form hydrotalcite in high yield.

3. A composition as set forth in claim 2 wherein said hydrotalcite is formed in high purity.

4. A composition as set forth in claim 3, wherein said reacting further comprising a first step of heating magnesium carbonate or magnesium hydroxide to a temperature between about 500°

-900°

C. to form said activated magnesia.

5. A composition as set forth in claim 4 wherein said magnesium carbonate or magnesium hydroxide is heated to a temperature between about 550°

-650°

C. for a period of about 30 to 120 minutes.

6. A composition as set forth in claim 5 wherein said aqueous solution containing ions of aluminate, carbonate, and hydroxyl comprises about 120-250 g/l NaOH (expressed as Na₂ CO₃), about 20-100 g/l Na₂ CO₃, and about 50-150 g/l Al₂ O₃.

7. A composition as set forth in claim 6 wherein about 5-25 g/l activated magnesia is added to said aqueous solution.

8. A composition as set forth in claim 7, said reacting step further comprising washing and drying to recover hydrotalcite as a solid in high purity.

9. A method of producing an adsorbent or substrate comprising:

(a) heating magnesium carbonate or magnesium hydroxide to a temperature in the range of about 500°

-900°

C. to form activated magnesia,

(b) reacting said activated magnesia at a temperature of about 80°

-100°

C. with an aqueous alkali solution containing ions of aluminate, carbonate, and hydroxyl comprising 120-250 g/l NaOH (expressed as Na₂ CO₃), 20-100 g/l Na₂ CO₃, and 50-150 g/l Al₂ O₃ to form a synthetic hydrotalcite,

(c) mixing said synthetic hydrotalcite with activated alumina, and

(d) heating said synthetic hydrotalcite to a temperature of about 500°

-600°

C. before or after said mixing with said activated alumina.

10. A method as set forth in claim 9 wherein said aqueous solution has a pH above about 13 and said magnesia is added in an amount of about 1.0 mols to 2.5 mols aluminate ion.

11. A method as set forth in claim 10 wherein said solution is essentially free from chlorine or sulfate ions other than as impurities present in the Bayer liquor.

12. A method as set forth in claim 11 further comprising recovering hydrotalcite by drying and heating to a temperature in the range of about 500°

-600°

C. to form a highly porous and adsorbent product prior to mixing with the activated alumina.

13. A method as set forth in claim 12 wherein said mixing is followed by rehydration and forming steps carried out by pan-type agglomeration, fluidized bed, extruder, or tabletting.

14. A method as set forth in claim 13 wherein said reacting compreses heating to a temperature of at least about 80°

C. at atmospheric pressure.

15. A method of producing an adsorbent product comprising:

(a) heating magnesium carbonate or magnesium hydroxide to a temperature in the range of about 500°

-900°

C. to form activated magnesia,

(b) reacting said activated magnesia with an aqueous solution of industrial Bayer liquor at a temperature of abut 80°

-100°

C. and a pH above about 13, said Bayer liquor containing aluminate, carbonate, and hydroxyl ions present in an amount of 120-250 g/l sodium hydroxide expressed as sodium carbonate, 20-100 g/l sodium carbonate, and 50-150 g/l aluminate,

(c) washing and drying said hydrotalcite to form recovered hydrotalcite,

(d) heating said recovered hydrotalcite to a temperature in the range of about 500°

-600°

C. to form a porous and adsorbent product,

(e) mixing said porous product of hydrotalcite with activated alumina to form an adsorbent mixture, and

(f) rehydrating said mixture of hydrotalcite and alumina and forming by pan-type agglomerator, fluidized bed, extruder, or tablet forming apparatus.