Self regulating heating device employing positive temperature coefficient of resistance compositions

• US 4,658,121 A
• Filed: 08/29/1985
• Issued: 04/14/1987
• Est. Priority Date: 08/04/1975
• Status: Expired due to Term

• Current Assignee: Tyco Electronics Corporation (TE Connectivity Limited)
• Original Assignee: Raychem Corporation (TE Connectivity Limited)
• Inventors: Hammack, Teddy J., Horsma, David A.
• Primary Examiner(s): Griffin, Donald A.
• Application Number:
  US06/771,384
• Time in Patent Office: 593 Days
• Field of Search: 219/505, 219/510, 219/553, 338/22 R, 252/500, 252/511
• US Class Current: 219/553
• CPC Class Codes: C08L 101/00 Compositions of unspecified macromolecular compounds
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: H01B 1/24 the conductive material comprising carbon-silicon compounds, carbon or silicon
• CPC Class Codes: H01C 7/027 consisting of conducting or semi-conducting material dispersed in a non-conductive organic material

Abstract

Disclosed is a positive temperature coefficient of resistance (PTC) crosslinked polymeric composition comprising a first polymeric material exhibiting high green strength prior to crosslinking and elastomeric behavior subsequent to cross-linking, and a second polymeric material comprising a thermoplastic, both said materials having dispersed therein conductive particles, e.g., carbon black, and further, said composition exhibiting a rise in resistance with increased temperature at temperatures above the melting point of either material.

Claims

1. A self-regulating heating article comprising at least two electrodes and a crosslinked electrically conductive polymer composition, the electrodes being connectable to a power supply so that current will pass between the electrodes through the conductive polymer composition, said composition having a positive temperature coefficent of resistivity and comprising (1) a first polymeric material which prior to cross-linking exhibits significant green strength corresponding to a tensile stress of at least 10 psi at 20% elongation and which exhibits elastomeric properties at ambient temperatures in the crosslinked state;

(2) a second thermoplastic polymer material; and

(3) conductive particles which have been dispersed in said polymeric material such that the composition exhibits increased resistance with increased temperatures at temperatures substantially above the melting point of either material.

2. The article of claim 1 wherein the conductive particles are carbon black.

3. The article of claim 1 wherein the elastomeric and thermoplastic materials are separate segments contained in a graft or block copolymer.

4. The article of claim 3 wherein the elastomeric material is polytetramethylene oxide and the thermoplastic material is polytetramethylene terephthalate.

5. The article of claim 3 wherein the elastomeric region provides 30-70% by weight of the copolymer.

6. The article of claim 1 wherein the elastomeric and thermoplastic materials comprise a physical blend of polymers.

7. The article of claim 6 wherein the elastomeric material is selected from the group consisting of chlorinated polyethylene.

8. The article of claim 1 wherein the elastomeric material is an ethylenepropylene rubber and the thermoplastic material is a crystalline polyolefin.

9. The article of claim 1 wherein the elastomeric material is an ethylenepropylene rubber and the thermoplastic material is a polystyrene.

10. The article of claim 1 wherein the crosslinked polymeric composition comprises an ethylene-propylene rubber, polypropylene and carbon black.

11. The article of claim 10 wherein the polypropylene is in the range of from 5 to 40% of the composition, the ethylene-propylene rubber is from 40 to 90% and the carbon black ranges from 5 to 35%.

12. The article of claim 1 wherein the amount of the elastomeric material is from about 3 to about 75% by weight of the combined weight of elastomeric material and thermoplastic material.

13. The article of claim 12 wherein the amount of the elastomeric material is from about 4 to about 40% by weight of elastomeric material and thermoplastic material.

14. The article of claim 1 wherein the amount of the conductive material is from about 4 to 60% by weight of the composition.

15. The article of claim 14 wherein the amount of the conductive material is from about 5 to 50% by weight of the composition.

16. The article of claim 1 wherein the amount of the elastomeric material is from about 4 to 40% by weight of the combined weight of the elastomeric material and the thermoplastic material, and the amount of the conductive filler is from 5 to 50% by weight of the composition.

17. The article of claim 1 which has been cross-linked by ionizing radiation.

18. The article of claim 1 which has been annealed to obtain minimum resistance.