Delayed coking process

• US 4,661,241 A
• Filed: 04/01/1985
• Issued: 04/28/1987
• Est. Priority Date: 04/01/1985
• Status: Expired due to Term

• Current Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Original Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Inventors: Malladi, Madhava, Dabkowski, Michael J.
• Primary Examiner(s): Metz, Andrew H.
• Assistant Examiner(s): MCFARLANE, ANTHONY R
• Application Number:
  US06/718,328
• Time in Patent Office: 757 Days
• Field of Search: 208/131, 208/50, 208/56, 208/132, 208/107
• US Class Current: 208/131
• CPC Class Codes: C10B 55/00 Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material cracking oils C10G
• CPC Class Codes: C10B 57/06 containing additives
• CPC Class Codes: C10G 9/02 in retorts

Abstract

A delayed coking process having improved liquid yield and liquid product distribution relative to coke yield is characterized by the absence of heavy recycle. The coker feedstock is heated in the coker furnace and led to the coker drums where coking takes place and the vaporous effluence are passed to a fractionator from which the heavy gas oil fraction is removed as product. Process heat is conserved by indirect heat exchange of the feedstock with the coking products prior to the feedstock entering the coking furnace. A further improvement in liquid yield and selectivity is obtained by adding a solvent or diluent to the feedstock and this may be either a hydrocarbon fraction such as a coker distillate, a light gas oil or another fraction having an end point below 450° C.; in addition, it may be used in conjunction with a reactive or nonreactive gas such as nitrogen, steam, hydrogen or hydrogen sulfide.

Claims

1. In a delayed coking process in which a heavy oil coker feedstock is heated to an elevated coking temperature in a furnace and the heated feedstock is subsequently subjected to delayed coking in a coker drum under superatmospheric pressure and the vaporous coking products are removed from the drum and passed to a coker fractionator from which a bottoms fraction is removed,

the improvement comprising coking a feed without the addition of the bottoms fraction from the fractionator and adding to the feed to the coker drum a lower boiling hydrocarbon diluent having an end boiling point of not more than 450°

C., the lower boiling hydrocarbon diluent being added to the heated feedstock after the feedstock has passed through the furnace.

2. A process according to claim 1 in which the diluent comprises a light gas oil.

3. A process according to claim 1 in which the hydrocarbon diluent is present in an amount from 1 to 40 percent of the fresh coker feedstock.

4. A process according to claim 1 in which the amount of the hydrocarbon diluent is from 5 to 25 percent of the fresh coker feedstock.

5. A process according to claim 1 in which the feedstock has a gravity of less than 12 °

API.

6. A process according to claim 1 in which the feedstock has a gravity of less than 9 °

API.

8. A process according to claim 1 in which the feedstock has a gravity of less than 9 °

API and a Conradsen Carbon Residue greater than 14.0.

9. A process according to claim 1 in which the hydrocarbon diluent comprises a hydrogen donor diluent.

10. A process according to claim 1 in which the vaporous coking products are passed from the coker drum to a fractionator tower to produce fractionated coking products including a gas oil product which is withdrawn from the system, a portion of the gas oil product being returned to the fractionator to condense the vaporous coking products from the coker drum.

11. A process according to claim 10 in which a portion of the gas oil product is withdrawn to quench the vaporous coking products as they leave the coker drum.

12. A process according to claim 1 in which the hydrocarbon diluent comprises a liquid product of the coking process which is added as diluent to the fresh coker feedstock.

13. A process according to claim 1 in which the coker feedstock is cracked in the absence of added catalysts.

14. A process according to claim 13 in which the coker feedstock is cracked in the absence of added hydrogen.

15. A process according to claim 1 in which an inert gas diluent is added to the feedstock.

16. A process according to claim 15 in which the inert gas comprises steam.

17. A process according to claim 1 in which a reactive gas is added to the feedstock.

18. A process according to claim 1 in which the coker feedstock comprises a vacuum residuum.

19. A process according to claim 1 in which the hydrocarbon diluent comprises a hydrogen donor solvent.

20. A process according to claim 19 in which the hydrogen donor solvent comprises tetrahydronaphthalene.

7. A process according to clam 1 in which the feedstock has a gravity of less than 12 °

API and a Conradsen Carbon Residue greater than 10.0.