Dichroic dye-nematic liquid crystal mirror

• US 4,660,937 A
• Filed: 06/25/1984
• Issued: 04/28/1987
• Est. Priority Date: 06/25/1984
• Status: Expired due to Fees

• Current Assignee: Crystaloid Electronics Co. (Kimberly-Clark Corporation)
• Original Assignee: Crystaloid Electronics Co. (Kimberly-Clark Corporation)
• Inventors: Richardson, Kenneth J.
• Primary Examiner(s): NOT, DEFINED
• Assistant Examiner(s): NOT, DEFINED
• Application Number:
  US06/623,976
• Time in Patent Office: 1,037 Days
• Field of Search: 350/349, 350/352, 350/331 R
• US Class Current: 349/195
• CPC Class Codes: B60R 1/088 using a cell of electrically changeable optical characteristic, e.g. liquid-crystal or electrochromic mirrors
• CPC Class Codes: G02F 1/13725 based on guest-host interaction G02F1/13762, G02F1/13737, take precedence

Abstract

A dichroic dye-containing nematic liquid crystal mirror has a photocell connected thereto to automatically change, that is, to dim or brighten, the mirror upon exposure to light. Under the preferred operating conditions, the mirror functions as an ordinary mirror but is dimmed by light. The invention is especially suited for the rearview mirror of an automobile.

Claims

1. An electro-optic, light changeable mirror, comprising:

a transparent front member and a transparent back member;

said front member having a conductive coating thereon and said back member having a conductive coating thereon;

a nematic liquid crystal located between said front transparent member and said back transparent member, said liquid crystal having a negative dielectric anisotropy;

a dichroic dye, said dichroic dye admixed in said liquid crystal;

a reflective surface, said reflective surface located in back of said nematic liquid crystal; and

a light sensitive photocell, said photocell connected to said front transparent conductive coating and to said back conductive coating.

2. An electro-optic, light dimmable mirror according to claim 1, wherein said front member has said conductive coating on the back side thereof, wherein said back member has said conductive coating on the front side thereof, and wherein said liquid crystal contacts said front transparent conductive coating and said back conductive coating.

3. An electro-optic, light dimmable mirror according to claim 2, wherein the amount of said dichroic dye is from about 0.01 to about 10 parts by weight per 100 parts by weight of said liquid crystal.

4. An electro-optic, light changeable mirror according to claim 3, wherein said dichroic dye is positive.

5. An electro-optic, light changeable mirror according to claim 4, wherein said mirror is free of light polarizers.

6. An electro-optic, light changeable mirror according to claim 5, whereupon said photo sensitive receiving a threshold of light incident thereon automatically reduces the amount of light reflected from said mirror.

7. An electro-optic, light changeable mirror according to claim 6, wherein said mirror is substantially reflective in the absence of any electrical current supplied to said coatings by said photocell and wherein said back conductive coating is said mirror reflective surface.

8. An electro-optic, light changeable mirror according to claim 7, wherein the amount of said dichroic dye ranges from about 0.1 to about 3.5 parts by weight per 100 parts by weight of said liquid crystal.

9. An electro-optic, light changeable mirror according to claim 3, wherein said negative liquid crystal is selected from the group consisting of phenylcyclohexane, and wherein said positive dichroic dye is selected from the group consisting of azo dyes, anthraquinone dyes, and combinations thereof.

10. An electro-optic, light changeable mirror, comprising:

a transparent front member and a transparent back member;

said front member having a conductive coating thereon and said back member having a conductive coating thereon;

a nematic liquid crystal located between said front transparent member and said back transparent member, said liquid crystal having a positive dielectric anisotropy;

a dichroic dye, said dichroic dye admixed in said liquid crystal;

a reflective surface, said reflective surface located in back of said nematic liquid crystal; and

a light sensitive photocell, said photocell connected to said front transparent conductive coating and to said back conductive coating.

11. An electro-optic, light changeable mirror according to claim 10, wherein said front member has said conductive coating on the back side thereof, wherein said back member has said conductive coating on the front side thereof, wherein said liquid crystal contacts said front transparent conductive coating and said back conductive coating, and wherein the amount of said dichroic dye is from about 0.01 to about 10 parts by weight per 100 parts by weight of said liquid crystal.

12. An electro-optic, light changeable mirror according to claim 11, wherein said dichroic dye is positive and wherein said mirror is free of light polarizers.

13. An electro-optic, light changeable mirror according to claim 12, wherein said mirror has a low amount of reflectivity in the absence of any electrical current supplied to said coatings and wherein said back conductive coating is said mirror reflective surface.

14. An electro-optic, light changeable mirror according to claim 13, wherein the amount of said dichroic dye ranges from about 0.1 to about 3.5 parts by weight per 100 parts by weight of said liquid crystal.

15. A dichroic dye-nematic liquid crystal mirror, comprising:

a mirror, said mirror having a controlled amount of light incident thereupon, liquid crystal being of a negative or positive dielectric anisotropy material;

a front transparent conductive material and a back conductive material, said liquid crystal located between said front conductive and said back conductive material;

said mirror having a reflective mirror surface, said reflective mirror surface located in back of said liquid crystal;

the dichroic dye admixed in said liquid crystal in an amount of from about 0.01 to about 10 parts by weight per 100 parts by weight of said liquid crystal;

a light sensitive photocell, said photocell connected to said front and said back conductive materials so that said photocell controls the amount of reflectivity therefrom.

16. A dichroic dye-nematic liquid crystal mirror according to claim 15, wherein said mirror is free from any polarizers, and wherein said liquid crystal contacts said front and said back coating material.

17. A dichroic dye-nematic liquid crystal mirror according to claim 15, wherein said liquid crystal is a negative dielectric anisotropy material and said dye is a positive dichroic dye.

18. A dichroic dye-nematic liquid crystal mirror according to claim 17, wherein increased light intensity to said photocell decreases the amount of reflection.

19. A dichroic dye-nematic liquid crystal mirror according to claim 18, wherein the amount of said dichroic dye ranges from about 0.1 to about 3.5 parts by weight.

20. A dichroic dye-nematic liquid crystal mirror according to claim 19, wherein said reflective mirror surface is said back conductive coating.