Method for the decaffeination of roasted coffee extracts

• US 4,659,577 A
• Filed: 10/31/1985
• Issued: 04/21/1987
• Est. Priority Date: 09/27/1984
• Status: Expired due to Fees

• Current Assignee: General Foods Corporation 250 North Street White Plains NY
• Original Assignee: General Food Corporation (Altria Group, Inc.)
• Inventors: Musto, Joseph A., Meinhold, James F., Gottesman, deceased, Martin, Kramer, Karl C.
• Primary Examiner(s): Golian, Joseph
• Application Number:
  US06/793,505
• Time in Patent Office: 537 Days
• Field of Search: 426/424, 426/387
• US Class Current: 426/387
• CPC Class Codes: A23F 5/226 by extraction with selective solvents

Abstract

A method of decaffeinating aqueous roasted coffee extracts is disclosed. An organic caffeine solvent is first loaded with essentially hydrolyzed coffee solids. The aqueous roasted coffee extract is contacted with the loaded organic caffeine solvent for a sufficient period of time to transfer at least some of the caffeine from the coffee extract to the caffeine solvent, whereupon the extract is separated from the caffeine-containing solvent. The resultant coffee extract has been found to have noticably more body notes than a coffee extract which is decaffeinated with a solvent that has not been loaded with hydrolyzed coffee solids.

Claims

1. A method of decaffeinating aqueous roasted coffee extracts which comprises:

(a) loading an organic caffeine solvent with hydrolyzed roasted coffee solids obtained from roasted coffee grounds after the grounds have been at least thoroughly atmospherically extracted of at least 20% of the solids therein;

(b) contacting an aqueous extract of roasted and ground coffee with the loaded organic caffeine solvent of (a) for a period of time sufficient to transfer at least 96% of the caffeine from the aqueous roasted coffee extract to the loaded caffeine solvent;

(c) separating the roasted decaffeinated coffee extract from which the caffeine has been transferred from the then caffeine-containing loaded organic caffeine solvent; and

(d) drying the roasted decaffeinated coffee extract.

2. A method as in claim 1 wherein the hydrolyzed coffee extract in step (a) is at a concentration of from 10% to 40% by weight hydrolyzed coffee solids.

3. A method as in claim 2 wherein the organic caffeine solvent is contacted with the hydrolyzed coffee extract in a liquid-liquid contactor at a weight ratio of from 1:

1 to 10;

1 organic caffeine solvent to hydrolyzed coffee extract.

4. A method as in claim 3 wherein the organic caffeine solvent is contacted with the hydrolyzed coffee extract at a temperature of from 70°

F. to 180°

F.

5. A method as in claim 4 wherein the loaded organic caffeine solvent has a hydrolyzed coffee solids concentration of from 0.1% to 1.0% by weight.

6. A method as in claim 1 wherein the organic caffeine solvent is loaded with hydrolyzed coffee solids by contacting the caffeine solvent with an aqueous hydrolyzed coffee extract prepared from the acid hydrolysis or thermal hydrolysis without the incorporation of an acid catalyst of roasted coffee spent grounds which have been at least atmospherically extracted.

7. A method as in claim 6 wherein the hydrolyzed coffee extract is at a concentration of from 10% to 40% by weight hydrolyzed coffee solids.

8. A method as in claim 7 wherein the organic caffeine solvent is contacted with the hydrolyzed coffee extract in a liquid-liquid contactor at a weight ratio of from 1:

1 to 10;

1 organic caffeine solvent, to hydrolyzed coffee extract.

9. A method as in claim 8 wherein the organic caffeine solvent is contacted with the hydrolyzed coffee extract at a temperature of from 70°

F. to 180°

F.

10. A method as in claim 9 wherein the loaded organic caffeine solvent has a hydrolyzed coffee solids concentration of from 0.1% to 1.0% by weight.

11. A method as in claim 1 wherein the organic caffeine solvent is loaded with essentially hydrolyzed coffee solids by contacting the caffeine solvent with spent coffee grounds.

12. A method as in claim 11 wherein the spent coffee grounds have had about 10% to 55% by weight of the starting weight of the roasted and ground coffee previously extracted.

13. A method as in claim 12 wherein the organic caffeine solvent is contacted with the spent grounds in a solid-liquid contactor at a weight ratio (dry basis spent grounds) of from 1:

1 to 10;

1 organic caffeine solvent to spent coffee grounds.

14. A method as in claim 13 wherein the organic caffeine solvent is contacted with the spent coffee grounds at a temperature of from 70°

F. to 180°

F.

15. A method as in claim 14 wherein the loaded organic caffeine solvent has a hydrolyzed coffee solids concentration of from 0.1% to 1.0% by weight.

16. A method as in claim 1 wherein the roasted coffee extract has a total solids concentration of from 10% to 50% by weight and a caffeine concentration of from 0.1% to 5% by weight.

17. A method as in claim 16 wherein the organic caffeine solvent is a halogenated hydrocarbon solvent.

18. A method as in claim 17 wherein the organic caffeine solvent is methylene chloride.

19. A method as in claim 18 wherein the roasted coffee extract is contacted with the loaded organic caffeine solvent in a liquid-liquid contactor at a weight ratio of from 1:

1 to 10;

1 organic caffeine solvent to roasted coffee extract.

20. A method as in claim 19 wherein the roasted coffee extract is contacted with the loaded organic caffeine solvent at a temperature of from 70°

F. to 180°

F.

21. A method as in claim 20 which further comprises stripping the volatile flavor and aroma components from the roasted coffee extract prior to the contact of the extract and the loaded organic caffeine solvent and collecting the volatile flavor and aroma components for subsequent addition to the coffee extract.

22. A method as in claim 21 which further comprises stripping residual organic caffeine solvent from the roasted coffee extract from which a portion of the caffeine has been transferred;

and adding the collected volatile flavor and aroma components to the coffee extract.

23. A method as in claim 1 which further comprises recovering the caffeine from the caffeine-containing loaded organic caffeine solvent and recycling the organic caffeine solvent to the method of claim 1.